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Orientation control of lead zirconate titanate film by combination of sol-gel and sputtering deposition

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Abstract

Highly oriented lead zirconate titanate (PZT) films were fabricated on a platinized silicon substrate using a combination of sol-gel and radio frequency (RF) magnetron sputtering deposition methods. A sol-gel derived PZT layer highly oriented to the (100) plane was deposited as a seed layer, and PZT with the same composition then was deposited on the seed layer by RF-magnetron sputtering. The film deposited on the seed layer showed a strong (100) preferred orientation, while the film deposited without the seed layer showed a (111) preferred orientation. Furthermore, a thick PZT film of up to 4 μm was able to be deposited without cracks by using the seed layer. The piezoelectric property of the (100) oriented film was much better than that of the (111) oriented film.

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References

  1. D.L. Polla and L.F. Francis: Ferroelectric thin films in microelectromechanical systems applications. MRS Bull. 21, 59 (1996).

    Article  CAS  Google Scholar 

  2. S.M. Spearing: Materials issues in microelectromechanical systems (MEMS). Acta Mater. 48, 179 (2000).

    Article  CAS  Google Scholar 

  3. X. Du, U. Belegundu, and K. Uchino: Crystal orientation dependence of piezoelectric properties in lead zirconate titanate: theoretical expectation for thin films. Jpn. J. Appl. Phys. 36, 5580 (1997).

    Article  CAS  Google Scholar 

  4. X. Du, J. Zheng, U. Belegundu, and K. Uchino: Crystal orientation dependence of piezoelectric properties of lead zirconate titanate near the morphotropic phase boundary. Appl. Phys. Lett. 72, 2421 (1998).

    Article  CAS  Google Scholar 

  5. S-E. Park and T.R. Shrout: Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals. J. Appl. Phys. 82, 1804 (1997).

    Article  CAS  Google Scholar 

  6. S-Y. Chen and I-W. Chen: Temperature-time texture transition of Pb(Zr1-xTix)O3 thin films: II, Heat treatment and compositional effects. J. Am. Ceram. Soc. 77, 2337 (1994).

    Article  CAS  Google Scholar 

  7. H. Suzuki, S. Kaneko, K. Murakami, and T. Hayashi: Lowtemperature processing of highly oriented Pb(ZrxTi1-x)O3 thin film with multi-seeding layers. Jpn. J. Appl. Phys. 36, 5803 (1997).

    Article  CAS  Google Scholar 

  8. G-T. Park, J-J. Choi, C-S. Park, J-W. Lee, and H-E. Kim: Piezoelectric and ferroelectric properties of 1 μm-thick PZT film fabricated by a double spin coating process. Appl. Phys. Lett. 85, 2322 (2004).

    Article  CAS  Google Scholar 

  9. S. Takenaka and H. Kozuka: Sol-gel preparation of single-layer, 0.75μm-thick lead zirconate titanate films from lead nitratetitanium and zirconium alkoxide solutions containing polyvinylpyrrolidone. Appl. Phys. Lett. 79, 3485 (2001).

    Article  CAS  Google Scholar 

  10. G-T. Park, J-J. Choi, J. Ryu, H. Fan, and H-E. Kim: Measurement of piezoelectric coefficients of lead zirconate titanate thin films by strain-monitoring pneumatic loading method. Appl. Phys. Lett. 80, 4606 (2002).

    Article  CAS  Google Scholar 

  11. Z.J. Wang, H. Kokawa, and R. Maeda: Growth of lead zirconate titanate thin films by hybrid processing: Sol-gel method and pulsed-laser deposition. J. Cryst. Growth 262, 359 (2004).

    Article  CAS  Google Scholar 

  12. B.H. Park, S.J. Hyun, C.R. Moon, B-D. Cheo, J. Lee, C.Y. Kim, W. Jo, and T.W. Noh: Imprint failures and asymmetric electrical properties induced by thermal process in epitaxial Bi4Ti3O12 thin films. J. Appl. Phys. 84, 4428 (1998).

    Article  CAS  Google Scholar 

  13. A. Gruverman, B.J. Rodriguez, A.I. Kingon, R.J. Nemanich, A.K. Tagantsev, J.S. Cross, and M. Tsukada: Mechanical stress effect on imprint behavior of integrated ferroelectric capacitors. Appl. Phys. Lett. 83, 728 (2003).

    Article  CAS  Google Scholar 

  14. D.V. Taylor and D. Damjanovic: Piezoelectric properties of rhombohedral Pb(Zr,Ti)O3 thin films with (100), (111), and “Random”. Crystallographic Orientation. Appl. Phys. Lett. 76, 1615 (2000).

    Article  CAS  Google Scholar 

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Park, CS., Kim, SW., Park, GT. et al. Orientation control of lead zirconate titanate film by combination of sol-gel and sputtering deposition. Journal of Materials Research 20, 243–246 (2005). https://doi.org/10.1557/JMR.2005.0030

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  • DOI: https://doi.org/10.1557/JMR.2005.0030

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