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Comparison of aspen wood hydrolysates produced by pretreatment with liquid hot water and carbonic acid

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Abstract

Hydrolysates produced by the pretreatment of aspen wood with liquid hot water were compared with hydrolysates produced using carbonic acid pretreatment. Pretreatment temperatures tested ranged from 180° to 220°C; reaction times were varied between 2.5 and 30.5 min. Under most conditions tested, it was found that the presence of carbonic acid had no discernible effect on the amount of xylose released or concentration of furan compounds, as indicated by ultraviolet-visual absorbance between 270 and 280 nm. Thus, there appears to be little difference in the severity of the pretreatment conditions with or without the presence of carbonic acid. The presence of carbonic acid did, however, result in a hydrolysate with a higher final pH. It is hypothesized that the presence of the carbonic acid during the reaction may have the effect of reducing the accumulation of organic acids in the hydrolysate.

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References

  1. Holtzapple, M. T. (1993), in Hemicellulose, Encyclopedia of Food Science, Food Technology, and Nutrition, vol. 4, Macrae, R., Robinson, R. K., and Sadler, M. J., eds., Academic Press, London, San Diego, CA, NY, Boston, MA, Sydney, Tokyo, Toronto, pp. 2324–2334.

    Google Scholar 

  2. Holtzapple, M. T. (1993), in Lignin, Encyclopedia of Food Science, Food Technology, and Nutrition, vol. 4, Macrae, R., Robinson, R. K., and Sadler, M. J., eds., Academic Press, London, San Diego, CA, NY, Boston, MA, Sydney, Tokyo, Toronto, pp. 2731–2738.

    Google Scholar 

  3. Holtzapple, M. T. (1993), in Cellulose, Encyclopedia of Food Science, Food Technology, and Nutrition, vol. 2, Macrae, R., Robinson, R. K., and Sadler, M. J., eds., Academic Press, London, San Diego, CA, NY, Boston, MA, Sydney, Tokyo, Toronto, pp. 758–767.

    Google Scholar 

  4. McMillan, J. D. (1994), ACS Symp. Ser. 566, 292–324.

    CAS  Google Scholar 

  5. Quang, A. N., Tucker, M. P., Keller, F. A., and Eddy, F. P. (2000), Appl. Biochem. Biotechnol. 84–86, 561–576.

    Google Scholar 

  6. Boussaid, A., Esteghlalian, A. R., Gregg, D. J., Lee, K. H., and Saddler, J. N. (2000), Appl. Biochem. Biotechnol. 84–86, 693–705.

    Article  Google Scholar 

  7. Bouchard, J., Lacelle, S., Chornet, E., Vidal, P. F., and Overend, R. P. (1993), Holzforschung 47(4), 291–296.

    CAS  Google Scholar 

  8. Dale, B. E., Weaver, J., and Byers, F. M. (1999), Appl. Biochem. Biotechnol. 77–70, 35–45.

    Article  Google Scholar 

  9. Weil, J. R., Sarikaya, A., Rau, S., Goetz, J., Ladisch, C. M., Brewer, M., Hendrickson, R., and Ladisch, M. R. (1998), Appl. Biotechnol. Bioeng. 73, 1–17.

    CAS  Google Scholar 

  10. Ritter, D. C. and Campbell, A. G. (1987), Biotechnol. Bioeng. Symp. 17, 179–182.

    Google Scholar 

  11. van Walsum, G.P. (2001), Appl. Biochem. Biotechnol. 91–93, 317–329.

    Article  Google Scholar 

  12. van Walsum, G. P., Allen, S. G., Spencer, M. J., Laser, M. S., Antal, M. J., and Lynd, L. R. (1996), Appl. Biochem. Biotechnol. 54/55, 157–170.

    Google Scholar 

  13. Heitz, M., Capek-Menard, E., Koeberle, P. G., Gagne, J., Chornet, E., Overend, R. P., Taylor, J. D., and Yu, E. (1991), Bioresour. Technol. 35, 23–32.

    Article  CAS  Google Scholar 

  14. US Department of Energy (1993) Technical Report Eleven: Evaluation of a Potential Wood-to-Ethanol Process, US Department of Energy, Golden, CO.

    Google Scholar 

  15. Puri, V. P. and Mamers, H. (1983), Biotechnol. Bioeng. 25, 3149–3161.

    Article  CAS  Google Scholar 

  16. Martinez, A., Rodriguez, M. E., York, S. W., Preston, J. F., and Ingram, L. O. (2000), Biotechnol. Prog. 16, 637–641.

    Article  CAS  Google Scholar 

  17. Overend, R. P. and Chornet, E. (1987) Phiols. Trans. R. Soc. Lond. A321, 523–536.

    Article  Google Scholar 

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Correspondence to G. Peter van Walsum.

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McWilliams, R.C., van Walsum, G.P. Comparison of aspen wood hydrolysates produced by pretreatment with liquid hot water and carbonic acid. Appl Biochem Biotechnol 98, 109–121 (2002). https://doi.org/10.1385/ABAB:98-100:1-9:109

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