Skip to main content
Log in

Radiation Effects in Glasses Used for Immobilization of High-level Waste and Plutonium Disposition

  • Articles
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

This paper is a comprehensive review of the state-of-knowledge in the field of radiation effects in glasses that are to be used for the immobilization of high-level nuclear waste and plutonium disposition. The current status and issues in the area of radiation damage processes, defect generation, microstructure development, theoretical methods and experimental methods are reviewed. Questions of fundamental and technological interest that offer opportunities for research are identified.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Closing the Circle on the Splitting of the Atom (U.S. Department of Energy, Office of Environmental Management, Washington, DC, 1995).

  2. Management and Disposition of Excess Weapons Plutonium (National Academy Press, Washington, DC, 1994).

  3. Management and Disposition of Excess Weapons Plutonium–Reactor-Related Options (National Academy Press, Washington, DC, 1995).

  4. G. G. Wicks, A. R. Lodding, and M. A. Molecke, MRS Bull. XVIII (9), 33 (1993).

    Google Scholar 

  5. CM. Jantzen, J. Am. Ceram. Soc. 75 (9), 2433 (1992).

  6. B. Grambow, MRS Bull. XIX (12), 20 (1994).

  7. Storage and Disposition of Weapons-Usable Fissile Materials Draft Programmatic Environmental Impact Statement, DOE/EIS-0229-D (U.S. Department of Energy, Washington, DC, 1996).

  8. Defense Waste Processing Facility - Cost, Schedule, and Technical Issues, GAO/RCED 92-183 (U.S. General Accounting Office, Washington, DC, 1992).

  9. W. Lutze, presented at the National Research Council Workshop on Glass as a Waste Form and Vitrification Technology, Washington, DC, May 13–15, 1996 (unpublished).

  10. Cunnane and J. M. Allison, in Scientific Basis for Nuclear Waste Management XVII, edited by A. Barkatt and R. A. Van Konynenburg (Mater. Res. Soc. Symp. Proc. 333, Pittsburgh, PA, 1994), p. 3.

  11. Waste Form Compliance Plan for the West Valley Demonstration Project High-Level Waste Form, WVDP-185 (West Valley Demonstration Project, West Valley, NY, 1995).

  12. D. B. Amerine, presented at the National Research Council Workshop on Glass as a Waste Form and Vitrification Technology, Washington, DC, May 13–15, 1996 (unpublished).

  13. D. L. Illman, Chemical & Engineering News 71 (25), 9 (1993).

  14. Office of Technology Assessment, Complex Cleanup: The Environmental Legacy of Nuclear Weapons Production, OTA-O-484 (Congress of the United States, Washington, DC, 1991).

  15. Disposal of Weapon Plutonium, edited by E. R. Merz and C. E. Walter (Kluwer Academic Publishers, The Netherlands, 1996).

  16. A. Makhijani and A. Makhijani, Fissile Materials in a Glass, Darkly (IEER Press, Takoma Park, MD, 1995).

  17. E. Browne, J. M. Dairiki, and R. E. Doebler, Table of Isotopes, edited by C. M. Lederer and V. S. Sherley, 7th ed. (John Wiley and Sons, New York, 1978).

  18. G. Taubes, Science 268, 1836 (1995).

  19. C. D. Bowman and F. Venneri, Sci. Glob. Secur. 5, 279 (1996).

  20. R. A. Van Konynenburg, Sci. Glob. Secur. 5, 303 (1996).

  21. N. E. Bibler, W. G. Ramsey, T. F. Meaker, and J. M. Pareizs, in Scientific Basis for Nuclear Waste Management XIX, edited by W. M. Murphy and D. A. Knecht (Mater. Res. Soc. Symp. Proc. 412, Pittsburgh, PA, 1996), p. 65.

  22. J. K. Bates, A. J. G. Ellison, J. W. Emery, and J. C. Hoh, in Scientific Basis for Nuclear Waste Management XIX, edited by W. M. Murphy and D. A. Knecht (Mater. Res. Soc. Symp. Proc. 412, Pittsburgh, PA, 1996), p. 57.

  23. Hj. Matzke, Special issue for a workshop on Radiation Damage Effects in Nuclear Waste Materials, Nucl. Instrum. Methods in Phys. Res. B 32, 453 (1988).

