Hostname: page-component-76fb5796d-25wd4 Total loading time: 0 Render date: 2024-04-29T11:38:13.765Z Has data issue: false hasContentIssue false
  • English
  • Français

Rehydration of Zn-Al Layered Double Hydroxides

Published online by Cambridge University Press:  28 February 2024

F. Kooli ,
C. Depège ,
A. Ennaqadi ,
A. de Roy  and
J. P. Besse
F. Kooli
Affiliation:
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom
C. Depège
Affiliation:
Laboratoire de Physico-Chimie des Matériaux, URA CNRS 444, Université Blaise Pascal, 63177 Aubière Cedex, France
A. Ennaqadi
Affiliation:
Laboratoire de Physico-Chimie des Matériaux, URA CNRS 444, Université Blaise Pascal, 63177 Aubière Cedex, France
A. de Roy
Affiliation:
Laboratoire de Physico-Chimie des Matériaux, URA CNRS 444, Université Blaise Pascal, 63177 Aubière Cedex, France
J. P. Besse
Affiliation:
Laboratoire de Physico-Chimie des Matériaux, URA CNRS 444, Université Blaise Pascal, 63177 Aubière Cedex, France
Get access Rights & Permissions [Opens in a new window]

Abstract

Rehydration is shown to be straightforward for the reconstruction of polyoxometallate-pillared layered double hydroxides. Zn-Al hydrotalcite-like minerals were prepared with Zn/Al ratios of 1 to 5 by coprecipitation at pH 7. Good crystallinity was obtained for samples with Zn/Al ratios above 2. Thermal decomposition was achieved by calcining the samples at 300 to 900 °C. The calcined samples were exposed to decarbonated water, with or without hydrothermal treatment to evaluate reconstruction of the hydrotalcite-like minerals by rehydration. Restoration of the hydrotalcite-like structure was found to be independent of the Zn/Al ratios for samples calcined between 300 and 400 °C; however, asecond phase, aluminum hydroxide or zinc oxide, was generally detected. A spinel phase, formed during the calcination of samples at temperatures above 600 °C, inhibited reconstruction of the hydrotalcite-like phase. The rehydrated hydrotalcite-like minerals had Zn/Al ratios close to 2, irrespective of the chemistry of the starting material.

Keywords

HydrotalciteHydrothermal TreatmentLayered Double HydroxideReconstruction
Type
Research Article
Information
Clays and Clay Minerals , Volume 45 , Issue 1 , February 1997 , pp. 92 - 98
Copyright
Copyright © 1997, The Clay Minerals Society

