Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter August 3, 2016

Attributes of natural and synthetic materials pertaining to slow-release urea coating industry

  • Muhammad Yasin Naz

    Muhammad Yasin Naz is working as a research scientist with the director of Hybrid Energy Systems (HES) research at the Universiti Teknologi PETRONAS (UTP), Malaysia. He holds a MPhil degree in Plasma Physics from Quaid-i-Azam University, Islamabad, Pakistan, and a doctorate degree from UTP dealing with atomization of non-Newtonian fluids. From 2009 to 2012, he worked as a lecturer in physics at the University of Agriculture Faisalabad, Pakistan. With a very diverse research background, he has contributed to scholarly works on atomization and sprays, rheology, slow-release coatings, nanotechnology, plasma discharges, fluidized beds, erosion-corrosion of flow-lines, and electromagnetics. His research achievements include two silvers and one bronze from Science and Engineering Exhibitions, most publications award from UTP for the year 2013–2014, best paper award, and research productivity award for the year 2013.

    EMAIL logo
    and Shaharin Anwar Sulaiman

    Shaharin Anwar Sulaiman is an associate professor in the Department of Mechanical Engineering at Universiti Teknologi PETRONAS (UTP), Malaysia. He graduated in 1993 with a BSc in mechanical engineering from Iowa State University. He earned his MS. in thermal power and fluids engineering from UMIST in 2000 and obtained a PhD in combustion from the University of Leeds in 2006. He joined UTP in 1998 and is presently director of the Hybrid Energy Systems research group in the university. His research interests include air-conditioning and ventilation, combustion, sprays and atomization, and biomass energy. He is also a member of the American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) and Malaysian Energy Professionals Association (MEPA) and a corporate member of the Institution of Engineers Malaysia (IEM).

Abstract

Urea is one of the spirited input materials for plant growth. However, more than half of conventional urea applied to the soil may not reach the plants and be washed off by rain and irrigation water. The high lost proportion results not only in economic losses but also in environmental pollution. Alleviation in cost and nitrogen pollution is possible by mitigating the nitrogen release rate and synchronizing it with the plant’s need. A wide range of synthetic and natural materials are being tested for production of slow-release fertilizers. Each one of these materials has its own merits, with accompanying disadvantages. This study critically reviews the most featured natural and synthetic materials pertaining to the slow-release urea industry. The focused review was aimed at elaborating the benefits and limitations of polymeric and nonpolymeric coating materials, release mechanism of conventional and coated urea, methods to characterize the coated urea, slow-release characteristics imparted by a coating to the coated urea, and release patterns of conventional and coated urea. This discussion was further extended to commercially available coatings and slow-release potential of superabsorbent, urethane, and starch-based coatings.

About the authors

Muhammad Yasin Naz

Muhammad Yasin Naz is working as a research scientist with the director of Hybrid Energy Systems (HES) research at the Universiti Teknologi PETRONAS (UTP), Malaysia. He holds a MPhil degree in Plasma Physics from Quaid-i-Azam University, Islamabad, Pakistan, and a doctorate degree from UTP dealing with atomization of non-Newtonian fluids. From 2009 to 2012, he worked as a lecturer in physics at the University of Agriculture Faisalabad, Pakistan. With a very diverse research background, he has contributed to scholarly works on atomization and sprays, rheology, slow-release coatings, nanotechnology, plasma discharges, fluidized beds, erosion-corrosion of flow-lines, and electromagnetics. His research achievements include two silvers and one bronze from Science and Engineering Exhibitions, most publications award from UTP for the year 2013–2014, best paper award, and research productivity award for the year 2013.

Shaharin Anwar Sulaiman

Shaharin Anwar Sulaiman is an associate professor in the Department of Mechanical Engineering at Universiti Teknologi PETRONAS (UTP), Malaysia. He graduated in 1993 with a BSc in mechanical engineering from Iowa State University. He earned his MS. in thermal power and fluids engineering from UMIST in 2000 and obtained a PhD in combustion from the University of Leeds in 2006. He joined UTP in 1998 and is presently director of the Hybrid Energy Systems research group in the university. His research interests include air-conditioning and ventilation, combustion, sprays and atomization, and biomass energy. He is also a member of the American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE) and Malaysian Energy Professionals Association (MEPA) and a corporate member of the Institution of Engineers Malaysia (IEM).