  24. W. J. Weber, L. K. Mansur, F. W. Clinard, Jr., and D. M. Parkin, J. Nucl. Mater. 184, 1 (1991).

  25. W. J. Weber and F. P. Roberts, Nucl. Technol. 60, 178 (1983).

  26. W. G. Burns, A. E. Hughes, J. A. C. Marples, R. S. Nelson, and A. M. Stoneham, J. Nucl. Mater. 107, 245 (1982).

  27. W. G. Burns, A. E. Hughes, J. A. C. Marples, R. S. Nelson, and A. M. Stoneham, in Scientific Basis for Nuclear Waste Management V, edited by W. Lutze (Mater. Res. Soc. Symp. Proc. 11, Pittsburgh, PA, 1982), p. 339.

  28. D. H. Day, A. E. Hughes, J. W. Leake, J. A. C. Marples, G. P. Marsh, J. Rae, and B. O. Wade, Rep. Prog. Phys. 48, 101 (1985).

  29. W. J. Weber, Nucl. Instrum. Methods in Phys. Res. B 32, 471 (1988).

  30. W. J. Weber, J. Minerals, Metals and Materials Sociery 43 (7), 35 (1991).

  31. D. J. Wronkiewicz, Effects of Radionuclide Decay on Waste Glass Behavior–A Critical Review, ANL-93/45 (Argonne National Laboratory, Argonne, IL, 1993).

  32. R. C. Ewing, W. J. Weber, and F. W. Clinard, Jr., Progress in Nuclear Energy 29 (2), 63 (1995).

  33. W. J. Weber and R. C. Ewing, in Scientific Basis for Nuclear Waste Management XVIII, edited by T. Murakami and R. C. Ewing (Mater. Res. Soc. Symp. Proc. 353, Pittsburgh, PA, 1995), p. 1389.

  34. W. J. Weber, R. C. Ewing, and W. Lutze, in Scientific Basis for Nuclear Waste Management XIX, edited by W. M. Murphy and D. A. Knecht (Mater. Res. Soc. Symp. Proc. 412, Pittsburgh, PA, 1996), p. 25.

  35. Radioactive Waste Forms for the Future, edited by W. Lutze and R. C. Ewing (North-Holland, Amsterdam, 1988).

  36. R. C. Ewing, J. Nucl. Mater. 190, vii (1992).

  37. T. A. Buscheck, J. J. Nitao, and L. D. Ramspott, in Scientific Basis for Nuclear Waste Management XIX, edited by W. M. Murphy and D. A. Knecht (Mater. Res. Soc. Symp. Proc. 412, Pittsburgh, PA, 1996), p. 715.

  38. J. F. Ziegler, J. P. Biersack, and U. Littmark, The Stopping and Range of Ions in Solids (Pergamon, New York, 1985).

  39. W. J. Gray, Nature (London) 296, 547 (1982).

  40. R. P. Turcotte, Radiation Effects in Solidified High-Level Wastes–Part 2, Helium Behavior, BNWL-2051 (Pacific Northwest National Laboratory, Richland, WA, 1976).

  41. S. Sato, H. Furuya, K. Morikawa, M. Sugisaki, and Y. Inagaki, J. Nucl. Sci. and Technol. 27, 343 (1990).

  42. B. J. Todd, J. L. Lineweaver, and J. T. Kerr, J. Appl. Phys. 31, 51 (1960).

  43. J. L. Lineweaver, J. Appl. Phys. 34, 1786 (1963).

  44. N. E. Bibler, in Scientific Basis for Nuclear Waste Management, edited by S. V. Topp (Mater. Res. Soc. Symp. Proc. 6, North-Holland, New York, 1982), p. 681.

  45. Standard Method for Testing the Long Term Alpha Irradiation Stability of Solidified High-Level Radioactive Waste Forms, ISO 6962 (International Organization for Standardization, Geneva, Switzerland, 1982).

  46. Nuclear Waste Materials Handbook, Test Methods, DOE/TIC-11400 (Pacific Northwest Laboratory, Richland, WA, 1981).

  47. W. J. Weber, J. W. Wald, and G. L. McVay, J. Am. Ceram. Soc. 68 (9), C-253 (1985).

  48. G. Wagner and P. van den Haute, Fission-Track Dating (Kluwer Academic Publishers, Dordrecht, The Netherlands, 1992).

  49. Y. Eyal and R. C. Ewing, in Proceedings of the International Conference on Nuclear Waste Management and Environmental Remediation, Vol. 1, edited by D. Alexandre, R. Baker, R. Kohout, and J. Marek (ASME Press, New York, 1993), p. 191.

