Macrocrystal Ordering in Star Polymer Solutions

, and

Published under licence by IOP Publishing Ltd
, , Citation T. A. Witten et al 1986 EPL 2 137 DOI 10.1209/0295-5075/2/2/011

0295-5075/2/2/137

Abstract

We show that a solution of f-armed star polymers develops a peak in its scattering structure function S(q), whose height scales as f3/2. The peak is largest when the separation between neighboring stars is about equal to the radius of a star. Our results follow from general scaling properties of polymers in a good solvent. We predict crystalline ordering of the polymers when the functionality f exceeds a universal threshold fc.

Export citation and abstract BibTeX RIS