References

Akiyama E, Kashimoto A, Fukuda K, Hotta H, Suzuki T, Kitsuki T. Thickening properties and emulsification mechanisms of new derivatives of polysaccharides in aqueous solution. J Colloid Interf Sci 2005; 282: 448–457.10.1016/j.jcis.2004.08.178Search in Google Scholar PubMed

Ali TM, Hasnain A. Morphological, Physicochemical, and pasting properties of modified white sorghum (sorghum bicolor) Starch. Int J Food Prop 2013; 17: 523–535.10.1080/10942912.2012.654558Search in Google Scholar

Al-Zahrani SM. Utilization of polyethylene and paraffin waxes as controlled delivery systems for different fertilizers. Ind Eng Chem Res 2000; 39: 367–371.10.1021/ie980683fSearch in Google Scholar

Ariyanti S, Man Z, Azmi BM. Improvement of hydrophobicity of urea modified tapioca starch film with lignin for slow release fertilizer. Adv Mater Res 2013; 626: 350–354.10.4028/www.scientific.net/AMR.626.350Search in Google Scholar

Azeem B, KuShaari K, Man ZB, Basit A, Thanh TH. Review on materials & methods to produce controlled release coated urea fertilizer. J Control Release 2014; 181: 11–21.10.1016/j.jconrel.2014.02.020Search in Google Scholar PubMed

Bansiwal AK, Rayalu SS, Labhasetwar NK, Juwarkar AA, Devotta S. Surfactant-modified zeolite as a slow release fertilizer for phosphorus. Agric Food Chem 2006; 54: 4773–4779.10.1021/jf060034bSearch in Google Scholar PubMed

Biniwale RB, Kariya N, Yamashiro H, Ichikawa M. Heat transfer and thermographic analysis of catalyst surface during multiphase phenomena under spray-pulsed conditions for dehydrogenation of cyclohexane over Pt catalysts. J Phys Chem B 2006; 110: 3189–3196.10.1021/jp0558268Search in Google Scholar PubMed

Blouin GM, Rindt DW, Moore OE. Sulphur-coated fertilizers for controlled release. Pilot plant production. J Agric Food Chem 1971; 19: 801–808.10.1021/jf60177a039Search in Google Scholar

Bortolin A, Aouada FA, Mattoso LHC, Ribeiro C. Nanocomposite PAAm/methyl cellulose/montmorillonite hydrogel: evidence of synergistic effects for the slow release of fertilizers. J Agric Food Chem 2013; 61: 7431–7439.10.1021/jf401273nSearch in Google Scholar PubMed

Chen D, Freney J, Rochester I, Constable G, Mosier A, Chalk P. Evaluation of a polyolefin coated urea (Meister) as a fertilizer for irrigated cotton. Nutr Cycl Agroecosyst 2008; 81: 245–254.10.1007/s10705-007-9160-0Search in Google Scholar

Cherif R. Study of coating of solid particles in a fluidized bed. Proceedings from CHISA 1996; 96: P7.65.Search in Google Scholar

Chiellini E, Solaro R. Biodegradable polymeric materials. Adv Mater 1996; 8: 305–313.10.1002/adma.19960080406Search in Google Scholar

Choi MMS, Meisen A. Sulfur coating of urea in shallow spouted beds. Chem Eng Sci 1997; 52: 1073–1086.10.1016/S0009-2509(96)00377-6Search in Google Scholar

Chowdary KPR, Krishna M. Synthesis and evaluation of starch-urea-borate as rate controlling matrix for controlled release. Int J Pharm Nanotechnol 2008; 1: 167–170.Search in Google Scholar

Czech Z, Wilpiszewska K, Tyliszczak B, Jiang X, Bai Y, Shao L. Biodegradable self-adhesive tapes with starch carrier. Int J Adhes Adhes 2013; 44: 195–199.10.1016/j.ijadhadh.2013.03.002Search in Google Scholar

Davies LH. Two grass field trials with a sulphur-coated urea to examine its potential as a slow release nitrogen fertiliser in the U.K. J Sci Food Agric 1973; 24: 63–67.10.1002/jsfa.2740240110Search in Google Scholar

Deka A, Dey N. Rheological studies of two component high build epoxy and polyurethane based high performance coatings. J Coat Technol Res 2013; 10: 305–315.10.1007/s11998-012-9445-3Search in Google Scholar

