Low-Temperature Deposition of Highly Conductive n-Type Hydrogenated Nanocrystalline Cubic SiC Films for Solar Cell Applications

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Published 14 April 2006 Copyright (c) 2006 The Japan Society of Applied Physics
, , Citation Shinsuke Miyajima et al 2006 Jpn. J. Appl. Phys. 45 L432 DOI 10.1143/JJAP.45.L432

1347-4065/45/4L/L432

Abstract

Highly conductive n-type hydrogenated nanocrystalline cubic silicon carbide (nc-3C-SiC:H) films have been deposited by hot-wire chemical vapor deposition at low temperatures below 300 °C. We found that hexamethyldisilazane is an effective dopant for n-type doping into nc-3C-SiC:H films. Dark conductivity and its activation energy for the n-type nc-3C-SiC:H film were found to be 5.32 S/cm and 25 meV. We also fabricated nc-3C-SiC:H/crystalline silicon heterojunction diodes and solar cells. These devices showed good rectifying characteristics, and conversion efficiency of 13.4% was achieved.

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10.1143/JJAP.45.L432