Abstract
Solutions of zirconyl salts can be treated in a variety of ways to precipitate hydrous amorphous ZrO2. The phases formed upon heating these precipitates are described and rationalized based upon a theory of hydrolytic polymerization which had been proposed at an earlier stage.
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References
B. H. Davis, J. Am. Ceram. Soc. 67, C-168 (1984).
R. Srinivasan, R. J. DeAngelis, and B. H. Davis, J. Mater. Res. 1, 583 (1986).
L-M. Tau, R. Srinivasan, R. J. DeAngelis, T. Pinder, and B. H. Davis, J. Mater. Res. 3, 561 (1988).
R. Srinivasan, M. B. Harris, S. F. Simpson, R. J. DeAngelis, and B. H. Davis, J. Mater. Res. 3, 787 (1988).
A. Clearfield, Inorg. Chem. 3, 146 (1964).
A. Clearfield, Rev. Pure Appl. Chem. 14, 91 (1964).
A. Clearfield and P. A. Vaughan, Acta Crystallogr. 9, 555 (1956).
G. M. Muha and P. A. Vaughan, J. Chem. Phys. 33, 194 (1960).
J. S. Johnson and K. A. Kraus, J. Am. Chem. Soc. 78, 3937 (1956).
A. Clearfield, G. H. Nancollas, and R. H. Blessing, Ion Exchange and Solvent Extraction, edited by J. A. Marinsky and Y. Marcus (Marcel Dekker, Inc., New York, 1973), Vol. 5.
J. R. Fryer, J. L. Hutchenson, and R. Paterson, J. Colloid Interface Sci. 34, 238 (1970).
I. A. Sheka and Ts. V. Peuzner, Russ. J. Inorg. Chem. 5, 1119 (1960).
A. Bleier and R. M. Cannon, in Better Ceramics Through Chemistry, II. edited by C. J. Brinker, D. E. Clark, and D. R. Ulrich (Mater. Res. Soc., Pittsburgh, PA, 1986), p. 71.
M. A. Blesa, A. J. G. Maroto, S. I. Passagio, N. E. Figliolia, and G. Rigotti, J. Mater. Sci. 20, 4601 (1985).
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Clearfield, A. The mechanism of hydrolytic polymerization of zirconyl solutions. Journal of Materials Research 5, 161–162 (1990). https://doi.org/10.1557/JMR.1990.0161
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DOI: https://doi.org/10.1557/JMR.1990.0161