Du CW, Zhou JM, Shaviv A. Release characteristics of nutrients from polymer-coated compound controlled release fertilizers. J Polym Environ 2006; 14: 223–230.10.1007/s10924-006-0025-4Search in Google Scholar

Ebringerová A, Sroková I, Talába P, Hromádková Z. Amphiphili cbeechwood glucuronoxylan derivatives. J Appl Polym Sci 1998; 67: 1523–1530.10.1002/(SICI)1097-4628(19980228)67:9<1523::AID-APP3>3.0.CO;2-FSearch in Google Scholar

El-Rehim HAA, Hegazy ESA, El-Mohdy HLA. Radiation synthesis of hydrogels to enhance sandy soils water retention and increase plant performance. J Appl Polym Sci 2004; 93: 1360–1371.10.1002/app.20571Search in Google Scholar

Engelsjord ME, Fostad O, Singh BR. Effects of temperature on nutrient release from slow-release fertilizers. Nutr Cycl Agroecosyst 1996; 46: 179–187.10.1007/BF00420552Search in Google Scholar

Fernández-Pérez M, González-Pradas E, Villafranca-Sánchez M, Flores-Céspedes F. Mobility of isoproturon from an alginate-bentonite controlled release formulation in layered soil. Chemosphere 2000; 41: 1495–1501.10.1016/S0045-6535(99)00516-0Search in Google Scholar

Fernández-Pérez M, Garrido-Herrera FJ, González-Pradas E, Villafranca-Sánchez M, Flores-Céspedes F. Lignin and ethylcellulose as polymers in controlled release formulations of urea. J Appl Polym Sci 2008; 108: 3796–3803.10.1002/app.27987Search in Google Scholar

Fujita T, Shoji S. Kinds and properties of Meister fertilizers. In: Shoji S, editor. Meister controlled release fertilizer – properties and utilization. Sendai, Japan: Konno Printing Company Ltd, 1999: 13–34.Search in Google Scholar

Galloway JN, Cowling EB. Nitrogen and the world. Ambio 2002; 31: 64–71.10.1579/0044-7447-31.2.64Search in Google Scholar

García MC, Vallejo A, García L, Cartagena MC. Manufacture and evaluation of coated triple superphosphate fertilizers. Ind Eng Chem Res 1997; 36: 869–873.10.1021/ie960153oSearch in Google Scholar

Glibert P, Harrison J, Heil C, Seitzinger S. Escalating worldwide use of urea – a global change contributing to coastal eutrophication. Biogeochemistry 2006; 77: 441–463.10.1007/s10533-005-3070-5Search in Google Scholar

Goddard ED, Hannan RB. Cationic polymer/anionic surfactant interactions. J Colloid Interf Sci 1976; 55: 73–79.10.1016/0021-9797(76)90010-2Search in Google Scholar

Gunaratne A, Hoover R. Effect of heat-moisture treatment on the structure and physicochemical properties of tuber and root starches. Carbohyd Polym 2002; 49: 425–437.10.1016/S0144-8617(01)00354-XSearch in Google Scholar

Han WY, Ma LF, Shi YZ, Ruan JY, Kemmitt SJ. Nitrogen release dynamics and transformation of slow release fertiliser products and their effects on tea yield and quality. J Sci Food Agric 2008; 88: 839–846.10.1002/jsfa.3160Search in Google Scholar

Han X, Chen S, Hu X. Controlled-release fertilizer encapsulated by starch/polyvinyl alcohol coating. Desalination 2009; 240: 21–26.10.1016/j.desal.2008.01.047Search in Google Scholar

Hepburn C. Polyurethane elastomers. England: Elsevier Science, 1992.10.1007/978-94-011-2924-4Search in Google Scholar

Hergert GR, Ferguson C, Wortmann C. Enhanced efficiency fertilizers: will they enhance my fertilizer efficiency? Proceedings of the 3rd Annual Crop Production Clinics, University of Nebraska-Lincoln Extension, United States, 2011.Search in Google Scholar

Hoeung P, Bindar Y, Senda S. Development of granular urea-zeolite slow release fertilizer using inclined pan granulator. Jurnal Teknik Kimia Indonesia 2011; 10: 102–111.10.5614/jtki.2011.10.2.6Search in Google Scholar

Horváth E, Ormós Z. Film coating of dragée seeds by fluidized bed spraying methods. Acta Pharm Technol 1989; 35: 90–96.Search in Google Scholar

