Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter August 3, 2013

Preparation of graphene adsorbents and their applications in water purification

  • Jing Xu

    Jing Xu is an undergraduate at Southwest University for Nationalities majoring in Chemistry. She is currently under the supervision of Dr. Sheng-Tao Yang. She focuses her research on the adsorption of pollutants on graphene oxide composites.

    , Hongda Lv

    Hongda Lv obtained his BSc in 2011 at Southwest University for Nationalities majoring in Chemistry. He became a graduate student there in the same year under the supervision of Dr. Jianbin Luo. His research is mainly on the preparation of nanomaterials.

    , Sheng-Tao Yang

    Sheng-Tao Yang received his BSc in 2006 and his PhD in 2011 at Peking University majoring in Chemistry. He was a research scholar at Clemson University from 2008 to 2009. He also worked as a visiting scholar at Hunan University during 2011–2012. In 2011, he joined the College of Chemistry and Environment Protection Engineering, Southwest University for Nationalities in China as an Assistant Professor. He focuses his research on the preparation, applications, and biosafety of carbon nanomaterials.

    EMAIL logo
    and Jianbin Luo

    Jianbin Luo obtained his BSc in 1995 and his PhD in 2006 at Sichuan University majoring in Applied Chemistry and Polymer Science, respectively. He worked as a chemical engineer in Chengda Engineering Corporation of China from 1995 to 2001. In 2006, he joined the College of Chemistry and Environment Protection Engineering, Southwest University for Nationalities in China as an Associate Professor. He did his postdoctoral research in the University of New Brunswick from 2011 to 2012. He focuses his research on the preparation and applications of polymer materials and nanocomposites.

    EMAIL logo

Abstract

Graphene has attracted great interest for its unique structure, fantastic properties, and wide applications. Among the various applications, graphene-based materials hold great potential as adsorbents in decontaminating water because of the large surface area, diverse functionalities, ease of preparation, and low cost of treatment. Graphene and its composites have been used in treating heavy metals, dyes, pesticide, antibiotics, oils, and so on. In this paper, we reviewed the preparation methods of graphene adsorbents and their applications in water purification. The adsorption behaviors of contaminates on graphene are summarized. The interactions between graphene and contaminates are discussed, emphasizing the influence of functional groups. We also propose some guidelines in designing high-performance graphene adsorbents from the physicochemical perspective.


Corresponding authors: Sheng-Tao Yang and Jianbin Luo, College of Chemistry and Environment Protection Engineering, Southwest University for Nationalities, Chengdu 610041, China

About the authors

Jing Xu

Jing Xu is an undergraduate at Southwest University for Nationalities majoring in Chemistry. She is currently under the supervision of Dr. Sheng-Tao Yang. She focuses her research on the adsorption of pollutants on graphene oxide composites.

Hongda Lv

Hongda Lv obtained his BSc in 2011 at Southwest University for Nationalities majoring in Chemistry. He became a graduate student there in the same year under the supervision of Dr. Jianbin Luo. His research is mainly on the preparation of nanomaterials.

Sheng-Tao Yang

Sheng-Tao Yang received his BSc in 2006 and his PhD in 2011 at Peking University majoring in Chemistry. He was a research scholar at Clemson University from 2008 to 2009. He also worked as a visiting scholar at Hunan University during 2011–2012. In 2011, he joined the College of Chemistry and Environment Protection Engineering, Southwest University for Nationalities in China as an Assistant Professor. He focuses his research on the preparation, applications, and biosafety of carbon nanomaterials.

Jianbin Luo

Jianbin Luo obtained his BSc in 1995 and his PhD in 2006 at Sichuan University majoring in Applied Chemistry and Polymer Science, respectively. He worked as a chemical engineer in Chengda Engineering Corporation of China from 1995 to 2001. In 2006, he joined the College of Chemistry and Environment Protection Engineering, Southwest University for Nationalities in China as an Associate Professor. He did his postdoctoral research in the University of New Brunswick from 2011 to 2012. He focuses his research on the preparation and applications of polymer materials and nanocomposites.

We thank Prof. Y.-P. Sun at the Clemson University for his kind help. We acknowledge financial support from the Fundamental Research Funds for the Central Universities, Southwest University for Nationalities (No. 13NZYQN14), and State Administration of Foreign Experts Affairs (No. 2013–24).

