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Development of Thiol-Functionalized Mesoporous Silicate MCM-41 as a Modified Sorbent and Its Use in Chromatographic Separation of Metal Ions from Aqueous Nuclear Waste

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Abstract

Surface modified adsorbent mesoporous silicate MCM-41 has been prepared by grafting thiol containing functional group onto mesoporous silicate MCM-41. XRD, N2 adsorption/desorption measurements, SEM, FT-IR, thermogravimetry and elemental analysis have been made to confirm the ordered mesoporous framework and the functionalization of the thiol groups. Sorption of 18 metal ions on this sorbent have been studied and discussed. Chromatographic separation of Rb(I)–U(VI)–Sr(II)–Zr(IV), has been achieved on column of this sorbent.

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Acknowledgements

The authors are thankful to the staff of Jaber Ibn Hayan Laboratories for providing research facilities.

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Authors and Affiliations

  1. Jaber Ibn Hayan Research Laboratories, Nuclear Science and Technology Research Institute, AEOI, P.O. Box 11365/8486, Tehran, Iran

    Hamid Sepehrian & Mohammad Ghannadi-Maragheh

  2. Department of Chemistry, Faculty of Science, Science and Research Branch, Islamic Azad University, P.O. Box 14515-775, Poonak-Hesarak, Tehran, Iran

    Syed Waqif-Husain

Authors
  1. Hamid Sepehrian
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  2. Syed Waqif-Husain
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  3. Mohammad Ghannadi-Maragheh
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Correspondence to Syed Waqif-Husain.

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Sepehrian, H., Waqif-Husain, S. & Ghannadi-Maragheh, M. Development of Thiol-Functionalized Mesoporous Silicate MCM-41 as a Modified Sorbent and Its Use in Chromatographic Separation of Metal Ions from Aqueous Nuclear Waste. Chroma 70, 277–280 (2009). https://doi.org/10.1365/s10337-009-1133-9

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