Ibrahim KRM, Babadi FE, Yunus R. Comparative performance of different urea coating materials for slow release. Particuology 2014; 17: 165–172.10.1016/j.partic.2014.03.009Search in Google Scholar

Iley WJ. Effect of particle size and porosity on particle film coatings. Powder Technol 1991; 65: 441–445.10.1016/0032-5910(91)80205-WSearch in Google Scholar

Jiang L, Chen Y, Hu C. Polyurethaneurea aqueous dispersions prepared with diethyltoluenediamine as chain extender. J Coat Technol Res 2007; 4: 59–66.10.1007/s11998-007-9010-7Search in Google Scholar

Jin S, Wang Y, He J, Yang Y, Yu X, Yue G. Preparation and properties of a degradable interpenetrating polymer networks based on starch with water retention, amelioration of soil, and slow release of nitrogen and phosphorus fertilizer. J Appl Polym Sci 2012; 128: 407–415.10.1002/app.38162Search in Google Scholar

Kage H, Takahashi T, Yoshida T, Ogura H, Matsuno Y. Coating efficiency of seed particles in a fluidized bed by automization of powder suspension. Powder Technol 1996; 86: 243–250.10.1016/0032-5910(95)03066-2Search in Google Scholar

Kamm B, Gruber PR, Kamm M. Biorefineries – industrial processes and products. Weinheim: Wiley-VCH Verlag GmbH & Co. KGaA, 2006.10.1002/14356007.l04_l01Search in Google Scholar

Koo S, Lee K, Lee H. Effect of cross-linking on the physicochemical and physiological properties of corn starch. Food Hydrocoll 2010; 24: 619–625.10.1016/j.foodhyd.2010.02.009Search in Google Scholar

Lan R, Liu Y, Wang G, Wang T, Kan C, Jin Y. Experimental modeling of polymer latex spray coating for producing controlled-release urea. Particuology 2011; 9: 510–516.10.1016/j.partic.2011.01.004Search in Google Scholar

Liu YH, Wang TJ, Qin L, Jin Y. Urea particle coating for controlled release by using DCPD modified sulfur. Powder Technol 2008; 183: 88–93.10.1016/j.powtec.2007.11.022Search in Google Scholar

Lu DR, Xiao CM, Xu SJ. Starch-based completely biodegradable polymer materials. eXPRESS Polym Lett 2009; 6: 366–375.10.3144/expresspolymlett.2009.46Search in Google Scholar

Lubkowski K, Smorowska A, Markowska-Szczupak, A, Ukielski R. Copolyester-coated mineral fertilizers–preparation, characterization, and nutrient release. Toxicol Environ Chem 2016; doi:10.1080/02772248.2015.1130225.Search in Google Scholar

Ma X, Chang PR, Yu J, Stumborg M. Properties of biodegradable citric acid-modified granular starch/thermoplastic pea starch composites. Carbohyd Polym 2009; 75: 1–8.10.1016/j.carbpol.2008.05.020Search in Google Scholar

Mackley MR, Tock C, Anthony R, Butler SA, Chapman G, Vadillo DC. The rheology and processing behavior of starch and gum-based dysphagia thickeners. J Rheol 2013; 57: 1533–1553.10.1122/1.4820494Search in Google Scholar

Majeed Z, Ramli NK, Mansor N, Man Z. A comprehensive review on biodegradable polymers and their blends used in controlled release fertilizer processes. Rev Chem Eng 2015; 31: 69–95.10.1515/revce-2014-0021Search in Google Scholar

Mathews AS, Narine S. Poly[N-isopropyl acrylamide]-co-polyurethane copolymers for controlled release of urea. J Polym Sci Part A: Polym Chem 2010; 48: 3236–3243.10.1002/pola.24090Search in Google Scholar

Mazíková V, Sroková I, Ebringerová A. Solvent-free synthesis and properties of carboxymethyl starch fatty acid ester derivatives. Chem Pap 2009; 63: 71–76.10.2478/s11696-008-0088-xSearch in Google Scholar

Meinke LJ, Mayo Z, Weissling TJ. Pheromone delivery system: western corn rootworm (Coleoptera: Chrysomelidae) pheromone encapsulation in a starch borate matrix. J Econ Entomol 1989; 82: 1830–1835.10.1093/jee/82.6.1830Search in Google Scholar

Mikhailova A, Tamboura M, Jia M. Synthesis, characterization, and analyses of mechanical, adhesion, and thermal properties of polysiloxane resin modified with segmented polyurethane. J Coat Technol Res 2013; 10: 97–108.10.1007/s11998-012-9424-8Search in Google Scholar