  50. R. L. Fleischer, Science, 207, 979 (1980).

  51. G. W. Arnold, C. J. M. Northrup, and N. E. Bibler, in Scientific Basis for Nuclear Waste Management-V, edited by W. Lutze (Mater. Res. Soc. Symp. Proc. 11, Pittsburgh, PA, 1982), p. 357.

  52. G. Malow and H. Andresen, in Scientific Basis for Nuclear Waste Management, Vol. 1, edited by G. J. McCarthy (Plenum Press, New York, 1979), p.109.

  53. M. Antonini, F. Lanza, and A. Manara, in Ceramics in Nuclear Waste Management, edited by T. D. Chikalla and J. E. Mendel, CONF-790420 (National Technical Information Service, Springfield, VA, 1979), p. 289.

  54. L. F. Curtiss, Nature (London) 120, 406 (1927).

  55. S. C. Lind, Science 68, 643 (1928).

  56. D. G. Tuck, Int. J. Appl. Radiat. Isotopes 15, 49 (1964).

  57. E. Lell, N. J. Kreidl, and J. R. Hensler, in Progress in Ceramic Science, Vol. 4, edited by J. Burke (Pergamon Press, Oxford, New York, 1966), p. 1.

  58. D. L. Griscom, in Glass: Science and Technology Vol. 4B, edited by D. R. Uhlmann and N. J. Kreidl (Academic Press, Boston, 1990), p. 151.

  59. F. W. Clinard, Jr. and L. W. Hobbs, in Physics of Radiation Effects in Crystals, edited by R. A. Johnson and A. N. Orlov (Elsevier, Amsterdam, 1986), p. 387.

  60. R. A. B. Devine, Nucl. Instrum. Methods in Phys. Res. B 91, 378 (1994).

  61. F. Farges, R. C. Ewing, and G. E. Brown, Jr., J. Mater. Res. 8, 1983 (1993).

  62. L. W. Hobbs, J. Non-Cryst. Solids 192 & 193, 79 (1995).

  63. A. C. Wright, B. Bachra, T. M. Brunier, R. N. Sinclair, L. F. Gladden, and R. L. Portsmouth, J. Non-Cryst. Solids 150, 69 (1992).

  64. L. W. Hobbs, Nucl. Instrum. Methods in Phys. Res. B 91, 30–42 (1994).

  65. C. S. Marians and L. W. Hobbs, J. Non-Cryst. Solids 119, 269 (1990).

  66. L. F. Gladden, J. Non-Cryst. Solids 119, 318 (1990).

  67. P. Vashishta, A. Nakano, R. K. Kalia, and I. Ebbsjo, J. Non-Cryst. Solids 182, 59 (1995).

  68. A. G. Revesz and G. V. Gibbs, in The Physics of MOS Insulators, edited by G. Lucovsky, S. T. Pantelides, and F. L. Galeener (Pergamon, New York, 1980), p. 92.

  69. C. S. Marians and J. K. Burdett, J. Non-Cryst. Solids 124, 1 (1990).

  70. E. J. Friebele, D. L. Griscom, M. Stapelbroek, and R. A. Weeks, Phys. Rev. Lett. 42, 1346 (1979).

  71. L. W. Hobbs and M. R. Pascucci, J. Phys. 41 (C6), 237 (1980).

  72. F. Wooten and D. Weaire, J. Non-Cryst. Solids 64, 325 (1984).

  73. U. Jain, A. C. Powell, and L. W. Hobbs, in Defects in Materials, edited by P. D. Bristowe, J. E. Epperson, J. E. Griffith, and Z. Lillental-Weber (Mater. Res. Soc. Symp. Proc. 209, Pittsburgh, PA, 1991), p. 201.