References

Ai, L.; Zhang, C.; Chen, Z. Removal of methylene blue from aqueous solution by a solvothermal-synthesized graphene/magnetite composite. J. Hazard. Mater.2011, 192, 1515–1524.Search in Google Scholar

Aksu, Z. Application of biosorption for the removal of organic pollutants: a review. Process Biochem.2005, 40, 997–1026.Search in Google Scholar

Bi, H.; Xie, X.; Yin, K.; Zhou, Y.; Wan, S.; He, L.; Xu, F.; Banhart, F.; Sun, L.; Ruoff, R. S. Spongy graphene as a highly efficient and recyclable sorbent for oils and organic solvents. Adv. Funct. Mater.2012, 22, 4421–4425.Search in Google Scholar

Bonaccorso, F.; Sun, Z.; Hasan, T.; Ferrari, A. C. Graphene photonics and optoelectronics. Nat. Photonics.2010, 4, 611–612.Search in Google Scholar

Boyd, R. S. Heavy metal pollutants and chemical ecology: exploring new frontiers. J. Chem. Ecol.2010, 36, 46–58.Search in Google Scholar

Chang, Y. L.; Yang, S. T.; Liu, J. H.; Dong, E.; Wang, Y.; Cao, A.; Liu, Y.; Wang, H. In vitro toxicity evaluation of graphene oxide on A549 cells. Toxicol. Lett.2011, 200, 201–210.Search in Google Scholar

Chang, Y.; Ren, C.; Qu, J.; Chen, X. Preparation and characterization of Fe3O4/graphene nanocomposite and investigation of its adsorption performance for aniline and p-chloroaniline. Appl. Surf. Sci.2012, 261, 504–509.Search in Google Scholar

Chen, Y.; Chen, L.; Bai, H.; Li, L. Graphene oxide-chitosan composite hydrogels as broad-spectrum adsorbents for water purification. J. Mater. Chem. A2013, 1, 1992–2001.Search in Google Scholar

Cheng, J.; Du, J.; Zhu, W. Facile synthesis of three-dimensional chitosan-graphene mesostructures for reactive black 5 removal. Carbohydr. Polym. 2012, 88, 61–67.Search in Google Scholar

Choucair, M.; Tse, N. M. K.; Hill, M. R.; Stride, J. A. Adsorption and desorption characteristics of 3-dimensional networks of fused graphene. Surf. Sci.2012, 606, 34–39.Search in Google Scholar

Crini, G. Non-conventional low-cost adsorbents for dye removal: a review. Bioresour. Technol.2006, 97, 1061–1085.Search in Google Scholar

Fan, L.; Luo, C.; Li, X.; Lu, F.; Qiu, H.; Sun, M. Fabrication of novel magnetic chitosan grafted with graphene oxide to enhance adsorption properties for methyl blue. J. Hazard. Mater.2012, 215–216, 272–279.Search in Google Scholar

Fan, L.; Luo, C.; Sun, M.; Li, X.; Qiu, H. Highly selective adsorption of lead ions by water-dispersible magnetic chitosan/graphene oxide composites. Colloids. Surf. B.2013a, 103, 523–529.Search in Google Scholar

Fan, L.; Luo, C.; Sun, M.; Qiu, H.; Li, X. Synthesis of magnetic β-cyclodextrin-chitosan/graphene oxide as nanoadsorbent and its application in dye adsorption and removal. Colloids. Surf., B.2013b, 103, 601–607.Search in Google Scholar

Gao, W.; Majumder, M.; Alemany, L. B.; Narayanan, T. N.; Ibarra, M. A.; Pradhan, B. K.; Ajayan, P. M. Engineered graphite oxide materials for application in water purification. ACS Appl. Mater. Interfaces2011, 3, 1821–1826.Search in Google Scholar

Gao, Y.; Li, Y.; Zhang, L.; Huang, H.; Hu, J.; Shah, S. M.; Su, X. Adsorption and removal of tetracycline antibiotics from aqueous solution by graphene oxide. J. Colloid Interface Sci.2012, 368, 540–546.Search in Google Scholar

Geim, A. K. Graphene: status and prospects. Science2009, 324, 1530–1534.10.1126/science.1158877Search in Google Scholar PubMed

Geng, Z.; Lin, Y.; Yu, X.; Shen, Q.; Ma, L.; Li, Z.; Pan, N.; Wang, X. Highly efficient dye adsorption and removal: a functional hybrid of reduced graphene oxide-Fe3O4 nanoparticles as an easily regenerative adsorbent. J. Mater. Chem.2012, 22, 3527–3535.Search in Google Scholar

