Abstract
Soluble copolyimides based on 2,3,5-tricarboxycyclopentyl acetic dianhydride (TCA-AH)/aromatic tetracarboxilic dianhydrides/diamino diphenyl ether (DDE) were obtained. The maximum incorporation ratios of aromatic dianhydrides depend on flexibility of the dianhydrides. The ratios increase in the order of pyromellitic dianhydride (PMDA) (25 mol%), 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA) (50 mol%) and 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA) (65 mol%). The incorporation of conventional aromatic tetracarboxilic dianhydrides results in improvement of the thermal stability of soluble polyimides based on TCA-AH by the increment of aromatic components in polymer backbone, and the reduction of amount of a special monomer, that is TCA-AH.
Similar content being viewed by others
Article PDF
References
K. L. Mittal, “Polyimides,” Plenum Press, New York, N.Y., 1984.
J. E. McGrath, M. E. Rogers, C. A. Arnold, Y. J. Kim, and J. C. Hedrick, Macromol. Chem., Macromol. Symp., 51, 103 (1991).
S. Z. D. Cheng, F. E. Arnold, Jr., A. Zhang, S. L.-C. Hsu, and F. W. Harris, Macromolecules, 24, 5856 (1991).
F. E. Arnold, Jr., S. Z. D. Cheng, S. L.-C. Hsu, C. J. Lee, F. W. Harris, and S.-F. Lau, Polymer, 33, 5179 (1992).
M. E. Rogers, M. H. Brink, J. E. McGrath, and A. Brennan, Polymer, 34, 849 (1993).
J. W. Park, M. Lee, M.-H. Lee, J. W. Liu, S. D. Kim, J. Y. Chang, and S. B. Rhee, Macromolecules, 27, 3459 (1994).
P. A. Falcigno, S. Jasne, and M. King, J. Polym. Sci., Polym. Chem. Ed., 30, 1433 (1992).
C.-P. Yang and J.-H. Lin, J. Polym. Sci., Polym. Chem. Ed., 32, 423 (1994).
Y. Oishi, M. Ishida, M. Kakimoto, Y. Imai, and T. Kurosaki, J. Polym. Sci., Polym. Chem. Ed., 30, 1027 (1992).
C. A. Arnold, J. D. Summers, Y. P. Chen, R. H. Bott, D. Chen, and J. E. McGrath, Polymer, 30, 986 (1989).
S. Itamura, M. Yamada, S. Tamura, T. Matsumoto, and T. Kurosaki, Macromolecules, 26, 3940 (1993).
M. Yamada, M. Kusama, T. Matsumoto, and T. Kurosaki, Macromolecules, 26, 4961 (1993).
M. Kusama, T. Matsumoto, and T. Kurosaki, Macromolecules, 27, 1117 (1994).
R. G. Bryant, ACS Polym. Prepri., 35, 517 (1994).
Y. Tsuda, Y. Tanaka, K. Kamata, N. Hiyoshi, S. Mataka, Y. Matsuki, M. Nishikawa, S. Kawamura, and N. Bessho, Polym. J., 29, 574 (1997).
Y. Oishi, M. Ishida, H. Takado, M. Yoneyama, M. Kakimoto, and Y. Imai, J. Polym. Sci., Polym. Chem. Ed., 28, 1763 (1990).
V. M. Denisov, V. M. Svetlichnyi, A. Gindin, V. A. Zubkov, A. I. Kol’tsov, M. M. Koton, and V. V. Kudryavtsev, Polym. Sci. USSR, A21, 1644 (1979).
T. Takekoshi, in “Polyimides,” M. K. Ghosh, and K. L. Mittal, Ed., Marcel Dekker, New York, N.Y., 1996, p 10.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Tsuda, Y., Etou, K., Hiyoshi, N. et al. Soluble Copolyimides Based on 2,3,5-Tricarboxycyclopentyl Acetic Dianhydride and Conventional Aromatic Tetracarboxylic Dianhydrides. Polym J 30, 222–228 (1998). https://doi.org/10.1295/polymj.30.222
Issue Date:
DOI: https://doi.org/10.1295/polymj.30.222
Keywords
This article is cited by
-
Structure–property relationships for partially aliphatic polyimides
Journal of Polymer Research (2011)