Solid‐State  CO 2 Sensor with Li2 CO 3 ‐ Li3 PO 4 ‐ LiAlO2 Electrolyte and LiCoO2 ‐ Co3 O 4 as Solid Reference Electrode

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© 1997 ECS - The Electrochemical Society
, , Citation Yi Can Zhang et al 1997 J. Electrochem. Soc. 144 4345 DOI 10.1149/1.1838190

1945-7111/144/12/4345

Abstract

A solid‐state electrochemical cell of the type mole percent (m/o) (+5 m/o + 6 m/o )/Au, , was composed for determining concentration, where , a lithium ion conductor, is an electrolyte, and is used as the solid reference electrode. Electromotive force (EMF) of the cell depended logarithmically on the partial pressure in gas mixtures at temperatures between 350 and 400°C. EMF reached a constant value within 1 min after the change of partial pressure at 400°C. The sensitivity to of this cell was not affected by coexistence of water vapor. The sensor worked stably during a test period of 30 days. The sensing mechanism of was discussed together with an explanation to the stability of this sensor.

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10.1149/1.1838190