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Low temperature synthesis and some physical properties of barium-substituted lanthanum manganite (La1−x BaxMnO3)

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Abstract

Barium-substituted lanthanum manganite (La1−xBaxMnO3) powders have been synthesized by a novel autoignition technique, and the effect of barium content on the autoignition characteristics, stability of the compound, and the powder characteristics have been investigated. X-ray examinations show that the material exists as a single phase having perovskite structure up to 40 at. % substitution of Ba for La, beyond which mixed phases of LaMnO3 and BaMnO3 are formed at least up to the highest limit of substitution (50 at. %) and calcination temperature (1350 °C) investigated. Electrical conductivity and thermal expansion behavior of the material have been studied for plausible use as cathode material in solid oxide fuel cells.

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References

  1. G. H. Jonker and J.H. Van Santen, Physica (Utrecht) XVI, 337 (1950).

    Article  Google Scholar 

  2. G. H. Jonker, Physica (Utrecht) XXII, 707 (1956).

    Article  Google Scholar 

  3. J.B.A.A. Elemans, B.V. Laar, K.R. Van Der Veen, and B.O. Loopstra, J. Solid State Chem. 3, 238 (1971).

    Article  CAS  Google Scholar 

  4. M. S. G. Baythoun and F.R. Sale, J. Mater. Sci. 17, 2757 (1982).

    Article  CAS  Google Scholar 

  5. H. Taguchi, D. Matsuda, M. Nagao, K. Tanihata, and Y. Miyamoto, J. Am. Ceram. Soc. 75, 201 (1992).

    Article  CAS  Google Scholar 

  6. S. Bilger, E. Syskakis, A. Naoumidis, and H. Nickel, J. Am. Ceram. Soc. 75, 964 (1992).

    Article  CAS  Google Scholar 

  7. D. W. Johnson, P. K. Gallagher, F. Schrey, and W. W. Rhodes, Am. Ceram. Soc. Bull. 55, 520 (1976).

    CAS  Google Scholar 

  8. A. Chakraborty, P. S. Devi, S. Roy, and H. S. Maiti, J. Mater. Res. 9, 986 (1994).

    Article  CAS  Google Scholar 

  9. A. Chakraborty, P. S. Devi, and H. S. Maiti, Mater. Lett. 20, 63 (1994).

    Article  CAS  Google Scholar 

  10. S. Roy, A. Das Sharma, S.N. Roy, and H. S. Maiti, J. Mater. Res. 8, 2761 (1993).

    Article  CAS  Google Scholar 

  11. P. S. Devi and H. S. Maiti, J. Solid State Chem. 109, 35 (1994).

    Article  CAS  Google Scholar 

  12. P. S. Devi and H. S. Maiti, J. Mater. Res. 9, 1357 (1994).

    Article  CAS  Google Scholar 

  13. H. Taguchi, D. Matsuda, M. Nagao, and H. Shibahara, J. Mater. Sci. Lett. 12, 891 (1993).

    Article  CAS  Google Scholar 

  14. A. Hammouche, E. Siebert, and A. Hammou, Mater. Res. Bull. XXIV, 367 (1989).

    Article  Google Scholar 

  15. A. Wold and R.J. Arnott, J. Phys. Chem. Solids 9, 176 (1959).

    Article  CAS  Google Scholar 

  16. J. Volger, Physica (Utrecht) XX, 49 (1954).

    Article  Google Scholar 

  17. F.J. Disalvo and P.K. Gallagher, J. Solid State Chem. 14, 395 (1975).

    Article  Google Scholar 

  18. B. C. Tofield and W. R. Scott, J. Solid State Chem. 10, 183 (1974).

    Article  CAS  Google Scholar 

  19. J.B. Goodenough, Magnetism and the Chemical Bond (Interscience Publisher, New York, 1963).

    Google Scholar 

  20. D. W. Richerson, Modem Ceramic Engineering, 2nd ed. (Marcel Dekker, Inc., New York, 1992), p. 843.

