Discotic Micellar Nematic and Lamellar Phases under Shear Flow

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Published under licence by IOP Publishing Ltd
, , Citation J. T. Mang et al 1994 EPL 28 489 DOI 10.1209/0295-5075/28/7/006

0295-5075/28/7/489

Abstract

Small-angle neutron scattering was employed to study the effect of shear flow on the nematic (N) and lamellar (Lα) phases in aqueous solutions of cesium perfluoro-octanoate. Shear rates as high as ∼ 4000 s-1 were used. The N phase was found to align with the director in the direction of the gradient velocity. The Lα phase oriented with lamellae parallel to the shear plane. This change in equilibrium orientation is attributed, primarily, to changes in the value of the Ericksen viscosity parameter α2. Subtle shear-rate-dependent director reorientations were also observed in the proximity of the N-to-Lα phase transition.

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10.1209/0295-5075/28/7/006