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Licensed Unlicensed Requires Authentication Published by De Gruyter (O) June 29, 2020

Shock wave induced defect engineering on structural and optical properties of pure and dye doped potassium dihydrogen phosphate crystals

  • Sivakumar Aswathappa , Eniya Palaniyasan , Sahaya Jude Dhas Sathiyadhas , Kalyana Sundar Jayaperumal , Sivaprakash Paramasivam , Arumugam Sonachalam and Martin Britto Dhas Sathiyadhas Amalapushpam EMAIL logo

Abstract

Based on the importance of the shock recovery experiments, the authors report the structural and optical properties of pure and 0.001 M dye-doped potassium dihydrogen phosphate (KDP) crystals for virgin and shock wave loaded samples. Rhodamine B and Methylene blue dyes are selected as dopants to be doped with KDP crystal for the present investigation. The test crystals of pure and doped KDP crystals are grown by slow evaporation technique and cut and polished crystals of (200) face are used for the present investigation. Table-top pressure driven shock tube is utilized for the shock wave generation and the used functional Mach number is 1.7. Virgin and shock wave loaded test crystals’ surface morphology, structural properties and optical transmissions are observed using optical microscope, powder X-ray diffractometer and UV-Visible spectrometer, respectively. Crystalline nature and optical transmission of pure and doped KDP crystals are found to have reduced by the impact of shock waves. It occurs due to the enhancement of defect concentration on the surface of the test crystals. From the observed results, we assert that the pure KDP crystal is relatively more stable to shock wave induced damage compared to doped KDP crystals as reflected by structural and optical studies.


Corresponding author: Martin Britto Dhas Sathiyadhas Amalapushpam, Department of Physics, Abdul Kalam Research Center, Sacred Heart College, Tirupattur, Vellore, 635601, Tamil Nadu, India, E-mail:

Award Identifier / Grant number: SR/FST/College-2017/130 (c)

Acknowledgment

The authors thank Department of Science and Technology (DST), India for funding through DST-FIST programme (SR/FST/College-2017/130 (c)).

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: The authors thank Department of Science and Technology (DST), India for funding through DST-FIST programme (SR/FST/College-2017/130 (c)).

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-02-18
Accepted: 2020-04-27
Published Online: 2020-06-29
Published in Print: 2020-07-28

© 2020 Walter de Gruyter GmbH, Berlin/Boston

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