Millan G, Agosto F, Vazquez M, Botto L. Use of clinoptilolite as a carrier for nitrogen fertilizers in soils of the Pampean Regions of Argentina. J Cienc Investig AGRAR 2008; 35: 245–254.Search in Google Scholar

Mulder WJ, Gosselink RJA, Vingerhoeds MH, Harmsen PFH, Eastham D. Lignin based controlled release coatings. Ind Crop Prod 2011; 34: 915–920.10.1016/j.indcrop.2011.02.011Search in Google Scholar

Naz MY, Sulaiman SA. Testing of starch-based carbohydrate polymer coatings for enhanced urea performance. J Coat Technol Res 2014a; 11: 747–756.10.1007/s11998-014-9590-ySearch in Google Scholar

Naz MY, Sulaiman SA. Surface morphology and dissolution rate of slow discharge urea coated with starch-urea-borax matrix. Polym Plast Technol Eng 2014b; 53: 1778–1787.10.1080/03602559.2014.919657Search in Google Scholar

Naz MY, Sulaiman SA, Ariwahjoedi B, Shaari KZK. Characterization of modified tapioca starch solutions and their sprays for high temperature coating applications. Sci World J 2014a; 2014: 1–10.10.1155/2014/375206Search in Google Scholar PubMed PubMed Central

Naz MY, Sulaiman SA, Ariwahjoedi B, Shaari KZK. Effect of pre-coat solution temperature on fluidized bed urea coatings. Surf Eng 2014b; 31: 486–491.10.1179/1743294414Y.0000000381Search in Google Scholar

Naz MY, Sulaiman SA, Ariwahjoedi B. Effect of the borax mass and pre-spray medium temperature on droplet size and velocity vector distributions of intermittently sprayed starchy solutions. Phys Chem Chem Phys 2015; 17: 3704–3714.10.1039/C4CP04378BSearch in Google Scholar PubMed

Naz MY, Sulaiman SA. Slow release coating remedy for nitrogen loss from conventional urea: a review. J Control Release 2016; 225: 109–120.10.1016/j.jconrel.2016.01.037Search in Google Scholar PubMed

Newman AW, Mueller RL, Vitez I. Starches and starch derivatives. In: James Swarbrick, editor. Encyclopedia of pharmaceutical science and technology, 4th ed. Boca Raton, Florida, USA: CRC Press and Taylor & Francis, 2013: 3331–3339.Search in Google Scholar

Ni B, Liu M, Lü S. Multifunctional slow-release urea fertilizer from ethylcellulose and superabsorbent coated formulations. Chem Eng J 2009; 155: 892–898.10.1016/j.cej.2009.08.025Search in Google Scholar

Ni B, Liu M, Lü S, Xie L, Wang Y. Multifunctional slow-release organic-inorganic compound fertilizer. J Agric Food Chem 2010; 58: 12373–12378.10.1021/jf1029306Search in Google Scholar PubMed

Noordover BAJ, Heise A, Malanowksi P, Senatore D, Mak M, Molhoek L, Duchateau R, Koning CE, van Benthem RATM. Biobased step-growth polymers in powder coating applications. Prog Org Coat 2009; 65: 187–196.10.1016/j.porgcoat.2008.11.001Search in Google Scholar

Oliveira WP. Study of tablet coating by spouted bed process with and without a draft tube. Proceedings of World Congress on Particle Technology, Brighton, UK, 1998.Search in Google Scholar

Otey FH, Trimnell D, Westhoff RP, Shasha BS. Starch matrix for controlled release of urea fertilizer. J Agric Food Chem 1984; 32: 1095–1098.10.1021/jf00125a041Search in Google Scholar

Overbeek A. Polymer heterogeneity in waterborne coatings. J Coat Technol Res 2010; 7: 1–21.10.1007/s11998-009-9201-5Search in Google Scholar

Piculell L, Lindman B. Association and segregation in aqueous polymer/polymer, polymer/surfactant and surfactant/surfactant mixtures: similarities and differences. Adv Colloid Interf Sci 1992; 41: 149–178.10.1016/0001-8686(92)80011-LSearch in Google Scholar

Polat E, Karaca M, Demir H, Onus AN. Use of natural zeolite (clinoptilolite) in agriculture. J Fruit Ornam Plant Res 2004; 12: 183–189.Search in Google Scholar

