Design of Primary and Secondary Cells: II . An Equation Describing Battery Discharge

© 1965 ECS - The Electrochemical Society
, , Citation C. M. Shepherd 1965 J. Electrochem. Soc. 112 657 DOI 10.1149/1.2423659

1945-7111/112/7/657

Abstract

A discussion is given of the derivation and application of an equation which gives an excellent description of a wide variety of cell and battery discharges. This equation gives the cell potential during discharge as a function of discharge time, current density, and certain other factors. It makes possible a complete description of cell discharge characteristics, using a minimum of experimental data and at the same time pinpointing experimental errors. It can also be used to describe cell charges, capacities, power evolution, and to predict capacities. A description is given of a simple numerical method for fitting this equation to a particular set of battery discharge curves. A graphical method is described for comparing characteristics of various types of cells.

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