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Laser-Induced Decomposition of 2,2',4,4',6,6'-Hexanitrostillbene at 263, 527 and 1053 nm
Corresponding Author(s) : Tao Xu
Asian Journal of Chemistry,
Vol. 25 No. 8 (2013): Vol 25 Issue 8
Abstract
Investigation on laser-induced decomposition will provide important information for a better understanding of detonation mechanism of energetic materials. The effects of laser irradiation on 2,2',4,4',6,6'-hexanitrostillbene at different laser wavelengths has been studied by XPS and FT-IR. Results showed photodecomposition mechanism of 2,2',4,4',6,6'-hexanitrostillbene is wavelength-dependent. In case of 263 and 527 nm irradiated, the nitro-nitrite isomerization and the fragmentation of trans-C=C bond are the main decomposition steps, while in the case of 1053 nm, only the fragmentation of trans-C=C bond was observed.
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- X.Y. Shu, Y. Tian, G.B. Song, H.B. Zhang, B. Kang, C.Y. Zhang, Y. Liu, X.F. Liu and J. Sun, J. Mater. Sci., 46, 2536 (2011).
- H. Gifers and M. Pravica, J. Phys. Chem. A, 112, 3352 (2008).
- Bhattacharya, Y.Q. Guo and E.R. Bernstein, J. Phys. Chem. A, 113, 811 (2009).
- Y.G. Lazarou and P. Papagiannakopoulos, J. Phys. Chem., 94, 7114 (1990).
- M.J. McQuaid, A.W. Miziolek and R.C. Sausa, J. Phys. Chem., 95, 2713 (1991).
- D. L. Williams, J. C. Timmons, J. D. Woodyard, K. A. Rainwater, J. M. Lightfoot, B. R. Richardson, C. E. Burgess, and J. K. Heh, J. Phys.Chem. A, 107, 9491 (2003).
- J. Sharma, W.L. Garrett, F.J. Owens and V.L. Vogel, J. Phys. Chem., 86, 1657 (1982).
- D. Britt, W.B. Moniz, G.C. Chingas, D.W. Moore, C.A. Heller and C.L. Ko, Prop. Explos. Pyrotechnol., 6, 94 (1981).
- J.W. Mconald, T. Schenkel and M.W. Newman, J. Energ. Mater., 19, 101 (2001).
- E.A. Glascoe, J.M. Zaug, M.R. Armstrong, J.C. Crowhurst, Christian D. Grant and Laurence E. Fried, J. Phys. Chem. A, 113, 5881 (2009).
- H.S. lm and E.R. Bernstein, J. Chem. Phys., 113, 7911 (2000).
- Y.Q. Guo, M. Greenfield and E.R. Bernnstein, J. Chem. Phys., 122, 244310 (2005).
- M. Greenfield, E.R. Bernnstein and Y.Q. Guo, Chem. Phys. Lett, 430, 277 (2006).
- Y.Q. Guo, M. Greenfield, A. Bhattacharya and E.R. Bernnstein, J. Chem. Phys., 127, 154301 (2007).
- M.D. Pace, Mol. Cryst. Liq. Cryst., 156, 167 (1988).
- J. Hawari, S. Deschamps, C. Beaulieu, L. Paquent and A. Halasz, Water Res., 38, 4055 (2004).
- M.D. Pace and A.J. Carmichael, J. Phys. Chem., 101, 1848 (1997).
- N.L. Garland, H.D. Ladouceur and H.H. Nelson, J. Phys. Chem. A, 101, 8508 (1997).
- A.B. Kunz, M.M. Kuklja, T.R. Botcher and T.P. Russell, Thermochim. Acta, 384, 279 (2002)
References
X.Y. Shu, Y. Tian, G.B. Song, H.B. Zhang, B. Kang, C.Y. Zhang, Y. Liu, X.F. Liu and J. Sun, J. Mater. Sci., 46, 2536 (2011).
H. Gifers and M. Pravica, J. Phys. Chem. A, 112, 3352 (2008).
Bhattacharya, Y.Q. Guo and E.R. Bernstein, J. Phys. Chem. A, 113, 811 (2009).
Y.G. Lazarou and P. Papagiannakopoulos, J. Phys. Chem., 94, 7114 (1990).
M.J. McQuaid, A.W. Miziolek and R.C. Sausa, J. Phys. Chem., 95, 2713 (1991).
D. L. Williams, J. C. Timmons, J. D. Woodyard, K. A. Rainwater, J. M. Lightfoot, B. R. Richardson, C. E. Burgess, and J. K. Heh, J. Phys.Chem. A, 107, 9491 (2003).
J. Sharma, W.L. Garrett, F.J. Owens and V.L. Vogel, J. Phys. Chem., 86, 1657 (1982).
D. Britt, W.B. Moniz, G.C. Chingas, D.W. Moore, C.A. Heller and C.L. Ko, Prop. Explos. Pyrotechnol., 6, 94 (1981).
J.W. Mconald, T. Schenkel and M.W. Newman, J. Energ. Mater., 19, 101 (2001).
E.A. Glascoe, J.M. Zaug, M.R. Armstrong, J.C. Crowhurst, Christian D. Grant and Laurence E. Fried, J. Phys. Chem. A, 113, 5881 (2009).
H.S. lm and E.R. Bernstein, J. Chem. Phys., 113, 7911 (2000).
Y.Q. Guo, M. Greenfield and E.R. Bernnstein, J. Chem. Phys., 122, 244310 (2005).
M. Greenfield, E.R. Bernnstein and Y.Q. Guo, Chem. Phys. Lett, 430, 277 (2006).
Y.Q. Guo, M. Greenfield, A. Bhattacharya and E.R. Bernnstein, J. Chem. Phys., 127, 154301 (2007).
M.D. Pace, Mol. Cryst. Liq. Cryst., 156, 167 (1988).
J. Hawari, S. Deschamps, C. Beaulieu, L. Paquent and A. Halasz, Water Res., 38, 4055 (2004).
M.D. Pace and A.J. Carmichael, J. Phys. Chem., 101, 1848 (1997).
N.L. Garland, H.D. Ladouceur and H.H. Nelson, J. Phys. Chem. A, 101, 8508 (1997).
A.B. Kunz, M.M. Kuklja, T.R. Botcher and T.P. Russell, Thermochim. Acta, 384, 279 (2002)