Skip to main content
Log in

Growth and characterization of c-axis oriented LiNbO3 film on a transparent conducting Al:ZnO inter-layer on Si

  • Articles
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

C-axis oriented lithium niobate (LiNbO3) films were deposited by pulsed-laser deposition on silicon using a transparent conducting interlayer of aluminum (Al)-doped zinc oxide (ZnO). Only two x-ray diffraction reflections corresponding to (006) and (0012) planes of LiNbO3 were observed in the films deposited at a 100-mTorr oxygen pressure and a 450–500 °C substrate temperature. Presence of sharp modes corresponding to E(TO) and A(LO), and absence of any superfluous peaks mainly around 900–905 cm−1 in the Raman spectra confirmed the formation of textured LiNbO3 film. Measured value of direct current and alternate current (AC) conductivities and dielectric constant are 8.6 × 10-12 Ω−1cm-1, 1.16 × 10-6 Ω−1cm-1, and 29.3, respectively, at room temperature. Behavior of dielectric constant and AC conductivity with frequency and temperature are close to the reported single-crystal data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. L. Wooten, K.M. Kissa, A. Yi-Yan, E.J. Murphy, D.A. Lafaw, P.F. Hallemeier, D. Maack, D.V. Attanasio, D.J. Fritz, G.J. McBrien, and D.E. Bossi: A review of Lithium niobate modulators for fibre-optic communication systems. IEEE J. Sel. Top. Quantum Electron. 6, 69 (2000).

    Article  CAS  Google Scholar 

  2. M. Vethen and Ph. Ghosez: First-principles study of the dielectric and dynamical properties of lithium niobate. Phys. Rev. B 65, 214 (2002).

    Google Scholar 

  3. A. de Bernabe, C. Prieto, and A. de Andres: Effect of stoichi-ometry on the dynamic mechanical properties of LiNbO3. J. Appl. Phy. 79, 143 (1996).

    Article  Google Scholar 

  4. S. Tan, T. Gilbert, C-Y. Hung, and T.E. Schlesinger: The role of Si3N4 layers in determining the texture of sputter deposited LiNbO3 thin films. J. Appl. Phys. 79, 3548 (1996).

    Article  CAS  Google Scholar 

  5. Y. Kong, J. Xu, X. Chen, C. Zhang, W. Zhang, and G. Zhang: Ilmenite like stacking defect in non-stoichiometric lithium niobate crystals investigated by Raman scattering spectra. J. Appl. Phys. 87, 4410 (2000).

    Article  CAS  Google Scholar 

  6. Y. Shibata, K. Kaya, K. Akashi, M. Kanai, T. Kawai, and S. Kawai: Epitaxial growth and surface acoustic wave properties of lithium niobate films grown by pulsed laser deposition. J. Appl. Phys. 77, 1498 (1995).

    Article  CAS  Google Scholar 

  7. H. Matsunaga, H. Ohno, Y. Okamoto, and Y. Nakajima: Hetero-epitaxial growth of LiNbO3 single crystal films by ion plating method. J. Cryst. Growth 99, 630 (1990).

    Article  CAS  Google Scholar 

  8. S. Tan, T.E. Schlesinger, and M. Migliuolo: Sputter deposited c-oriented LiNbO3 thin films on SiO2. Appl. Phys. Lett. 68, 2651 (1996).

    Article  CAS  Google Scholar 

  9. W.S. Hu, Z.G. Liu, Z.C. Wu, J.M. Liu, X.Y. Chen, and D. Feng: Pulsed laser deposition of (001) textured LiNbO3 films on Al2O3/ SiO2/Si substrate. Appl. Surf. Sci. 141, 197 (1999).

    Article  CAS  Google Scholar 

  10. M. Shimizu, Y. Furushima, T. Nishida and T. Shiosaki: Preparation and optical waveguide properties of LiNbO3 thin films by rf magnetron sputtering. Jpn. J. Appl. Phys., Part 1 32, 4111 (1993).

    Article  CAS  Google Scholar 

  11. A. Mansingh and A. Dhar: The ac conductivity and dielectric constant of lithium niobate single crystals. J. Phys. D 18, 2059 (1985).

    Article  CAS  Google Scholar 

  12. K. Nassau, H.J. Levinstein, and G.M. Loiacono: Ferroelectric lithium niobate 2. preparation of single domain crystals. J. Phys. Chem. Solids 27, 989 (1966).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. S. Katiyar.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gupta, V., Bhattacharya, P., Yuzyuk, Y.I. et al. Growth and characterization of c-axis oriented LiNbO3 film on a transparent conducting Al:ZnO inter-layer on Si. Journal of Materials Research 19, 2235–2239 (2004). https://doi.org/10.1557/JMR.2004.0322

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.2004.0322

Navigation