Abstract
Bulk thermal expansion properties of 19 members of the A2M3O12 family of tungstates and molybdates were determined from room temperature to 800 °C. The observed behavior ranges from strong negative thermal expansion (α = −11 × 10−6 K−1) in Sc2W3O12 to near zero thermal expansion in Al1.68Sc0.02In0.30W3O12.
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J.S. O. Evans, T. A. Mary, and A.W. Sleight, J. Solid State Chem. 133, 580–583 (1997).
J.S. O. Evans, T. A. Mary, and A.W. Sleight, Physica B, 241–243, 311–316 (1998).
J.S. O. Evans, T. A. Mary, and A.W. Sleight, J. Solid State Chem. 137, 148–160 (1998).
A. W. Sleight and L.H. Brixner, J. Solid State Chem. 7, 172–174 (1973).
A. W. Sleight, Inorg. Chem. 37, 2854–2860 (1998).
P. M. Forster, A. Yokochi, and A.W. Sleight, J. Solid State Chem. 140, 157–158 (1998).
R. Roy, D. K. Agrawal, J. Alamo, and R. A. Roy, Mater. Res. Bull. 19, 471–477 (1984).
W. R. Buessem, in Mechanical Properties of Engineering Ceramics, edited by W. W. Kreigel and H. Palmour III (Interscience, New York, 1961), pp. 127–148.
S. Y. Limaye, D. K. Agrawal, and H. A. McKinstry, J. Am. Ceram. Soc. 70, C232 (1987).
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Mary, T.A., Sleight, A.W. Bulk thermal expansion for tungstate and molybdates of the type A2M3O12. Journal of Materials Research 14, 912–915 (1999). https://doi.org/10.1557/JMR.1999.0122
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DOI: https://doi.org/10.1557/JMR.1999.0122