  74. D. J. Jacobs and M. F. Thorpe, Phys. Rev. E 52, 3682 (1996).

  75. P. K. Gupta, J. Am. Ceram. Soc. 76, 1088 (1993).

  76. G. N. Greaves, J. Non-Cryst. Solids 71, 203 (1985).

  77. B. C. Sales, J. O. Ramey, J. C. McCallum, and L. A. Boatner, J. Non-Cryst. Solids 126, 179 (1990).

  78. W. Primak, L. H. Fuchs, and P. Day, Phys. Rev. 92, 1064 (1953).

  79. W. Primak, Phys. Rev. 110, 1240 (1958).

  80. M. Whittels and F. A. Sherrill, Phys. Rev. 93, 1117 (1954).

  81. E. P. EerNisse, J. Appl. Phys. 45, 167 (1974).

  82. H. M. Presby and W. L. Brown, Appl. Phys. Lett. 24, 511 (1974).

  83. G. W. Arnold, Radiat. Eff. 65, 17 (1982).

  84. S. Sato, H. Furuya, Y. Inagaki, T. Kozaka, and M. Sugisaki, J. Nucl. Sci. Technol. 24, 920 (1987).

  85. S. Sato, H. Furuya, K. Asakura, K. Ohta, and T. Tamai, Nucl. Instrum. Methods in Phys. Res. B 1, 534 (1984).

  86. J. E. Shelby, J. Appl. Phys. 51, 2561 (1980).

  87. W. Primak and R. Kampwirth, J. Appl. Phys. 39, 6010 (1968).

  88. C. B. Norris and E. P. EerNisse, J. Appl. Phys. 45, 3876 (1974).

  89. G. W. Arnold, in Scientific Basis for Nuclear Waste Management VIII, edited by C. M. Jantzen, J. A. Stone, and R. C. Ewing (Mater. Res. Soc. Symp. Proc. 44, Pittsburgh, PA, 1985), p. 617.

  90. A. Hiraiwa, H. Usui, and K. Yagi, Appl. Phys. Lett. 54, 1106 (1989).

  91. M. Antonini, A. Manara, and S. Buckley, Radiat. Eff. 65, 55 (1982).

  92. M. Antonini, A. Manara, and P. Lensi, in Physics of SiO2 and its Interfaces, edited by S. T. Pantiledes (Pergamon, New York, 1978), p. 316.

  93. R. A. B. Devine and M. Marchand, Appl. Phys. Lett. 63, 619 (1993).

  94. K. Fukumi, A. Chayahara, M. Satou, M. Hayakawa, M. Hangyo, and S. Nakashima, Jpn. J. Appl. Phys. 29, 905 (1990).

  95. A. C. Wright, J. Non-Cryst. Solids 179, 84 (1994).

  96. R. A. Weeks, J. Appl. Phys. 27, 1376 (1956).

  97. R. A. Weeks, Phys. Rev. 130, 570 (1963).

  98. D. L. Griscom, Nucl. Instrum. Methods in Phys. Res. B 1, 481 (1984).

  99. F. J. Feigl, W. B. Fowler, and K. L. Yip, Solid State Commun. 14, 225 (1974).

  100. K. W. Yip and W. B. Fowler, Phys. Rev. B 11, 2327 (1975).

  101. K. C. Snyder and W. B. Fowler, Phys. Rev. B 48, 13 238 (1993).

  102. R. A. Weeks, Proc. VII Intl. Cong. on Glass, Brussels, Paper No. 41 (1965).

  103. R. Tohmon, H. Mizuno, Y. Ohki, K. Sasagane, K. Nagasawa, and Y. Hama, Phys. Rev. B 39, 1337 (1989).

  104. H. Imai, K. Arai, H. Hosono, Y. Abe, T. Arai, and H. Imagawa, Phys. Rev. B 44, 4812 (1991).

  105. D. L. Griscom, J. Ceram. Soc. Jpn. 99, 923 (1991).

  106. A. V. Amossov and A. O. Rybaltovsky, J. Non-Cryst. Solids 75 (1994).

  107. D. L. Griscom, in Proc. Thirty-Third Frequency Control Symposium (Electronics Industries Assn., Washington, DC, 1979), p. 109.

  108. W. Hayes, M. J. Kane, O. Salimen, R. L. Wood, and S. P. Doherty, J. Phys. C: Solid State 17, 2943 (1984).

  109. T. E. Tsai and D. L. Griscom, Phys. Rev. Lett. 67, 2517 (1991).

  110. N. Itoh, T. Shimizu-Iyayama, and T. Fujita, J. Non-Cryst. Solids 179, 194 (1994).

  111. A. H. Edwards and W. B. Fowler, Phys. Rev. B 26, 6649 (1982).

  112. R. L. Pfeffer, in The Physics and Technology of Amorphous SiO2, edited by R. A. B. Devine (Plenum Publishing, New York, 1988), p. 181.

  113. R. L. Pfeffer, in The Physics and Chemistry of SiO2 and the SiSiO2 Interface, edited by C. R. Helms and B. E. Deal (Plenum Press, New York, 1988), p. 169.