Guo, J.; Wang, R.; Tjiu, W. W.; Pan, J.; Liu, T. Synthesis of Fe nanoparticles@graphene composites for environmental applications. J. Hazard. Mater.2012, 225–226, 63–73.Search in Google Scholar

Hao, L.; Song, H.; Zhang, L.; Wan, X.; Tang, Y.; Lv, Y. SiO2/graphene composite for highly selective adsorption of Pb(II) ion. J. Colloid Interface Sci.2012, 369, 381–387.Search in Google Scholar

He, F.; Fan, J.; Ma, D.; Zhang, L.; Leung, C.; Chan, H. L. The attachment of Fe3O4 nanoparticles to graphene oxide by covalent bonding. Carbon2010, 48, 3139–3144.Search in Google Scholar

Hu, X.; Zhou, Q. Health and ecosystem risks of graphene. Chem. Rev.2013, 113, 3815–3835.Search in Google Scholar

Huang, Z.; Zheng, X.; Lv, W.; Wang, M.; Yang, Q.; Kang, F. Adsorption of lead (II) ions from aqueous solution on low-temperature exfoliated graphene nanosheets. Langmuir2011, 27, 7558–7562.Search in Google Scholar

Hummers Jr., W. S.; Offerman R. E. Preparation of graphitic oxide. J. Am. Chem. Soc.1958, 80, 1339.Search in Google Scholar

Kovtyukhova, N. I.; Ollivier, P. J.; Martin, B. R.; Mallouk, T. E.; Chizhik, S. A.; Buzaneva, E. V.; Gorchinskiy, A. D. Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations. Chem. Mater.1999, 11, 771–778.Search in Google Scholar

Li, B.; Cao, H.; Yin, G. Mg(OH)2@reduced graphene oxide composite for removal of dyes from water. J. Mater. Chem.2011a, 21, 13765–13768.Search in Google Scholar

Li, Y.; Zhang, P.; Du, Q.; Peng, X.; Liu, T.; Wang, Z.; Xia, Y.; Zhang, W.; Wang, K.; Zhu, H.; Wu, D. Adsorption of fluoride from aqueous solution by graphene. J. Colloid Interface Sci.2011b, 363, 348–354.Search in Google Scholar

Liu, F.; Chung, S.; Oh, G.; Seo, T. S. Three-dimensional graphene oxide nanostructure for fast and efficient water-soluble dye removal. ACS Appl. Mater. Interfaces2011, 4, 922–927.Search in Google Scholar

Liu, Y.; Li, Y.; Yan, X. P. Preparation, characterization, and application of L-cysteine functionalized multiwalled carbon nanotubes as a selective sorbent for separation and preconcentration of heavy metals. Adv. Funct. Mater.2008, 18, 1536–1543.Search in Google Scholar

Liu, L.; Li, C.; Bao, C.; Jia, Q.; Xiao, P.; Liu, X.; Zhang, Q. Preparation and characterization of chitosan/graphene oxide composites for the adsorption of Au(III) and Pd(II). Talanta2012a, 93, 350–357.10.1016/j.talanta.2012.02.051Search in Google Scholar PubMed

Liu, T.; Li, Y.; Du, Q.; Sun, J.; Jiao, Y.; Yang, G.; Wang, Z.; Xia, Y.; Zhang, W.; Wang, K.; Zhu, H.; Wu, D. Adsorption of methylene blue from aqueous solution by graphene. Colloids Surf. B2012b, 90, 197203.10.1016/j.colsurfb.2011.10.019Search in Google Scholar PubMed

Luo, X.; Wang, C.; Luo, S.; Dong, R.; Tu, X.; Zeng, G. Adsorption of As (III) and As (V) from water using magnetite Fe3O4-reduced graphite oxide-MnO2 nanocomposites. Chem. Eng. J.2012, 187, 45–52.Search in Google Scholar

Madadrang, C. J.; Kim, H. Y.; Gao, G.; Wang, N.; Zhu, J.; Feng, H.; Gorring, M.; Kasner, M. L.; Hou, S. Adsorption behavior of EDTA-graphene oxide for Pb (II) removal. ACS Appl. Mater. Interfaces2012, 4, 1186–1193.Search in Google Scholar

Maliyekkal, S. M.; Sreeprasad, T. S.; Krishnan, D.; Kouser, S.; Mishra, A. K.; Waghmare, U. V.; Pradeep, T. Graphene: a reusable substrate for unprecedented adsorption of pesticides. Small2013, 9, 273–283.Search in Google Scholar

