Skip to content
BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Thermodynamics of SmCl3 and TmCl3: Experimental Enthalpy of Fusion and Heat Capacity. Estimation of Thermodynamic Functions up to 1300K

  • L. Rycerz and M. Gaune-Escard EMAIL logo

Heat capacities of solid SmCl3 and TmCl3 were measured by differential scanning calorimetry in the ternperature range from 300 K up to the respective melting temperatures. The heat capacity of liquid SmCl3 was also investigated. These results were compared with literature data and fitted by a polynomial temperature dependence. The temperature coefficients were given. Additionally, the enthalpy of fusion of SmCl3 was measured. Furthermore, by combination of these results with the literature data on the entropy at 298.15 K, S0m(LnCl3, s, 298.15 K) and the standard molar enthalpy of formation of Δform H0m(LnCl3,s, 298.15 K), the meruiodynaniic functions were calculated up to T = 1300 K.

Received: 2001-12-19
Published Online: 2014-6-2
Published in Print: 2002-2-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Downloaded on 22.5.2024 from https://www.degruyter.com/document/doi/10.1515/zna-2002-1-212/html
Scroll to top button