  114. E. J. Friebele, D. L. Griscom, M. Stapelbroek, and R. A. Weeks, Phys. Rev. Lett. 42, 1346 (1979).

  115. M. Stapelbroek, D. L. Griscom, E. J. Friebele, and G. H. Sigel, Jr., J. Non-Cryst. Solids 32, 313 (1979).

  116. D. L. Griscom, J. Non-Cryst. Solids 68, 301 (1984).

  117. D. L. Griscom, G. H. Sigel, Jr., and R. J. Ginther, J. Appl. Phys. 47, 960 (1976).

  118. E. J. Friebele and D. L. Griscom, in Defects in Glasses, edited by F. L. Galeener, D. L. Griscom, and M. J. Weber (Mater. Res. Soc. Symp. Proc. 61, Pittsburgh, PA, 1986), p. 319.

  119. D. L. Griscom, E. J. Friebele, K. J. Long, and J. W. Fleming, J. Appl. Phys. 54, 3743 (1983).

  120. G. W. Arnold, Radiat. Eff. 98, 55 (1986).

  121. G. W. Arnold, Nucl. Instrum. Methods in Phys. Res. B 1, 516 (1984).

  122. G. Battaglin, G. Della Mea, G. De Marchi, P. Mazzoldi, and O. Puglisi, J. Non-Cryst. Solids 50, 119 (1982).

  123. G. Battaglin, G. Della Mea, G. De Marchi, P. Mazzoldi, and O. Puglisi, Radiat. Eff. 64, 99 (1982).

  124. J. F. DeNatale, D. G. Howitt, and G. W. Arnold, Radiat. Eff. 98, 63 (1986).

  125. J. W. H. Schreurs, J. Chem. Phys. 47, 818 (1967).

  126. D. L. Griscom, J. Non-Cryst. Solids 64, 229 (1984).

  127. R. Cases and D. L. Griscom, Nucl. Instrum. Methods in Phys. Res. B 1, 503 (1984).

  128. R. Cases and D. L. Griscom, in Proc. XVI Int’l Cong. Glass, Vol. 3, Glass Structure (1992), p. 53.

  129. D. L. Griscom, J. Non-Cryst. Solids 6, 275 (1971).

  130. P. W. Levy, J. M. Loman, and J. A. Kierstead, Nucl. Instrum. Methods in Phys. Res. B 1, 549 (1984).

  131. N-G. Vannerberg, in Progress in Inorganic Chemistry 4 (1962), p. 125.

  132. J. F. DeNatale and D. G. Howitt, Am. Ceram. Soc. Bull. 61, 582 (1982).

  133. J. F. DeNatale and D. G. Howitt, Nucl. Instrum. Methods in Phys. Res. B 1, 489 (1984).

  134. J. P. Heuer, H. W. Chan, D. G. Howitt, and J. F. DeNatale, in Nuclear Waste Management II, edited by D. E. Clark, W. B. White, and J. J. Machiels (Advances in Ceramics 20, The American Ceramic Society, Westerville, OH, 1986), p. 175.

  135. A. Manara, M. Antonini, P. Camagni, and P. N. Gibson, Nucl. Instrum. Methods in Phys. Res. B 1, 475 (1984).

  136. P. B. Adams and D. L. Evans, Mater. Res. Sci. 12, 525 (1978).

  137. E. Snoeks, T. Weber, A. Cacciato, and A. Polman, unpublished.

  138. E. Snoeks, Ph.D. Thesis, Utrecht University (1995).

  139. G. W. Arnold, Nucl. Instrum. Methods in Phys. Res. B 32, 504 (1988).

  140. S. Klaumünzer, Radiat. Eff. 110, 78 (1989).

  141. A. Benyagoub, S. Löffler, M. Rammansee, and S. Klaumünzer, Nucl. Instrum. Methods in Phys. Res. B 65, 228 (1992).

  142. D. L. Griscom, in Experimental Techniques of Glass Science, edited by O. El-Bayoumi and C. J. Simmons (The American Ceramic Society, Westerville, OH, 1993), p. 161.

  143. D. L. Griscom, J. Chem. Phys. 55, 1113 (1971).

  144. J. A. C. Marples, Nucl. Instrum. Methods in Phys. Res. B 32, 480 (1988).

  145. Y. Inagaki, H. Furuya, K. Idemitsu, T. Banba, S. Matsumoto, and S. Muraoka, in Scientific Basis for Nuclear Waste Management XV, edited by C. G. Sombret (Mater. Res. Soc. Symp. Proc. 257, Pittsburgh, PA, 1992), p. 199.

  146. T. Banba, S. Matsumoto, S. Muraoka, K. Yamada, M. Saito, H. Ishikawa, and N. Sasaki, in Scientific Basis for Nuclear Waste Management XVIII, edited by T. Murakami and R. C. Ewing (Mater. Res. Soc. Symp. Proc. 353, Pittsburgh, PA, 1995), p. 1397.

