Abstract
The partial Gibbs energies of zinc in the liquid Cu– In–Zn system as a function of temperature and concentration were measured in the temperature range between the melting points of the alloys and 1073 K using an EMF method with a liquid electrolyte. The thermodynamic properties were determined for 30 alloys at three different constant ratios of Cu : In of 1 : 2, 1 : 1, and 2 : 1 with zinc added in the concentration range between 5 and 90 at.%. The integral Gibbs free energy and the integral enthalpy of mixing of the ternary system were calculated with the Gibbs Duhem equation.
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This investigation is a contribution to the European COST 531 on “Lead-free Solder Materials” Financial support of the Austrian Science Foundation (FWF, Project Nr. P 16491-N11) is gratefully acknowledged.
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