Six new minor saponins, together with known ginsenosides, were isolated from the leaves of Panax ginseng. The new saponins were named as ginsenoside-Rh₅, -Rh₆, -Rh₇-Rh₈, -Rh₉ and -Rg₇, and their structures were elucidated on the basis of chemical and physicochemical evidence to be as follows: ginsenoside-Rh₅: 3β, 6α, 12β, 24ζ-tetrahydroxy-dammar-20 (22), 25-diene 6-O-β-D-glucopyranoside (1), -Rh₆: 3β, 6α, 12β, 20 (S)-tetrahydroxy-25-hydroperoxy-dammar-23-ene 20-O-β-D-glucopyranoside (2), -Rh₇: 3β, 7β, 12β, 20 (S)-tetrahydroxy-dammar-5, 24-diene 20-O-β-D-glucopyranoside (3), -Rh₈: 3β, 6α, 20 (S)-trihydroxy-dammar-24-ene-12-one 20-O-β-D-glucopyranoside (4), -Rh₉: 3β, 6α, 20 (S)-trihydroxy-12β, 23-epoxy-dammar-24-ene 20-O-β-D-glucopyranoside (5) and -Rg₇: 3-O-β-D-glucopyranosyl 3β, 12β, 20 (S), 24 (R)-tetrahydroxy-dammar-25-ene 20-O-β-D-glucopyranoside (6).