  147. M. Antonini, P. Camagni, F. Lanza, and A. Manara, in Scientific Basis for Nuclear Waste Management-2, edited by C. J. M. Northrup, Jr. (Plenum Press, New York, 1980), p. 127.

  148. S. Sato, H. Furuya, T. Kozaka, Y. Inagaki, and T. Tamai, J. Nucl. Mater. 152, 265 (1988).

  149. A. Manara, P. N. Gibson, and M. Antonini, in Scientific Basis for Nuclear Waste Management-V, edited by W. Lutze (Mater. Res. Soc. Symp. Proc. 11, North-Holland, New York, 1982), p. 349.

  150. A. M. Stoneham, Nucl. Instrum. Methods in Phys. Res. B 91, 1 (1994).

  151. F. P. Roberts, G. H. Jenks, and C. D. Bopp, Radiation Effects in Solidified High-Level Wastes–Part 1, Stored Energy, BNWL-1944 (Pacific Northwest National Laboratory, Richland, WA, 1976).

  152. A. R. Hall, J. T. Dalton, B. Hudson, and J. A. C. Marples, in Management of Radioactive Wastes from the Nuclear Fuel Cycle, Vol. II, IAEA-SM-207 (International Atomic Energy Agency, Vienna, 1976), p. 3.

  153. G. Malow, J. A. C. Marples, and C. Sombret, in Radioactive Waste Management and Disposal, edited by R. Simon and S. Orlowski (Harwood Academic Publishers, Chur, Switzerland, 1980), p. 341.

  154. A. K. Dé, B. Luckscheiter, W. Lutze, G. Malow, and E. Schiewer, Am. Ceram. Soc. Bull. 55, 500 (1976).

  155. J. F. DeNatale and D. G. Howitt, Radiat. Eff. 91, 89 (1985).

  156. W. J. Weber, R. P. Turcotte, L. R. Bunnell, F. P. Roberts, and J. H. Westsik, in Ceramics in Nuclear Waste Management, edited by T. D. Chikalla and J. E. Mendel, CONF-790420 (National Technical Information Service, Springfield, VA, 1979), p. 294.

  157. S. Sato, K. Asakura, and H. Furuya, Nucl. Chem. Waste Management 4, 147 (1983).

  158. J. F. DeNatale and D. G. Howitt, Am. Ceram. Soc. Bull. 66, 1393 (1987).

  159. J. P. Heuer, M. S. Thesis, Department of Mechanical Engineering, University of California–Davis 1987.

  160. D. G. Howitt, H. W. Chan, J. F. DeNatale, and J. P. Heuer, J. Am. Ceram. Soc. 74, 1145 (1991).

  161. M. H. Tosten, TEM examination of irradiated waste glass, WSRCRP 89-584 (Westinghouse Savannah River Co., Aiken, SC, 1989).

  162. N. E. Bibler, M. H. Tosten, and D. C. Beam, in High-Level Radioactive Waste Management, Vol. 2 (American Nuclear Society, La Grange Park, IL, 1990), p. 1103.

  163. J. Y. Laval and K. H. Westmacott, in Electron Microscopy and Analysis, 1979, edited by T. Mulvey, Conference Series, No. 52 (Institute of Physics, London, 1980), p. 295.

  164. Y. Inagaki, H. Furuya, Y. Ono, K. Idemitsu, T. Banba, S. Matsumoto, and S. Muraoka, in Scientific Basis for Nuclear Waste Management XVI, edited by C. G. Interrante and R. T. Pabalan (Mater. Res. Soc. Symp. Proc. 294, Pittsburgh, PA, 1993), p. 191.

  165. Hj. Matzke and E. Toscano, Europ. Appl. Res. Rep. 7 (9), 1403 (1990).

  166. Hj. Matzke and E. Vernaz, J. Nucl. Mater. 201, 295 (1993).

  167. Hj. Matzke and J. van Geel, in Disposal of Weapons Plutonium, edited by E. R. Merz and C. E. Walter (Kluwer Academic Publishers, The Netherlands, 1996), p. 93.

  168. R. A. Bonniaud, N. R. Jacquet Francillon, R. L. Laude, and C. G. Sombret, in Ceramics in Nuclear Waste Management, edited by T. D. Chikalla and J. E. Mendel, CONF-790420 (National Technical Information Service, Springfield, VA, 1979), p. 57.