Mauter, M. S.; Elimelech, M. Environmental applications of carbon-based nanomaterials. Environ. Sci. Technol.2008, 42, 5843–5859.Search in Google Scholar

Mi, X.; Huang, G.; Xie, W.; Wang, W.; Liu, Y.; Gao, J. Preparation of graphene oxide aerogel and its adsorption for Cu2+ ions. Carbon2012, 50, 4856–4864.Search in Google Scholar

Mishra, A. K.; Ramaprabhu, S. Functionalized graphene sheets for arsenic removal and desalination of sea water. Desalination2011, 282, 39–45.Search in Google Scholar

Pan, Y.; Bao, H.; Li, L. Noncovalently functionalized multiwalled carbon nanotubes by chitosan-grafted reduced graphene oxide and their synergistic reinforcing effects in chitosan films. ACS Appl. Mater. Interfaces2011a, 3, 4819–4830.10.1021/am2013135Search in Google Scholar PubMed

Pan, Y.; Wu, T.; Bao, H.; Li, L. Green fabrication of chitosan films reinforced with parallel aligned graphene oxide. Carbohydr. Polym. 2011b, 83, 1908–1915.Search in Google Scholar

Passow, H; Clarkson, T. W.; Rothstein, A. The general pharmacology of the heavy metals. Pharmacol. Rev.1961, 13, 185–224.Search in Google Scholar

Ramesha, G.; Vijaya Kumara, A.; Muralidhara, H.; Sampath, S. Graphene and graphene oxide as effective adsorbents toward anionic and cationic dyes. J. Colloid Interface Sci.2011, 361, 270–277.Search in Google Scholar

Rao, C. N. R.; Sood, A. K.; Subrahmanyam, K. S.; Govindaraj, A. Graphene: the new two-dimensional nanomaterial. Angew. Chem. Int. Ed.2009, 48, 7752–7777.Search in Google Scholar

Ren, Y.; Yan, N.; Wen, Q.; Fan, Z.; Wei, T.; Zhang, M.; Ma, J. Graphene/δ-MnO2 composite as adsorbent for the removal of nickel ions from wastewater. Chem. Eng. J.2011, 175, 1–7.Search in Google Scholar

Ren, Y.; Yan, N.; Feng, J.; Ma, J.; Wen, Q.; Li, N.; Dong, Q. Adsorption mechanism of copper and lead ions onto graphene nanosheet/δ-MnO2. Mater. Chem. Phys.2012, 136, 538–544.Search in Google Scholar

Ren, X.; Li, J.; Tan, X.; Wang, X. Comparative study of graphene oxide, activated carbon and carbon nanotubes as adsorbents for copper decontamination. Dalton Trans.2013, 42, 5266–5274.Search in Google Scholar

Schwierz, F. Graphene transistors. Nat. Nanotechnol.2010, 5, 487–496.Search in Google Scholar

Song, H.; Hao, L.; Tian, Y.; Wan, X.; Zhang, L.; Lv, Y. Stable and water-dispersible graphene nanosheets: sustainable preparation, functionalization, and high-performance adsorbents for Pb2+. ChemPlusChem2012, 77, 379–386.Search in Google Scholar

Sreeprasad, T.; Maliyekkal, S. M.; Lisha, K.; Pradeep, T. Reduced graphene oxide-metal/metal oxide composites: facile synthesis and application in water purification. J. Hazard. Mater.2011, 186, 921–931.Search in Google Scholar

Sui, Z.; Meng, Q.; Zhang, X.; Ma, R.; Cao, B. Green synthesis of carbon nanotube-graphene hybrid aerogels and their use as versatile agents for water purification. J. Mater. Chem.2012, 22, 8767–8771.Search in Google Scholar

Sun, H.; Cao, L.; Lu, L. Magnetite/reduced graphene oxide nanocomposites: one step solvothermal synthesis and use as a novel platform for removal of dye pollutants. Nano Res.2011, 4, 550–562.Search in Google Scholar

Sun, L.; Yu, H.; Fugetsu, B. Graphene oxide adsorption enhanced by in situ reduction with sodium hydrosulfite to remove acridine orange from aqueous solution. J. Hazard. Mater.2012a, 203, 101110.Search in Google Scholar

Sun, Y.; Chen, C.; Shao, D.; Li, J.; Tan, X.; Zhao, G.; Yang, S.; Wang, X. Enhanced adsorption of ionizable aromatic compounds on humic acid-coated carbonaceous adsorbents. RSC Adv.2012b, 2, 10359–10364.Search in Google Scholar

