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Adsorption of a cationic porphyrin onto mesoporous silicas

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Abstract

The adsorption of a cationic porphyrin, tetrakis-(N-methyl-4-pyridiniumyl)porphine, into mesoporous silicas from solution of tetrakis-(N-methyl-4-pyridiniumyl)porphine p-toluene sulfonate was investigated. Irrespective of the pore size (2.4, 3.5 and 4.2 nm), the cationic porphyrin was adsorbed effectively onto mesoporous silicas to give brown-colored powders. Depending on the amounts adsorbed, which correlate with the average intermolecular distance, the porphines tend to aggregate (dimer).

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Authors and Affiliations

  1. Department of Earth sciences and Graduate School of Science and Engineering, Waseda University, Nishiwaseda 1-6-1, 169-8050, Shinjuku-ku, Tokyo, Japan

    Atsuko Yoshida, Norishige Kakegawa & Makoto Ogawa

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  1. Atsuko Yoshida
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  2. Norishige Kakegawa
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  3. Makoto Ogawa
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Correspondence to Makoto Ogawa.

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Yoshida, A., Kakegawa, N. & Ogawa, M. Adsorption of a cationic porphyrin onto mesoporous silicas. Res. Chem. Intermed. 29, 721–731 (2003). https://doi.org/10.1163/156856703322601735

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  • DOI: https://doi.org/10.1163/156856703322601735

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