Abstract
The thermoelectric properties of Bi2Sr2Co2Ox (BSC-222) bulk materials prepared by three different processing methods, i.e., conventional sintering, hot pressing, or partial melting, were investigated and compared. The electrical current, temperature difference for Seebeck coefficient, and thermal diffusion were measured in the same direction. The hot pressing and partial melting are effective processing methods for improving the electrical transport property in BSC-222 bulk materials due to an improvement of density in hot-pressed samples or by grain growth during partial melting process. For partially melted samples, a decrease in the thermal conductivity is also observed. The highest dimensionless thermoelectric figure of merit (ZT) values have been obtained in the sample prepared by partial melting method, for which ZT has been increased by a factor of 2.7 by comparison with bulk materials prepared by conventional sintering. At 700 °C in air, ZT value reaches 0.27 for partially melted Bi2Sr2Co2Ox bulk materials. This study shows that optimized electrical and thermal transport properties can be achieved in BSC-222 bulk materials possessing microstructures with both large average grain size and appropriate bulk density.
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B. Poudel, Q. Hao, Y. Ma, Y. Lan, A. Minnich, B. Yu, X. Yan, D. Wang, A. Muto, D. Vashaee, X. Chen, J. Liu, M.S. Dresselhaus, G. Chen, and Z. Ren: High-thermoelectric performance of nanostructured bismuth antimony telluride bulk alloys. Science 320, 634 (2008).
I. Terasaki, Y. Sasago, and K. Uchinokura: Large thermoelectric power in NaCo2O4 single crystals. Phys. Rev. B 56(20), 12685 (1997).
R. Funahashi, I. Matsubara, H. Ikuta, T. Takeuchi, U. Mizutani, and S. Sodeoka: An oxide single crystal with high thermoelectric performance in air. Jpn. J. Appl. Phys. 39, L1127 (2000).
A. Maignan, S. Hébert, M. Hervieu, C. Michel, D. Pelloquin, and D. Khomskii: Magnetoresistance and magnetothermopower properties of Bi/Ca/Co/O and Bi(Pb)/Ca/Co/O misfit layer cobaltites. J. Phys.: Condens. Matter 15, 2711 (2003).
R. Funahashi and M. Shikano: Bi2Sr2Co2Oy whiskers for high thermoelectric figure of merit. Appl. Phys. Lett. 81(8), 1459 (2002).
H. Leligny, D. Grebille, O. Perez, A.C. Masset, M. Hervieu, and B. Raveau: A five-dimensional structural investigation of the misfit layer compound [Bi0.87SrO2]2[CoO2]1.82. Acta Crystallogr., Sect. B 56, 173 (2000).
R. Funahashi, I. Matsubara, and S. Sodeoka: Thermoelectric properties of Bi2Sr2Co2Ox polycrystalline materials. Appl. Phys. Lett. 76(17), 2385 (2000).
W. Shin and N. Murayama: Thermoelectric properties of (Bi,Pb)-Sr-Co-O oxide. J. Mater. Res. 15(2), 382 (2000).
Y. Masuda, D. Nagahama, H. Itahara, T. Tani, W.S. Seo, and K. Koumoto: Thermoelectric performance of Bi- and Na-substituted Ca3Co4O9 improved through ceramic texturing. J. Mater. Chem. 13(5), 1094 (2003).
K. Shinzato and T. Baba: A laser flash apparatus for thermal diffusivity and specific heat capacity measurements. J. Therm. Anal. Calorim. 64, 413 (2001).
K. Rubešová, T. Hlásek, V. Jakeš, D. Sedmidubský, and J. Hejtmánek: Water based sol-gel methods used for Bi-222 thermoelectrics preparation. J. Sol-Gel Sci. Technol. 64(1), 93 (2012).
H.C. Hsu, W.L. Lee, K.K. Wu, Y.K. Kuo, B.H. Chen, and F.C. Chou: Enhanced thermoelectric figure-of-merit ZT for hole-doped Bi2Sr2Co2Oy through Pb substitution. J. Appl. Phys. 111, 103709 (2012).
S. Wang, Z. Bai, H. Wang, Q. Lü, J. Wang, and G. Fu: High temperature thermoelectric properties of Bi2Sr2Co2Oy/Ag composites. J. Alloys Compd. 554, 254 (2013).
H. Muta, T. Kanemitsu, K. Kurosaki, and S. Yamanaka: High-temperature thermoelectric properties of Nb-doped MNiSn (M=Ti, Zr) half-Heusler compound. J. Alloys Compd. 469, 50 (2009).
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The authors gratefully acknowledge the Japan Society for the Promotion of Science (JSPS) for their financial support.
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Combe, E., Funahashi, R., Azough, F. et al. Relationship between microstructure and thermoelectric properties of Bi2Sr2Co2Ox bulk materials. Journal of Materials Research 29, 1376–1382 (2014). https://doi.org/10.1557/jmr.2014.135
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DOI: https://doi.org/10.1557/jmr.2014.135