Nowy sposób sieciowania żywicy epoksydowej wykorzystujący bis(heptafenyloglinosilseskwioksan) jako utwardzacz

D. Chmielewska; M. Barczewski; T. Sterzyński

Published : 2013-04-30

Vol. 58 No. 4 (2013)

A new method of curing epoxy resin by using bis(heptaphenylaluminosilsesquioxane) as a hardener

D. Chmielewska M. Barczewski T. Sterzyński

Abstract

The curing process of epoxy resin Epidian 6 with bis(heptaphenylaluminosilsesquioxane) was studied. The curing conditions for the defined compositions were established on the basis of measurements made during the crosslinking reaction. Differential scanning calorimetry (DSC) was used to determine the temperature of the exothermal reaction related to the course of the curing process. Also, the temperature of crosslinking process and gel time at ambient temperature were determined. The homogeneity of the distribution of POSS additives in the epoxy matrix was investigated using microscopic analysis (SEM). Fourier transform infrared (FT-IR) spectroscopy was used to evaluate the chemical changes in the resin. It was shown that bis(heptaphenylaluminosilsesquioxane) can be applied as a curing agent for epoxy resins, with the main advantages of a low curing temperature and long life time.

Keywords

żywica epoksydowa ; POSS ; analiza termiczna ; sieciowanie epoxy resin ; POSS ; thermal analysis ; crosslinkings

Details

References

Statistics

Authors

Download files

PDF (Język Polski)

Zasady cytowania

Chmielewska, D., Barczewski, M., & Sterzyński, T. (2013). A new method of curing epoxy resin by using bis(heptaphenylaluminosilsesquioxane) as a hardener. Polimery, 58(4), 270-275. Retrieved from http://polimery.ichp.vot.pl/index.php/p/article/view/732

References

Czub P., Penczek P., Boñcza-Tomaszewski Z., Pielichowski J.: „Chemia i technologia żywic epoksydowych”, WNT, Warszawa 2002, str. 17—25.

2. Maka H., Spychaj T., Pilawka R.: Ind. Eng. Chem. Res. 2012, 51, 5197.

3. Czub P.: Polimery 2008, 53, 182.

4. Pat. PL 53 276 (1967).

5. Cho H., Liang K., Chatterjee S., Pittman Jr. C. U.: J. Inorg. Organomet. Polym. 2005, 15, 541.

6. Pielichowski K., Njuguna J., Janowski B., Pielichowski J.: Adv. Polym. Sci. 2006, 201, 225.

7. Hao W., Hu J., Chen L., Zhang J., Xing L., Yang W.: Polym. Test. 2011, 30, 355.

8. Liu H., Zheng S., Nie K.: Macromolecules 2005, 38, 5088.

9. Ni Y., Zheng S., Nie K.: Polymer 2004, 45, 5557.

10. Murias P., Maciejewski H., Galina H.: Eur. Polym. J. 2012, 48, 769.

11. Matìjka L., Murias P., Pleštil J.: Eur. Polym. J. 2012, 48, 260.

12. Chen G.-X., Si L., Lu P., Li Q.: J. Appl. Polym. Sci. 2012, 125, 3929.

13. Zhang Z., Liang G., Wang X.: Polym. Bull. 2007, 58, 1013.

14. Lin P.-H., Khare R.: Macromolecules 2009, 42, 4319.

15. Rashid E. S. A., Ariffin K., Kooi C. C., Akil H. M.: Mater. Design. 2009, 30, 1.

16. Franchini E., Galy J., Gerard J.-F., Tabuani D., Medici A.: Polym. Degrad. Stab. 2009, 94, 1728.

17. Liu Y., Zheng S., Nie K.: Polymer 2005, 46, 12 016.

18. Urbaniak M.: Polimery 2011, 56, 240.

19. Zgłosz. pat. P-398 899 (2012).

20. Fina A., Tabuani D., Carniato F., Frache A., Boccaleri E., Camino G.: Thermochim. Acta 2006, 440, 36.

21. Nikolic G., Zlatkovic S., Cakic Z., Cakic S., Lacnjevac C., Rajic Z.: Sensors 2010, 10, 684.

22. Fu B. X., Namani M., Lee A.: Polymer 2003, 44, 7739.

Google Scholar

Citing articles via

Statistics

Total abstract views : 98

PDF Downloads : 165