Abstract
We studied amorphous lead titanium alkoxide-derived heterometallic complexes, prepared from lead acetate and titanium n-propoxide or n-butoxide in parent alcohol medium. According to gas-liquid chromatography (GLC) and thermogravimetric analysis with mass spectrometry of evolved species (TGA/EGA) analyses, the type of alkoxide group influences oxo or acetate bridging, as well as the amounts of hydroxyl and organic groups bound to the metal network. From XANES and EXAFS analysis, local environments of lead and titanium atoms were determined within the analyzed range of 3.4 Å. Local environments depend weakly on the type of alkoxide used. Titanium atoms are pentacoordinated. A Pb–Ti correlation is established with lead atoms bound to titanium atoms by oxygen linkages.
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References
C. D. Chandler, C. Roger, and M. J. Hampden-Smith, Chem. Rev. 93, 1205 (1993).
B. Jaffe, W. R. Cook, and H. Jaffe, Piezoelectric Ceramics (Academic Press, London, United Kingdom, 1971).
A. H. Carim, B. A. Tuttle, D. H. Doughty, and S. L. Martinez, J. Am. Ceram. Soc. 74, 1455 (1991).
C. Kwok, S. Desu, and L. Kammerdiner, in Ferroelectric Thin Films, edited by E. R. Myers and A. I. Kingon (Mater. Res. Soc. Symp. Proc. 200, Pittsburgh, PA, 1990), p. 83.
T. Tani and D.A. Payne, J. Am. Ceram. Soc. 77, 1242 (1994).
G. Tomandl, A. Stiegelschmitt, and R. Boehner, in Science of Ceramics 14, edited by D. Taylor (The Institute of Ceramics, Shelton, Stoke-on-Trent, Staffordshire, United Kingdom, 1991), p. 305.
B. Malič, M. Kosec, and D. Kolar, in Ceramic Processing Science and Technology, edited by H. Hausner, G. L. Messing, and S. I. Hirano (Ceramic Transactions 51, The American Ceramic Society, Westerville, OH, 1995), p. 291.
C. J. Brinker and G. W. Scherer, Sol-gel Science: The Physics and Chemistry of Sol-Gel Processing (Academic Press, San Diego, CA, 1990).
T. W. Dekleva, J. M. Hayes, L. E. Cross, and G. L. Geoffrey, J. Am. Ceram. Soc. 71, C280 (1988).
T. Beltram, M. Kosec, and S. Stavber, Mater. Res. Bull. 28, 313 (1993).
S. D. Ramamurthi and D.A. Payne, J. Am. Ceram. Soc. 73, 2547 (1990).
S. Li, R. A. Condrate, Sr., and R. M. Spriggs, J. Mater. Sci. 24, 3873 (1989).
L. Hubert-Pfalzgraf, in Better Ceramics Through Chemistry V, edited by M. J. Hampden-Smith, W. G. Klemperer, and C. J. Brinker (Mater. Res. Soc. Symp. Proc. 271, Pittsburgh, PA, 1992), p. 15.
R. W. Schwartz, B. C. Bunker, D. B. Dimos, R. A. Assink, B. A. Tuttle, D. R. Tallant, and I. A. Weinstock, Integrated Ferroelectrics 2, 243 (1992).
D. C. Koningsberger and R. Prins, X-Ray Absorption—Principles, Applications, Techniques of EXAFS, SEXAFS, and XANES, Chemical Analysis (John Wiley & Sons, New York, 1988), p. 92.
F. Babonneau, S. Doeuff, A. Leaustic, C. Sanchez, C. Cartier, and M. Verdaguer, Inorg. Chem. 27, 3166 (1988).
S. S. Sangupta, L. Ma, D. L. Adler, and D. A. Payne, J. Mater. Res. 10, 1345 (1995).
U. Kolb, I. Abraham, D. Gutwerk, T. S. Ertel, W. Hoerner, H. Bertagnolli, S. Merklein, and D. Sporn, Physica B 208 & 209, 601 (1995).
M. Kosec and B. Malič, in Fourth Euroceramics 5: Electroceramics, edited by G. Gusmano and E. Traversa (Gruppo Editoriale Faenza Editrice, Italy, 1995), p. 9.
B. Malič, Ph.D. Thesis, University of Ljubljana (1995).
Handbook of Chemistry and Physics, 59th ed. (CRC Press, West Palm Beach, FL, 1978–79), p. D1.
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds (J. Wiley, New York, 1978).
B. Malič, M. Kosec, and B. Orel, Silicates Industriels 60, 163 (1995).
H. K. Chae, D. A. Payne, Z. Xu, and L. Ma, Chem. Mater. 6, 1589 (1994).
R. Brydson, H. Sauer, W. Engel, J. M. Thomas, E. Zeitler, N. Kosugi, and H. Kuroda, J. Phys.: Condens. Matter 1, 797 (1989).
E. A. Stern, M. Newville, B. Ravel, Y. Yacoby, and D. Haskel, Physica B 208 & 209, 117 (1995).
J. J. Rehr, R. C. Albers, and S. I. Zabinsky, Phys. Rev. Lett. 69, 3397 (1992).
L. Hubert-Pfalzgraf, in Better Ceramics Through Chemistry VI, edited by A. K. Cheetham, C. J. Brinker, M. L. Mecartney, and C. Sanchez (Mater. Res. Soc. Symp. Proc. 346, Pittsburgh, PA, 1994), p. 21.
S. Daniele, R. Papiernik, L. G. Hubert-Pfalzgraf, S. Jagner, and M. Hakansson, Inorg. Chem. 34, 628 (1995).
C. Sanchez, J. Livage, M. Henry, and F. Babonneau, J. Non-Cryst. Solids 100, 65 (1988).
D. R. Sandstrom, F. Lytle, P. S. P. Wei, R. B. Greegor, J. Wong, and P. J. Schultz, J. Non-Cryst. Solids 41, 201 (1980).
Z. Liu and R. J. Davis, J. Phys. Chem. 98, 1253 (1994).
D. C. Bradley, R. Gaze, and W. Wardlaw, J. Chem. Soc., 469 (1957).
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Malič, B., Arčon, I., Kosec, M. et al. A structural study of amorphous alkoxide-derived lead titanium complexes. Journal of Materials Research 12, 2602–2611 (1997). https://doi.org/10.1557/JMR.1997.0346
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DOI: https://doi.org/10.1557/JMR.1997.0346