Abstract
A maximum Al3+-substitution has been demonstrated to be 45 mole% of (M + Al) in the brucite layer of hydrotalcites. The chemical composition of the highly substituted hydrotalcites can be typically represented by [M0.55Al0.45(OH)2] [(CO3)0.225 · 0.50H2O] where M = Mg, Ni, Zn, and Co. It showed the small lattice parameters of a0 3.05–2.98 A in the hexagonal lattice, which corroborates Al3+-substitution in the brucite layer. The simultaneous thermal analyses (TG and DTA) and mass spectrometry (MS) study have been performed. The highly Al3+-substituted hydrotalcites also showed quite different isotherms for the CO2 adsorption. These materials adsorbed CO2 gas by removing water within the interlayer and showed the selectivity for CO2 adsorption: Cu–Al ∼Zn—Al < Co—Al < Mg—Al < Ni—Al. The Mg—Al and Co—Al hydrotalcite-like compounds showed a doubled amount of CO2 by removing carbonate ions within the interlayer.
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Tsuji, M., Mao, G., Yoshida, T. et al. Hydrotalcites with an extended Al3+-substitution: Synthesis, simultaneous TG-DTA-MS study, and their CO2 adsorption behaviors. Journal of Materials Research 8, 1137–1142 (1993). https://doi.org/10.1557/JMR.1993.1137
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DOI: https://doi.org/10.1557/JMR.1993.1137