Performance evaluation criteria for preparation and measurement of macro- and microfabricated ion-selective electrodes (IUPAC Technical Report)

Ernö Lindner; Yoshio Umezawa

doi:10.1351/pac200880010085

Publicly Available Published by De Gruyter January 1, 2009

Performance evaluation criteria for preparation and measurement of macro- and microfabricated ion-selective electrodes (IUPAC Technical Report)

Ernö Lindner and Yoshio Umezawa

From the journal Pure and Applied Chemistry

https://doi.org/10.1351/pac200880010085

Abstract

Over the last 30 years, IUPAC published several documents with the goal of achieving standardized nomenclature and methodology for potentiometric ion-selective electrodes (ISEs). The ISE vocabulary was formulated, measurement protocols were suggested, and the selectivity coefficients were compiled. However, in light of new discoveries and experimental possibilities in the field of ISEs, some of the IUPAC recommendations have become outdated. The goal of this technical report is to direct attention to ISE practices and the striking need for updated or refined IUPAC recommendations which are consistent with the state of the art of using macro- and microfabricated planar microelectrodes. Some of these ISE practices have never been addressed by IUPAC but have gained importance with the technological and theoretical developments of recent years. In spite of its recognized importance, a generally acceptable revision of the current IUPAC recommendations is far beyond the scope of this work.

Keywords: ion-selective electrodes; ISEs; IUPAC Analytical Chemistry Division; microfabricated; nanomolar; picomolar; potentiometry

Project Year: 2002, Project Code: 2002-003-2-500

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Published Online: 2009-01-01

Published in Print: 2008-01-01

Performance evaluation criteria for preparation and measurement of macro- and microfabricated ion-selective electrodes (IUPAC Technical Report)

Abstract

References

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