Abstract
The Mark-Houwink-Sakurada (MHS) relation for polydispersed poly(n-docosyl acrylate) was established from gel permeation chromatography (GPC) and intrinsic viscosity measurements. Average K and α for polydispersed comb-like poly(n-docosyl acrylate) in tetrahydrofuran at 35°C, were 4.95×10−5 dl g−1 and 0.738, respectively. The X-ray diffraction peak of poly(n-docosyl acrylate) at about 2θ=22° corresponded to the typical spacing of hexagonal packing of long alkyl side chains of the acrylate polymer.
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S. D. Baruah, N. C. Laskar, and B. Subrahmanyam, J. Appl. Polym. Sci., 51, 1701 (1994).
K. D. Miller and L. C. Parker, U.S. Patent, 3,675,671 (1972).
Exxon Research and Engineering Co., Ger. Patent, 2,613,315 (1976).
B. Subrahmanyam, S. D. Baruah, M. Rahman, J. N. Baruah, and N. N. Dass, J. Polym. Sci., Polym. Chem., 30, 2531 (1992).
B. Subrahmanyam, S. D. Baruah, M. Rahman, N. C. Laskar, and R. K. Mazumder, Polymer, 35, 862 (1994).
K. Yokota, M. Ohtubo, T. Hirabayashi, and Y. Inai, Polym. J., 25, 1079 (1993).
T. Hirabayashi, K. Kasabou, and K. Yokota, Polym. J., 20, 911 (1988).
K. Yokota and T. Hirabayashi, Polym. J., 18, 117 (1986).
K. Yokota, T. Hirabayashi, and Y. Inai, Polym. J., 26, 105 (1994).
Z. Grubisic, P. Rempp, and H. Benoit, J. Polym. Sci., B, 5, 753 (1967).
C. J. B. Dobbin, A. Rudin, and M. F. Tchir, J. Appl. Polym. Sci., 25, 2985 (1980).
C. J. B. Dobbin, A. Rudin, and M. F. Tchir, J. Appl. Polym. Sci., 27, 1081 (1982).
A. R. Weiss and E. Cohn-Ginsberg, J. Polym. Sci., Polym. Lett. Ed., 7, 379 (1969).
J. M. Goldwasser, A. Rudin, and W. L. Elsdon, J. Liq. Chromatogr., 5, 2253 (1982).
H. K. Mahabadi and L. Alexandru, Can. J. Chem., 63, 221 (1985).
O. F. Solomon and I. Z. Ciuta, J. Appl. Polym. Sci., 6, 683 (1962).
A. K. Chatterjee, S. D. Phatak, P. S. Murthy, and G. C. Joshi, J. Appl. Polym. Sci., 52, 887 (1994).
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Baruah, S., Laskar, N. Relationship between Molecular Weight and Viscosity for Polydispersed Poly(n-docosyl acrylate). Polym J 28, 893–895 (1996). https://doi.org/10.1295/polymj.28.893
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DOI: https://doi.org/10.1295/polymj.28.893