Pratap KG, Chowdary KPR, Yasoda KK. Evaluation of starch acetate as microencapsulating agent for controlled release of carbamazepine in comparison to other known polymers. Int J Pharm Sci 2012; 2: 67–69.Search in Google Scholar

Rashidzadeh A, Olad A. Slow-released NPK fertilizer encapsulated by NaAlg-g-poly(AA-co-AAm)/MMT superabsorbent nanocomposite. Carbohyd Polym 2014; 114: 269–278.10.1016/j.carbpol.2014.08.010Search in Google Scholar

Saleh DS, Hemati M. Experimental study and modeling of fluidized bed coating and agglomeration. Powder Technol 2003; 130: 116–123.10.1016/S0032-5910(02)00254-1Search in Google Scholar

Salman OA. Polymer coating on urea prills to reduce dissolution rate. J Agric Food Chem 1988; 36: 616–621.10.1021/jf00081a053Search in Google Scholar

Salman OA. Polyethylene-coated urea. Improved storage and handling properties. Ind Eng Chem Res 1989; 28: 630–632.10.1021/ie00089a021Search in Google Scholar

Samyn P, Schoukens G, Abbeele H, Vonck L, Stanssens D. Application of polymer nanoparticle coating for tuning the hydrophobicity of cellulosic substrates. J Coat Technol Res 2011; 8: 363–373.10.1007/s11998-010-9309-7Search in Google Scholar

Schellekens Y, Trimpont VB, Goelen PJ, Binnemans K, Smet M, Persoons MA, Vos DD. Tin-free catalysts for the production of aliphatic thermoplastic polyurethanes. Green Chem 2014; 16: 4401–4407.10.1039/C4GC00873ASearch in Google Scholar

Schexnailder P, Schmidt G. Nanocomposite polymer hydrogels. Colloid Polym Sci 2008; 287: 1–11.10.1007/s00396-008-1949-0Search in Google Scholar

Shalaby SW, McCormick CL, Butler GB. Water-soluble polymers. ACS Symposium. American Chemical Society, Washington DC, 1991; 467:1199.10.1021/bk-1991-0467Search in Google Scholar

Shaviv A. Controlled release fertilizers. IFA International Workshop on Enhanced-Efficiency Fertilizers, Frankfurt. International Fertilizer Industry Association Paris, France, 2005.Search in Google Scholar

Shi R, Bi J, Zhang Z, Zhu A, Chen D, Zhou X, Zhang L, Tian W. The effect of citric acid on the structural properties and cytotoxicity of the polyvinyl alcohol/starch films when molding at high temperature. Carbohyd Polym 2010; 74: 763–770.10.1016/j.carbpol.2008.04.045Search in Google Scholar

Simonne EH, Hutchinson CM. Controlled-release fertilizers for vegetable production in the era of best management practices: teaching new tricks to an old dog. Hort Technol 2005; 15: 36–46.10.21273/HORTTECH.15.1.0036Search in Google Scholar

Singh AV, Nath LK. Synthesis and evaluation of physicochemical properties of cross-linked sago starch. Int J Biol Macromol 2012; 50: 14–18.10.1016/j.ijbiomac.2011.09.003Search in Google Scholar

Suherman I, Anggoro DD. Producing slow release rate urea by coating with starch/acrylic acid in fluid bed spraying. Int J Eng Technol 2011; 11: 62–66.Search in Google Scholar

Suri IK. Coating of prilled urea with Neem. Fertilizer News 2000; 45: 71–72.Search in Google Scholar

Teramoto N, Motoyama T, Yosomiya R, Shibata M. Synthesis, thermal properties, and biodegradability of propyl-etherified starch. Eur Polym J 2003; 39: 255–261.10.1016/S0014-3057(02)00199-4Search in Google Scholar

Thiel WJ, Nguyen LT. Fluidised bed film coating of an ordered powder mixture to produce microencapsulated ordered units. J Pharm Pharmacol 1984; 36: 145–152.10.1111/j.2042-7158.1984.tb06928.xSearch in Google Scholar

Ţolescu C, Iovu H. Polymer conditioned fertilizers. UPB Sci Bull, Series B 2010; 72: 3–14.Search in Google Scholar

Trenkel ME. Improving fertilizer use efficiency. Controlled-release and stabilized fertilizers in agriculture. Paris: The International Fertilizer Industry Association, 1997.Search in Google Scholar

