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Chemical sensors based on dielectric response of functionalized mesoporous silica films

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Abstract

Dielectric response of mesoporous silica films was monitored as a function of several gas-phase chemical species. The effects of humidity, ammonia, and methane on dielectric constant and dissipation factor of films subjected to different chemical treatments are described. Dielectric constant and dissipation factor of partially dehydroxylated films were found to be highly sensitive to both water vapor and ammonia in air. The capacitive devices based on mesoporous silica films show potential for use in chemical sensors.

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References

  1. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, and J.S. Beck, Nature 359, 710 (1992).

    Article  CAS  Google Scholar 

  2. J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmidt, C.T-W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, and J.L. Schlenker, J. Am. Chem. Soc. 114, 10834 (1992).

    Article  CAS  Google Scholar 

  3. D.H. Olson, G.D. Stucky, and J.C. Vartuli, U.S. Patent No. 5 364 797 (November 15, 1994).

  4. R.W. Cernosek, J.R. Bigbie, M.T. Anderson, J.H. Small, and P.S. Sawyer, Technical Digest of the 1998 Solid-State Sensor and Actuator Workshop, Hilton Head Island, SC (1998), pp. 375–378.

  5. G-J. Li and S. Kawi, Talanta 45, 759 (1998).

    Article  CAS  Google Scholar 

  6. Y. Lu, L. Han, C.J. Brinker, T.M. Niemczyk, and G.P. Lopez, Sens. Actuators B 36, 517 (1996).

    Article  CAS  Google Scholar 

  7. M.E. Gimon-Kinsel, and K.J. Balkus Jr., Stud. Surf. Sci. Catal. 117, 111 (1998).

    Article  CAS  Google Scholar 

  8. P.J. Bruinsma, J.R. Bontha, J. Liu, and S. Baskaran, in Low Di-electric Constant Materials II, edited by A. Lagendijk, H. Treichel, K.J. Uram, and A.C. Jones (Mater. Res. Symp. Proc. 443, Pitts-burgh, PA 1997), pp. 105–110.

    Google Scholar 

  9. S. Baskaran, J. Liu, K. Domansky, N. Kohler, X. Li, C. Coyle, G.E. Fryxell, S. Thevuthasan, and R.E. Williford, Adv. Mater. 12, 291 (2000).

    Article  CAS  Google Scholar 

  10. D. Zhao, P. Yang, N. Melosh, J. Feng, B.F. Chmelka, and G.D. Stucky, Adv. Mater. 10, 1380 (1998).

    Article  CAS  Google Scholar 

  11. E.F. Vansant, P. Van der Voort, and K.C. Vrancken, in Charac-terization and Chemical Modification of the Silica Surface, (Elsevier, New York 1995), Vol, 93, 83–84.

    Google Scholar 

  12. C. Jin, J.D. Luttmer, D.M. Smith, and T.A. Ramos, MRS Bulletin, 22, 39 (1997).

    Article  CAS  Google Scholar 

  13. C. Cho, B.E. Gnade, and D.M. Smith, U.S. Patent No. 5 504 042 (April 2, 1996).

  14. K. Domansky, D.L. Baldwin, J.W. Grate, T.B. Hall, M. Josowicz, and J. Janata, Anal. Chem. 70, 473 (1998).

    Article  CAS  Google Scholar 

  15. A. Goetzberger, Bell Syst. Tech. J. 45, 1097 (1966).

    Article  CAS  Google Scholar 

  16. U. Kang and K.D. Wise, Technical Digest of the 1998 Solid-State Sensor and Actuator Workshop, Hilton Head Island, SC (1998), pp. 183–186.

  17. M.L. Hair, in Infrared Spectroscopy in Surface Chemistry, (Mar-cel Dekker, New York, 1967), pp. 102–103.

    Google Scholar 

  18. N.W. Cant and L.H. Little, Can. J. Chem., 43, 1252 (1965).

    Article  CAS  Google Scholar 

  19. I.D. Chapman and M.L. Hair, Trans. Faraday Soc. 61, 1507 (1965).

    Article  CAS  Google Scholar 

  20. J.B. Peri, J. Phys. Chem. 70, 2937 (1966).

    Article  CAS  Google Scholar 

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Correspondence to Suresh Baskaran.

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Domansky, K., Liu, J., Wang, LQ. et al. Chemical sensors based on dielectric response of functionalized mesoporous silica films. Journal of Materials Research 16, 2810–2816 (2001). https://doi.org/10.1557/JMR.2001.0387

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  • DOI: https://doi.org/10.1557/JMR.2001.0387

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