  169. J. L. Routbort and Hj. Matzke, Mater. Sci. and Eng. 58, 229 (1983).

  170. W. J. Weber and Hj. Matzke, Europ. Appl. Res. Rep. 7 (7), 1221 (1987).

  171. M. Yamashita and Hj. Matzke, in Modifications Induced by Irradiation in Glasses, edited by P. Mazzoldi (Elsevier Science, Amsterdam, 1992), p. 53.

  172. I. L. F. Ray and Hj. Matzke, unpublished results.

  173. R. P. Turcotte, Radioactive Waste Management 2, 169 (1981).

  174. J. C. Dran, Y. Langevin, M. Maurette, J. C. Petit, and B. Vassent, in Scientific Basis for Nuclear Waste Management, edited by S. V. Topp (Mater. Res. Soc. Symp. Proc. 6, North-Holland, New York, 1982), p. 651.

  175. W. Primak, Nucl. Sci. Engr. 80, 689 (1982).

  176. D. R. Cousens and S. Myhra, J. Non-Cryst. Solids 54, 345 (1983).

  177. J. R. Grover and B. E. Chidley, Reactor Science and Technology (J. Nucl. Energy Parts A/B) 16, 405 (1962).

  178. J. R. Grover, in Management of Radioactive Wastes from Fuel Reprocessing (Organisation for Economic Co-Operation and Development, Paris, 1973), p. 593.

  179. J. H. Westsik and C. O. Harvey, High-Temperature Leaching of a Simulated High-Level Waste Glass, PNL-3172 (Pacific Northwest Laboratory, Richland, WA, 1981).

  180. Y. Eyal and R. L. Fleischer, Geochimica et Cosmochimica Acta 49, 1155 (1985).

  181. D. R. Olander and Y. Eyal, Geochimica et Cosmochimca Acta 54, 1889 (1990).

  182. A. J. G. Ellison and A. Navrotsky, J. Am. Ceram. Soc. 75, 1430 (1992).

  183. A. J. G. Ellison and P. C. Hess, J. Non-Cryst. Solids 127, 247 (1991).

  184. R. Calemezuk and E. Bonjour, J. Non-Cryst. Solids 43, 427 (1981).

  185. A. Navrotsky, Transaction ACA 27, 1 (1991).

  186. S. Susman, K. J. Volin, R. C. Liebermann, G. Gwanmesia, and Y. Wang, Phys. Chem. Glasses 31, 144 (1990).

  187. R. J. Hemley, K. K. Mao, P. M. Bell, and B. O. Mysen, Phys. Rev. Lett. 57, 747 (1986).

  188. R. H. Stolen, J. T. Krause, and C. R. Kurkijan, Discuss. Faraday Soc. 50, 103 (1970).

  189. D. L. Griscom, SPIE 541, 38 (1985).

  190. G. W. Arnold and W. D. Compton, Phys. Rev. 116, 802 (1959).

  191. R. L. Pfeffer, J. Appl. Phys. 57, 5176 (1985).

    Article  CAS  Google Scholar 

  192. G. W. Arnold and P. Mazzoldi, in Ion Beam Modification of Insulators, edited by P. Mazzoldi and G. W. Arnold (Elsevier, Amsterdam, 1987), Chap. 5.

  193. P. Mazzoldi and A. Miotello, Radiat. Eff. 98, 205 (1986).

  194. A. Miotello and P. Mazzoldi, J. Phys. C: Solid State Phys. 15, 5615 (1982).

  195. A. Miotello, Phys. Lett. 103A, 279 (1984).

  196. W. J. Weber, R. C. Ewing, and L. M. Wang, J. Mater. Res. 9, 688 (1994).

  197. P. F. James, J. Mater. Sci. 10, 1802 (1975).

  198. Phase Separation in Glass, edited by O. V. Mazurin and E. A. PoraiKoshits (North-Holland, Amsterdam, 1984).

  199. P. Taylor, Atomic Energy of Canada Limited Report, AECL-10173, August, 1980.

  200. W. Haller, D. H. Blackburn, F. E. Wagstaff, and R. J. Charles, J. Am. Ceram. Soc. 53, 34 (1970).

  201. R. F. Fudali, M. D. Dayar, D. L. Griscom, and H. D. Schreiber, Geochim. Cosmochim. Acta 51, 2749 (1987).

  202. Y-M. Chiang and W. D. Kingery, J. Am. Ceram. Soc. 66, C171 (1983).

  203. A. N. Sreeram and L. W. Hobbs, in Beam-Solid Interactions: Fundamentals and Applications, edited by M. Nastasi, L. R. Harriott, N. Herbots, and R. S. Averback (Mater. Res. Soc. Symp. Proc. 279, Pittsburgh, PA, 1993), p. 559; A. N. Sreeram, Sc. D. Thesis, MIT (1995).

