Photoluminescence Spectra of Carbon Clusters Embedded in SiO2

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Copyright (c) 1993 The Japan Society of Applied Physics
, , Citation Shinji Hayashi et al 1993 Jpn. J. Appl. Phys. 32 L274 DOI 10.1143/JJAP.32.L274

1347-4065/32/2B/L274

Abstract

Composite films of carbon and SiO2 were prepared by a rf cosputtering technique and their photoluminescence and absorption spectra were measured. A strong and broad photoluminescence peak located around 2.2 eV (visible to the naked eye) was observed for the samples with relatively low carbon concentrations. The blue shift of the photoluminescence peak observed with decreasing carbon concentration and the increased absorption in the UV region strongly suggest that carbon clusters comparable to or smaller than C60 formed in the SiO2 matrices are responsible for the strong photoluminescence.

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10.1143/JJAP.32.L274