Tzika M, Alexandridou S, Kiparissides C. Evaluation of the morphological and release characteristics of coated fertilizer granules produced in a Wurster fluidized bed. Powder Technol 2003; 132: 16–24.10.1016/S0032-5910(02)00345-5Search in Google Scholar

Valenza DC, Mocanu G, Carpov A, Chapelle S, Merle L, Muller G. New hydrophobically modified carboxymethylcellulose derivatives. Carbohyd Polym 1997; 33: 177–186.10.1016/S0144-8617(97)00031-3Search in Google Scholar

Vashishtha M, Dongara P, Singh D. Improvement in properties of urea by phosphogypsum coating. Int J ChemTech Res 2010; 2: 36–44.Search in Google Scholar

Vossen P. Changing pH in soil. University of California Cooperative Extension, Santa Rosa, USA, 2013.Search in Google Scholar

Wang XQ, Zhou XF. Novel starch solution. BioResources 2011; 6: 1926–1938.Search in Google Scholar

Wang Y, Liu M, Ni B, Xie L. k-Carrageenan sodium alginate beads and superabsorbent coated nitrogen fertilizer with slow-release, water-retention, and anticompaction properties. Ind Eng Chem Res 2012; 51: 413–1422.10.1021/ie2020526Search in Google Scholar

Wang JL, Cheng F, Zhu PX. Structure and properties of urea-plasticized starch films with different urea contents. Carbohyd Polym 2014; 101: 1109–1115.10.1016/j.carbpol.2013.10.050Search in Google Scholar PubMed

Weiss PJ, Meisen A. Laboratory studies on sulphur-coating urea by the spouted bed process. Can J Chem Eng 1983; 61: 440–447.10.1002/cjce.5450610327Search in Google Scholar

Widiarto S. Effect of borax on mechanical properties and biodegradability of sago starch-poly(vinylalcohol) blend films. J Sci Technol 2005; 2: 151–157.Search in Google Scholar

Wu L, Liu M, Rui L. Preparation and properties of a double-coated slow-release NPK compound fertilizer with superabsorbent and water-retention. Bioresour Technol 2008; 99: 547–554.10.1016/j.biortech.2006.12.027Search in Google Scholar PubMed

Xiaofei M, Jiugao Y, Jin F. Urea and formamide as a mixed plasticizer for thermoplastic starch. Polym Int 2004; 53: 1780–1785.10.1002/pi.1580Search in Google Scholar

Xiaoyu N, Yuejin W, Zhengyan W, Lin W, Guannan Q, Lixiang Y. A novel slow-release urea fertiliser: Physical and chemical analysis of its structure and study of its release mechanism. Biosyst Eng 2013; 115: 274–282.10.1016/j.biosystemseng.2013.04.001Search in Google Scholar

Yin W, Zeng X, Li H, Lin X, Ren B, Tong Z. Steady rheological behaviors of UV-curable waterborne hyperbranched polyurethane acrylate dispersions. J Coat Technol Res 2013; 10: 57–64.10.1007/s11998-012-9432-8Search in Google Scholar

Zarei A, Ghaffarian V. Preparation and characterization of biodegradable cellulose acetate-starch membrane. Polym Plast Technol Eng 2013; 52: 387–392.10.1080/03602559.2012.752831Search in Google Scholar

Zeng X, Pramana SS, Batabyal SK, Mhaisalkar SG, Chen X, Jinesh KB. Low temperature synthesis of wurtzite zinc sulfide (ZnS) thin films by chemical spray pyrolysis. Phys Chem Chem Phys 2013; 15: 6763–6768.10.1039/c3cp43470bSearch in Google Scholar

Zhang LM. Cellulosic associative thickeners. Carbohyd Polym 2001; 45: 1–10.10.1016/S0144-8617(00)00276-9Search in Google Scholar

Zohuriaan-Mehr MJ, Omidian H, Doroudiani S, Kabiri K. Advances in non-hygienic applications of superabsorbent hydrogel materials. J Mater Sci 2010; 45: 5711–5735.10.1007/s10853-010-4780-1Search in Google Scholar

Received: 2015-11-5
Accepted: 2016-6-29
Published Online: 2016-8-3
Published in Print: 2017-5-24

©2017 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 26.4.2024 from https://www.degruyter.com/document/doi/10.1515/revce-2015-0065/html
Scroll to top button