Travlou, N. A.; Kyzas, G. Z.; Lazaridis, N. K.; Deliyanni, E. A. Functionalization of graphite oxide with magnetic chitosan for the preparation of a nanocomposite dye adsorbent. Langmuir2013, 29, 1657–1668.Search in Google Scholar

Wang, C.; Feng, C.; Gao, Y.; Ma, X.; Wu, Q.; Wang, Z. Preparation of a graphene-based magnetic nanocomposite for the removal of an organic dye from aqueous solution. Chem. Eng. J.2011a, 173, 92–97.Search in Google Scholar

Wang, Y.; Li, Z. H.; Wang, J.; Li, J. H.; Lin, Y. H. Graphene and graphene oxide: bio-functionalization and applications in biotechnology. Trends Biotechnol. 2011b, 29, 205–212.Search in Google Scholar

Wang, J.; Shi, Z.; Fan, J.; Ge, Y.; Yin, J.; Hu, G. Self-assembly of graphene into three-dimensional structures promoted by natural phenolic acids. J. Mater. Chem.2012, 22, 22459–22466.Search in Google Scholar

Wang, Q.; Li, J.; Song, Y.; Wang, X. Facile synthesis of high-quality plasma-reduced graphene oxide with ultrahigh 4,4′-dichlorobiphenyl adsorption capacity. Chem. Asian J.2013, 8, 225231.Search in Google Scholar

Wu, T.; Cai, X.; Tan, S.; Li, H.; Liu, J.; Yang, W. Adsorption characteristics of acrylonitrile, p-toluenesulfonic acid, 1-naphthalenesulfonic acid and methyl blue on graphene in aqueous solutions. Chem. Eng. J.2011, 173, 144149.Search in Google Scholar

Wu, Q.; Feng, C.; Wang, C.; Wang, Z. A facile one-pot solvothermal method to produce superparamagnetic graphene-Fe3O4 nanocomposite and its application in the removal of dye from aqueous solution. Colloids Surf., B.2013a, 101, 210214.Search in Google Scholar

Wu, Y.; Luo, H.; Wang, H.; Wang, C.; Zhang, J.; Zhang, Z. Adsorption of hexavalent chromium from aqueous solutions by graphene modified with cetyltrimethylammonium bromide. J. Colloid Interface Sci.2013b, 394, 183191.Search in Google Scholar

Xia, Y.; Xia, L. Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes. Chem. Eng. Res. Des.2013, 91, 361368.Search in Google Scholar

Xie, G.; Xi, P.; Liu, H.; Chen, F.; Huang, L.; Shi, Y.; Hou, F.; Zeng, Z.; Shao, C.; Wang, J. A facile chemical method to produce superparamagnetic graphene oxide-Fe3O4 hybrid composite and its application in the removal of dyes from aqueous solution. J. Mater. Chem.2012, 22, 10331039.Search in Google Scholar

Yang, S.-T.; Wang, H. F.; Guo, L.; Liu, Y. F.; Cao, A. N. Interaction of fullerenol with lysozyme investigated by experimental and computational approaches. Nanotechnology2008, 19, 395101.10.1088/0957-4484/19/39/395101Search in Google Scholar PubMed

Yang, S.-T.; Chang, Y.; Wang, H.; Liu, G.; Chen, S.; Wang, Y.; Liu, Y.; Cao, A. Folding/aggregation of graphene oxide and its application in Cu2+ removal. J. Colloid Interface Sci.2010a, 351, 122127.Search in Google Scholar

Yang, X.; Tu, Y.; Li, L.; Shang, S.; Tao, X. Well-dispersed chitosan/graphene oxide nanocomposites. ACS Appl. Mater. Interfaces2010b, 2, 17071713.10.1021/am100222mSearch in Google Scholar PubMed

Yang, S.-T.; Chen, S.; Chang, Y.; Cao, A.; Liu, Y.; Wang, H. Removal of methylene blue from aqueous solution by graphene oxide. J. Colloid Interface Sci.2011, 359, 2429.Search in Google Scholar

Yang, K.; Li, Y.; Tan, X.; Peng, R.; Liu, Z. Behavior and toxicity of graphene and its functionalized derivatives in biological systems. Small2012a, 9, 14921503.10.1002/smll.201201417Search in Google Scholar PubMed