  204. D. B. Spilman, L. L. Hench, and D. E. Clark, Nucl. Chem. Waste Management 6, 107 (1986).

  205. L. W. Hobbs, F. W. Clinard, Jr., S. J. Zinkle, and R. C. Ewing, J. Nucl. Mater. 216, 291 (1994).

  206. J. Yu, W. F. Sommer, and J. N. Bradbury, J. Nucl. Mater. 141–143, 65 (1986); J. Yu, W. F. Sommer, J. N. Bradbury, W. V. Green, and M. Victoria, J. Nucl. Mater. 227, 266 (1996).

  207. L. W. Hobbs, in Quantitative Electron Microscopy, edited by J. N. Chapman and A. J. Craven (Scottish Universities Summer Schools in Physics Publ., Edinburgh, 1984), p. 399; Scanning Microscopy, Suppl. 4, 171 (1990).

  208. C. R.A. Catlow, K.M. Diller, and L.W. Hobbs, Philos. Mag. 42, 123 (1980).

  209. L.W. Hobbs, J. Phys. 37 (C7), 3 (1976).

  210. Computer Simulation of Radiation Effects in Solids, edited by T. Diaz de la Rubia, G.H. Gilmer, and M-J. Caturla (North Holland, Amsterdam, 1995).

  211. J. B. Adams, A. Rockett, J. Kieffer, W. Xu, M. Nomura, K. A. Kiliam, D.F. Richards, and R. Ramprasad, J. Nucl. Mater. 216, 265 (1994).

  212. T. Mattila, R. M. Nieminen, and M. Dzugutov, Nucl. Instrum. Methods in Phys. Res. B 102, 119 (1995).

  213. N.V. Doan, Philos. Mag. A49, 683 (1984).

  214. R. G. Della Valle and H. C. Andersen, J. Chem. Phys. 97, 2682 (1992).

  215. G. Cormier, T. Peres, and J. A. Capobianco, J. Non-Cryst. Solids 195, 125, (1996).

  216. B. Vessal, A.C. Wright, and A.C. Hannon, J. Non-Cryst. Solids 196, 233 (1996).

  217. A.N. Cormack and Y. Cao, Mol. Eng. (1996), in press.

  218. J. M. Delaye and D. Ghaleb, J. Non-Cryst. Solids 195, 239 (1996).

  219. J. M. Delaye and D. Ghaleb, Mater. Sci. Eng. B37, 232 (1996).

  220. J. M. Delaye, presented at this panel meeting (unpublished).

  221. J. M. Delaye and D. Ghaleb, J. Nucl. Mater. (in press).

  222. J. M. Delaye and D. Ghaleb, in Proc. of the Third International Conference on Computer Simulations of Radiation Effects in Solids, University of Surrey, Guildford, UK, July 22–26, 1996.

  223. J. D. Wicks and R. L McGreevy, J. Non-Cryst. Solids 192/193, 23 (1995).

  224. J. D. Wicks, L. Börjesson, G. Bushnell-Wye, W. S. Howells, and R. L. McGreevy, Phys. Rev. Lett. 74, 726 (1995).

  225. J-G. Park and A. N. Cormack, Philos. Mag. B 73, 21 (1996).

  226. A. D. Brailsford and R. Bullough, J. Nucl. Mater. 44, 121 (1972).

  227. U. Jain and A. B. Lidiard, Philos. Mag. 35, 245 (1977).

  228. N. Yu, M. Nastasi, T. E. Levine, J. R. Tesmer, M. G. Hollander, C. R. Evans, and C. J. Maggiore, Nucl. Instrum. Methods in Phys. Res. B 99, 566 (1995).

  229. C. W. Allen, L. L. Funk, E. A. Ryan, and A. Taylor, Nucl. Instrum. Methods in Phys. Res. B 40/41, 553 (1989).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Weber, W.J., Ewing, R.C., Angell, C.A. et al. Radiation Effects in Glasses Used for Immobilization of High-level Waste and Plutonium Disposition. Journal of Materials Research 12, 1948–1978 (1997). https://doi.org/10.1557/JMR.1997.0266

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.1997.0266

Navigation