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Licensed Unlicensed Requires Authentication Published by De Gruyter March 15, 2014

Combustion behavior of oak wood (Quercus mongolica L.) modified by 1,3-dimethylol-4,5-dihydroxyethyleneurea (DMDHEU)

  • Yanjun Xie EMAIL logo , Na Liu , Qingwen Wang , Zefang Xiao , Fengqiang Wang , Yanhua Zhang and Holger Militz
From the journal Holzforschung

Abstract

The modification of wood with 1,3-dimethylol-4,5-dihydroxyethyleneurea (DMDHEU) is an efficient strategy to improve its dimensional stability and durability during its service period. In this study, oak wood (Quercus mongolica L.) was treated with DMDHEU and the combustion behavior of the treated wood was examined. The bench-scale thermogravimetry and cone calorimetry showed that the treatment with DMDHEU alone enhanced the flammability of wood, but a combined treatment with DMDHEU and traces of magnesium chloride as a catalyst lowered the flammability to the level of untreated wood. In full-scale fire tests for flooring materials, it could be confirmed that both the untreated and treated woods have similar combustion behavior and can be classified as Dfl-S1 (capable of resisting a small flame and, for a certain period, a heat flux attack; the total smoke production is limited). Accordingly, further fire-retardant treatments may be required if DMDHEU-treated wood is used in public areas.


Corresponding author: Yanjun Xie, Key Laboratory of Bio-based Material Science and Technology (Ministry of Education), College of Material Science and Engineering, Northeast Forestry University, 150040, Hexing Road, Harbin, P.R. China, Phone: +86 451 8219 1002, Fax: +86 451 8219 1002, e-mail:

Acknowledgments

The authors are grateful to the support from the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-11-0608) and the Fundamental Research Funds for the Central Universities (DL12DB02). The Young Prominent Talent Support Program of Northeast Forestry University (PTSP-1213-03) is also acknowledged.

References

Browne, F.L. Theories of the combustion of wood and its control. Research report of the Forest Producs Laboratory, No. FPL-2136. 1958.Search in Google Scholar

Hedberg, E., Kristensson, A., Ohlsson, M., Johansson, C., Johanssond, P.-A., Swietlicki, E., Vesely, V., Wideqvist, U., Westerholm, R. (2002) Chemical and physical characterization of emissions from birch wood combustion in a wood stove. Atmos. Environ. 36:4823–4837.Search in Google Scholar

Heskestad, W.A., Hovde, P.J. (1994) Assessment of smoke production from building products. In: Fire Saftety Science. Proceedings of the Fourth International Symposium, Ottawa, Canada. T. Kashiwagi, T., pp. 527–538.10.3801/IAFSS.FSS.4-527Search in Google Scholar

Hill, C.A.S. Wood Modification: Chemical, Thermal and Other Processes. John Wiley & Sons, Ltd., Chichester, 2006.10.1002/0470021748Search in Google Scholar

Hirata, T., Kawamoto, S., Nishimoto, T. (1991) Thermogravimetry of wood treated with water-insoluble retardants and a proposal for wood. Fire Mater. 15:27–36.10.1002/fam.810150106Search in Google Scholar

Hoydonckx, H.E., Van Rhijn, W.M., Van Rhijn, W., Hueting, D., Tjeerdsma, B., van der Zee, M., Van Acker, J. (2007) Renewable furfuryl resin technology for wood modification. In: The Third European Conference on Wood Modification, Eds. Hill, C.A.S. et al. Cardiff, UK. pp. 81–86.Search in Google Scholar

Krause, A., Jones, D., Van der Zee, M., Militz, H. (2003) Interlace treatment – wood modification with N-methylol compounds. In: The First European Conference on Wood Modification. Eds. Van Acker, J., Hill, C.A.S. Ghent, Belgium. pp. 317–327.Search in Google Scholar

Krause, A., Wepner, F., Xie, Y., Militz, H. (2008) Wood protection with dimethylodihydroxy-ethyleneurea and its derivatives. In: Development of Commercial Wood Preservatives: Efficacy, Environmental, and Health Issues. Eds. Schultz, T.P. et al. ACS Symposium Series; American Chemical Society, Washington, DC. pp. 356–371.10.1021/bk-2008-0982.ch021Search in Google Scholar

Marney, D.C.O., Russell, L.J., Mann, R. (2008) Fire performance of wood (Pinus radiata) treated with fire retardants and a wood preservative. Fire Mater. 32:357–370.10.1002/fam.973Search in Google Scholar

Militz, H. (1993) Treatment of timber with water soluble dimethylol resins to improve their dimensional stability and durability. Wood Sci. Technol. 27:347–355.Search in Google Scholar

Papadopoulos, A.N., Pougioula, G. (2010) Mechanical behaviour of pine wood chemically modified with a homologous series of linear chain carboxylic acid anhydrides. Bioresour. Technol. 101:6147–6150.Search in Google Scholar

Plackett, D.V., Dunningham, E.A., Singh, A.P. (1992) Weathering of chemically modified wood: accelerated weathering of acetylated radiata pine. Eur. J. Wood Prod. 50:135–140.10.1007/BF02663254Search in Google Scholar

Ragland, K.W., Aerts, D.J., Baker, A.J. (1991) Properties of wood for combustion analysis. Bioresour. Technol. 37:161–168.Search in Google Scholar

Schuyten, H.A., Weaver J.W., Reid J.D. (1955) Effect of flameproofing agents on cotton cellulose. Ind. Eng. Chem. 47:1433–1439.Search in Google Scholar

Tang, W.K., Neill, W.K. (1964) Effect of flame retardants on pyrolysis and combustion of α-cellulose. J. Polym. Sci. Polym. Lett. 6:65–81.Search in Google Scholar

Verma, P., Dyckmans, J., Militz, H., Mai, C. (2008) Determination of fungal activity in modified wood by means of micro-calorimetry and determination of total esterase activity. Appl. Microbiol. Biot. 80:125–133.Search in Google Scholar

Wang, Q., Li, J., Winandy, J. (2004) Chemical mechanism of fire retardance of boric acid on wood. Wood Sci. Technol. 38:375–389.Search in Google Scholar

Xie, Y., Krause, A., Mai, C., Militz, H., Richter, K., Urban, K., Evans, P.D. (2005) Weathering of wood modified with the N-methylol compound 1,3-dimethylol-4,5-dihydroxyethyleneurea. Polym. Degrad. Stabil. 89:189–199.10.1016/j.polymdegradstab.2004.08.017Search in Google Scholar

Xie, Y., Krause, A., Militz, H., Mai, C. (2008) Weathering of uncoated and coated wood treated with methylated 1,3-dimethylol-4,5-dihydroxyethyleneurea (mDMDHEU). Eur. J. Wood Prod. 66:455–464.10.1007/s00107-008-0270-4Search in Google Scholar

Yasuda, R., Minato, K., Norimoto, M. (1994) Chemical modification of wood by non-formaldehyde cross-linking reagents. Part 2. Moisture adsorption and creep properties. Wood Sci. Technol. 28:209–218.Search in Google Scholar

Received: 2013-11-24
Accepted: 2014-2-24
Published Online: 2014-3-15
Published in Print: 2014-12-1

©2014 by De Gruyter

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