Yang, T.; Liu, L.; Liu, J.; Chen, M.; Wang, J. Cyanobacterium metallothionein decorated graphene oxide nanosheets for highly selective adsorption of ultra-trace cadmium. J. Mater. Chem.2012b, 22, 2190921916.Search in Google Scholar

Yang, S.-T.; Luo, J.; Liu, J.; Zhou, Q.; Wan, J.; Ma, C.; Liao, R.; Wang, H.; Liu, Y. Graphene oxide/chitosan composite for methylene blue adsorption. Nanosci. Nanotechnol. Lett.2013, 5, 372–376.Search in Google Scholar

Yao, Y.; Miao, S.; Yu, S.; Ping Ma, L.; Sun, H.; Wang, S. Fabrication of Fe3O4/SiO2 core/shell nanoparticles attached to graphene oxide and its use as an adsorbent. J. Colloid Interface Sci.2012, 379, 2026.Search in Google Scholar

Young, R. J.; Kinloch, I. A.; Gong, L.; Novoselov, K. S. The mechanics of graphene nanocomposites: a review. Compos. Sci. Technol.2012, 72, 1459–1476.Search in Google Scholar

Yuan, Y.; Zhang, G.; Li, Y.; Zhang, G.; Zhang, F.; Fan, X. Poly(amidoamine) modified graphene oxide as an efficient adsorbent for heavy metal ions. Polym. Chem.2013, 4, 21642167.Search in Google Scholar

Zeng, Q.; Cheng, J. S.; Liu, X. F.; Bai, H. T.; Jiang, J. H. Palladium nanoparticle/chitosan-grafted graphene nanocomposites for construction of a glucose biosensor. Biosens. Bioelectron.2011, 26, 3456–3463.Search in Google Scholar

Zhang, K.; Dwivedi, V.; Chi, C.; Wu, J. Graphene oxide/ferric hydroxide composites for efficient arsenate removal from drinking water. J. Hazard. Mater.2010, 182, 162–168.Search in Google Scholar

Zhang, N.; Qiu, H.; Si, Y.; Wang, W.; Gao, J. Fabrication of highly porous biodegradable monoliths strengthened by graphene oxide and their adsorption of metal ions. Carbon.2011a, 49, 827837.Search in Google Scholar

Zhang, W.; Zhou, C.; Zhou, W.; Lei, A.; Zhang, Q.; Wan, Q.; Zou, B. Fast and considerable adsorption of methylene blue dye onto graphene oxide. Bull. Environ. Contam. Toxicol.2011b, 87, 8690.Search in Google Scholar

Zhang, M.; Gao, B.; Yao, Y.; Xue, Y.; Inyang, M. Synthesis, characterization, and environmental implications of graphene-coated biochar. Sci. Total Environ.2012, 435–436, 567572.Search in Google Scholar

Zhao, G.; Jiang, L.; He, Y.; Li, J.; Dong, H.; Wang, X.; Hu, W. Sulfonated graphene for persistent aromatic pollutant management. Adv. Mater.2011, 23, 39593963.Search in Google Scholar

Zhao, G.; Wen, T.; Chen, C.; Wang, X. Synthesis of graphene-based nanomaterials and their application in energy-related and environmental-related areas. RSC Adv. 2012a, 2, 92869303.Search in Google Scholar

Zhao, J.; Ren, W.; Cheng, H. Graphene sponge for efficient and repeatable adsorption and desorption of water contaminations. J. Mater. Chem.2012b, 22, 2019720202.Search in Google Scholar

Zhao, Y.; Hu, C.; Hu, Y.; Cheng, H.; Shi, G.; Qu, L. A versatile, ultralight, nitrogen-doped graphene framework. Angew. Chem. Int. Ed.2012c, 124, 1153311537.Search in Google Scholar

Zhu, J.; Wei, S.; Gu, H.; Rapole, S. B.; Wang, Q.; Luo, Z.; Haldolaarachchige, N.; Young, D. P.; Guo, Z. One-pot synthesis of magnetic graphene nanocomposites decorated with core@double-shell nanoparticles for fast chromium removal. Environ. Sci. Technol.2011, 46, 977985.Search in Google Scholar

Received: 2013-4-29
Accepted: 2013-6-27
Published Online: 2013-08-03
Published in Print: 2013-08-01

©2013 by Walter de Gruyter Berlin Boston

Downloaded on 25.4.2024 from https://www.degruyter.com/document/doi/10.1515/revic-2013-0007/html
Scroll to top button