    Google Scholar 

  21. G.V. Subba Rao, B.M. Wanklyn, and C.N.R. Rao, J. Phys. Chem. Solids 32, 345 (1971).

    Article  Google Scholar 

  22. J. Tanaka, K. Takahashi, K. Yukino, and S. Horiuchi, Phys. Status Solidi A 80, 621 (1983).

    Article  CAS  Google Scholar 

  23. J. Tanaka, M. Umehara S. Tamura, M. Tsukioka, and S. Ehara, J. Phys. Soc. Jpn. 51, 1236 (1982).

    Article  CAS  Google Scholar 

  24. J. H. Kuo, H. U. Anderson, and D. M. Sparlin, J. Solid State Chem. 87, 55 (1990).

    Article  CAS  Google Scholar 

  25. M. Kertesz, I. Riess, D. S. Tannhauser, R. Langpage, and F. J. Rhor, J. Solid State Chem. 42, 125 (1982).

    Article  CAS  Google Scholar 

  26. D.P. Karim and A. T. Aldred, Phys. Rev. B 20, 2255 (1979).

    Article  CAS  Google Scholar 

  27. A. Hammouche, E.J.L. Schouler, and M. Henault, Solid State Ionics 28–30, 1205 (1988).

    Article  Google Scholar 

  28. A. Mackor, T. P. M. Koster, J. G. Kraaijkamp, J. Gerretsen, and J. P. G. M. Van Eijk, in Proc. 2nd Int. Symp. on Solid Oxide Fuel Cells, edited by F. Grosz, P. Zegers, S. C. Singhal, and O. Yamamoto (Commission of the European Communities, Luxembourg, Belgium, 1991), p. 463.

  29. P. Shuk, L. Tichonova, and U. Guth, Solid State Ionics 68, 177 (1994).

    Article  CAS  Google Scholar 

  30. G.H. Jonker, J. Appl. Phys. 37, 1424 (1966).

    Article  CAS  Google Scholar 

  31. R. S. Roth, in Progress in Science and Technology of Rare Earths (Pergamon, Elmsford, NY, 1964).

    Google Scholar 

  32. J.A.M. Van Roosmalen, J.P.P. Huijsmans, and E.H.P. Cordfunke, in Proc. 2nd Int. Symp. on Solid Oxide Fuel Cells, edited by F. Grosz, P. Zergers, S. C. Singhal, and O. Yamomoto (Commission of the European Communities, Luxembourg, Belgium, 1991), p. 507.

  33. H. S. Maiti, A. Chakraborty, and M. K. Paria, in Proc. 3rd Int. Symp. on Solid Oxide Fuel Cells, edited by S. C. Singhal and H. Iwahara (The Electrochemical Society, Pennington, NJ, 1993), p. 190.

  34. N.Q. Minh, J. Am. Ceram. Soc. 76, 563 (1993).

    Article  CAS  Google Scholar 

  35. R. Koc and H. U. Anderson, J. Mater. Sci. 27, 5837 (1992).

    Article  CAS  Google Scholar 

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Author notes

  1. P. Sujatha Devi

    Present address: Department of Chemistry and Biochemistry, Queen’s College, The City University of New York, New York, NY, 10021, USA

Authors and Affiliations

  1. Electroceramics Laboratory, Central Glass & Ceramic Research Institute, Calcutta, 700 032, India

    Amitava Chakraborty, P. Sujatha Devi & H. S. Maiti

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  1. Amitava Chakraborty
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  2. P. Sujatha Devi
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  3. H. S. Maiti
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Chakraborty, A., Devi, P.S. & Maiti, H.S. Low temperature synthesis and some physical properties of barium-substituted lanthanum manganite (La1−x BaxMnO3). Journal of Materials Research 10, 918–925 (1995). https://doi.org/10.1557/JMR.1995.0918

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  • DOI: https://doi.org/10.1557/JMR.1995.0918

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