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Bish, D.L. and Brindley, G.W.. 1977. A reinvestigation of takovite, a nickel aluminium hydroxy-carbonate of the pyroaurite group. Am Mineral 62: 458–464.Google Scholar
Brindley, W. and Kikkawa, W.. 1979. A crystal-chemical study of Mg,Al and Ni,Al hydroxy-perchlorates and hydroxy-carbonates. Am Mineral 64: 836–843.Google Scholar
Cavani, F., Trifiro, F. and Vaccari, A.. 1991. Hydrotalcite-type anionic clays: Preparation, properties and applications. Catal Today 11: 173–291.CrossRefGoogle Scholar
Chibwe, K. and Jones, W.. 1989. Intercalation of organic and inorganic anions into layered double hydroxides. J Chem Soc, Chem Commun 926–927.Google Scholar
Chibwe, M. and Pinnavaia, T.J.. 1993. Stabilization of a cobalt (II) phthalocyanine oxidation catalyst by intercalation in a layered double hydroxide host. J Chem Soc, Chem Commun 278–280.Google Scholar
Clause, O., Rebours, B., Merlen, E., Trifiro, F. and Vaccari, A.. 1992. Preparation and characterization of nickel-aluminium mixed oxides obtained by thermal decomposition of hydrotalcite-type precursors. J Catal 133: 231–246.CrossRefGoogle Scholar
Courty, P. and Marcilly, C.. 1983. A scientific approach to the preparation of bulk mixed oxide catalysts. In: Poncelet, G., Grange, P., Jacobs, P.A., editors. Preparation of catalysts III. Amsterdam: Elsevier Science. p 485–517.Google Scholar
de Roy, A. and Besse, J.P.. 1991. Evolution of protonic conduction in some synthetic anionic clays. Solid State Ionics 46: 95–101.CrossRefGoogle Scholar
de Roy, A., Forano, C., El Malki, K. and Besse, J.P.. 1992. Anionic clays: Trends in pillaring chemistry. In: Occelli, M.I., Robson, H.E., editors. Synthesis of microporous materials, vol 2. New York: Van Nostrand Reinhold. p 108–168.Google Scholar
Dupuis, J., Battut, J.P., Fawal, Z., Hajjimohamad, H., de Roy, A. and Besse, J.P.. 1990. Nuclear magnetic resonance of protons in the hydrotalcite-like compound Zn2/3Al1/3(OH)2Cl1/3.nH2O. Solid State Ionics 42: 251–255.CrossRefGoogle Scholar
El Malki, K.. 1991. Synthèse et caractérisation de nouveaux hydroxydes doubles lamellaires. Etude des échanges anioniques et de la réticulation. Etude des propriétés électriques et magnétiques [Ph. D. thesis]. Aubiere, France: Université Blaise Pascal. 337 p.Google Scholar
Gastuche, M.C., Brown, G. and Mortland, M.M.. 1967. Mixed Mg-Al hydroxides—I: Preparation and characterization of compounds. Clays Clay Miner 7: 177–192.CrossRefGoogle Scholar
Hernandez-Moreno, M.J., Ulibarri, M.A., Rendon, J.L. and Serna, C.J.. 1985. IR characteristics of hydrotalcite-like compounds. Phys Chem Miner 12: 34–38.CrossRefGoogle Scholar
Kooli, F., Kosuge, K., Hibino, T. and Tsunashima, A.. 1993. Synthesis and properties of Mg-Zn-Al-SO4 hydrotalcite-like compounds. J Mater Sci 28: 2769–2773.CrossRefGoogle Scholar
Kooli, F., Ulibarri, M.A. and Rives, V.. 1994. Vanadate-pillared hydrotalcite containing transition metal cations. Mater Sci Forum 152: 375–378.CrossRefGoogle Scholar
Kooli, F., Ulibarri, M.A. and Rives, V.. 1995. Preparation and study of decavanadate-pillared hydrotalcite-like anionic clays containing transition metal cations in the layers. 1. Samples containing nickel-aluminum prepared by anionic exchange and reconstruction. Inorg Chem 34: 5114–5121.CrossRefGoogle Scholar
Kopka, H., Beneke, K. and Lagaly, G.. 1988. Anionic surfactants between double metal hydroxide layers. J Colloid Interface Sci 123: 427–436.CrossRefGoogle Scholar
Martin, K.J. and Pinnavaia, T.J.. 1986. Halide ion reactivity in layered double hydroxides as supported anionic reagents. J Am Chem Soc 108: 541–542.CrossRefGoogle ScholarPubMed
Michalowicz, A.. 1991. Logiciels pour la chimie. Paris: Société Française de Chimie. p 102–103.Google Scholar
Miyata, S.. 1975. The synthesis of hydrotalcite-like compounds and their structures and physico-chemical properties—I: The systems Mg2+–Al3+-NO3–, Mg2+ –Al3+-Cl–, Mg2+-Al3+-ClO4–, Ni2+–Al3+–Cl– and Zn2+–Al3+–Cl–. Clays Clay Miner 23: 369–375.CrossRefGoogle Scholar
Miyata, S.. 1980. Physico-chemical properties of synthetic hydrotalcites in relation to composition. Clays Clay Miner 28: 50–56.CrossRefGoogle Scholar
Miyata, S.. 1983. Anionic exchange properties of hydrotalcite-like compounds. Clays Clay Miner 31: 305–311.CrossRefGoogle Scholar
Rebours, B., d'Espinose de la Caillerie, J.P. and Clause, O.. 1994. Decoration of nickel and magnesium oxide crystallites with spinel-type phases. J Am Chem Soc 116: 1707–1717.CrossRefGoogle Scholar
Reichle, W.T.. 1985. Catalytic reactions by thermally activated synthetic anionic clay minerals. J Catal 94: 547–557.CrossRefGoogle Scholar
Rey, F., Fornés, V. and Rojo, J.M.. 1992. Thermal decomposition of hydrotalcites. An infrared and nuclear magnetic resonance spectroscopic study. J Chem Soc, Faraday Trans 88: 2233–2238.CrossRefGoogle Scholar
Sato, T., Fujita, H., Endo, T., Shimada, M. and Tsunashima, A.. 1988. Synthesis of hydrotalcite-like compounds and their physico-chemical properties. React Solids 5: 219–228.CrossRefGoogle Scholar
Sato, T., Tezuka, M., Endo, T. and Shimada, M.. 1987. Removal of sulfuroxyanions by magnesium aluminum oxides and their thermal decomposition. J Chem Technol Biotechnol 39: 275–285.CrossRefGoogle Scholar
Sato, T., Wakabayashi, T. and Shimada, M.. 1986. Adsorption of various anions by magnesium aluminum oxide (Mg0.7AI0.3O1.15). Ind Eng Chem Res 25: 89–92.CrossRefGoogle Scholar
Shannon, R.D. and Prewitt, C.T.. 1969. Table of effective ionic radii. Acta Crystallogr B25: 925–946.Google Scholar
Suzuki, E., Okamoto, M. and Ono, Y.. 1989. Catalysis by interlayer anions of a synthetic hydrotalcite-like mineral in a halide exchange between organic halides. Chem Lett 1485–1486.CrossRefGoogle Scholar