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Improved critical current densities in MgB2 tapes fabricated through an ex situ process using powders treated in various chemical solutions

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Abstract

We have studied grain coupling and critical current density (Jc) in ex situ processed Fe-sheathed MgB2 tapes fabricated by a powder-in-tube (PIT) technique, using MgB2 powder soaked in various chemical solutions. The grain coupling and the Jc are strongly influenced by the chemical solutions. Compared with the chemical treatment in a benzene solution of benzoic acid, the use of a cyclohexane solution of benzoic acid doubles the Jc value. Cyclohexane is less stable and hence effectively removed from the surface of MgB2 grains, bringing about the improved coupling of grains and the Jc enhancement.

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References

  1. J. Nagamatsu, N. Nakagawa, T. Muranaka, Y. Zenitani J. Akimitsu: Superconductivity at 39 K in magnesium diboride. Nature 410, 63 2001

    Article  CAS  Google Scholar 

  2. S. Jin, H. Mavoori R.B. van Dover: High critical currents in iron-clad superconducting MgB2 wires. Nature 411, 563 2001

    Article  CAS  Google Scholar 

  3. H.L. Suo, C. Beneduce, M. Dhallé, N. Musolino, J-Y. Genoud R. Flükiger: Large transport critical currents in dense Fe- and Ni-clad MgB2 superconducting tapes. Appl. Phys. Lett. 79, 3116 2001

    Article  CAS  Google Scholar 

  4. H. Fujii, H. Kumakura K. Togano: Improved critical current in MgB2 tapes sheathed with carbon steels. J. Mater. Res. 17, 2339 2002

    Article  CAS  Google Scholar 

  5. H. Fujii, K. Togano H. Kumakura: Enhancement of critical current densities of powder-in-tube processed MgB2 tapes by using MgH2 as a precursor powder. Supercond. Sci. Technol. 15, 1571 2002

    Article  CAS  Google Scholar 

  6. H. Fujii, K. Togano H. Kumakura: Fabrication of MgB2 tapes sheathed with carbon steels by ex situ and in situ methods. IEEE Trans. Appl. Supercond. 13(2), 3217 2003

    Article  CAS  Google Scholar 

  7. H. Yamada, M. Hirakawa, H. Kumakura, A. Matsumoto H. Kitaguchi: Critical current densities of powder-in-tube MgB2 tapes fabricated with nanometer-size Mg powder. Appl. Phys. Lett. 84, 1728 2004

    Article  CAS  Google Scholar 

  8. H. Yamada, M. Hirakawa, H. Kumakura H. Kitaguchi: Effect of aromatic hydrocarbon addition on in situ powder-in-tube processed MgB2 tapes. Supercond. Sci. Technol. 19, 175 2006

    Article  CAS  Google Scholar 

  9. H. Fujii, H. Kumakura K. Togano: Influence of MgB2 powder quality on the transport properties of Cu-sheathed MgB2 tapes. Physica C 363, 237 2001

    Article  CAS  Google Scholar 

  10. T. Nakane, H. Kitaguchi H. Kumakura: Improvement in the critical current density of ex situ powder in tube processed MgB2 tapes by utilizing powder prepared from an in situ processed tape. Appl. Phys. Lett. 88, 022513 2006

    Article  Google Scholar 

  11. H. Fang, S. Padmanabhan, Y.X. Zhou K. Salama: High critical current density in iron-clad MgB2 tapes. Appl. Phys. Lett. 82, 4113 2003

    Article  CAS  Google Scholar 

  12. C. Fisher, C. Rodig, W. Hassler, O. Perner, J. Eckert, K. Nenkov, G. Fuchs, H. Wendrock, B. Holzapfel L. Schultz: Preparation of MgB2 tapes using a nanocrystalline partially reacted precursor. Appl. Phys. Lett. 83, 1803 2003

    Article  Google Scholar 

  13. H. Fujii, K. Togano K. Ozawa: Improved critical current densities in ex-situ processed MgB2 tapes fabricated with chemically treated powder. J. Mater. Res. 22, 1281 2007

    Article  CAS  Google Scholar 

  14. T. Masui, S. Lee S. Tajima: Carbon-substitution effect on the electronic properties of MgB2 single crystals. Phys. Rev. B 70, 024504 2004

    Article  Google Scholar 

  15. R.H.T. Wilke, S.L. Bud’ko, P.C. Canfield, D.K. Finnemore, R.J. Suplinskas S.T. Hannahs: Systematic effects of carbon doping on the superconducting properties of Mg(B1−xCx)2. Phys. Rev. Lett. 92, 217003 2004

    Article  CAS  Google Scholar 

  16. Handbook of Chemistry, Basic II 5th ed. (The Chemical Society of Japan, Tokyo, in Japanese) 340

  17. S.X. Dou, S. Soltanian, J. Horvat, X.L. Wang, S.H. Zhou, M. Ionescu, H.K. Liu, P. Monroe M. Tomsic: Enhancements of the critical current density and flux pinning of MgB2 superconductor by nanoparticle SiC doping. Appl. Phys. Lett. 81, 3419 2002

    Article  CAS  Google Scholar 

  18. C.P. Bean: Magnetization of high-field superconductors. Rev. Mod. Phys. 36, 31 1964

    Article  Google Scholar 

  19. H. Fujii, K. Togano, H. Kumakura K. Ozawa: Effect of SiC addition on the superconducting properties of MgB2 tapes fabricated through an ex-situ process using chemically treated powder. Supercond. Sci. Technol. 20, 579 2007

    Article  CAS  Google Scholar 

  20. T. Takenobu, T. Ito, D.H. Chi, K. Prassides Y. Iwasa: Intralayer carbon substitution in the MgB2 superconductor. Phys. Rev. B 64, 134513 2001

    Article  Google Scholar 

  21. A. Bharathi, S.J. Balaselvi, S. Kalavathi, G.L.N. Reddy, V.S. Sastry, Y. Hariharan T.S. Radhakrishnan: Carbon solubility and superconductivity in MgB2. Physica C 370, 211 2002

    Article  CAS  Google Scholar 

  22. S. Lee, T. Masui, A. Yamamoto, H. Uchiyama S. Tajima: Carbon-substituted MgB2 single crystals. Physica C 397, 7 2003

    Article  CAS  Google Scholar 

  23. H. Fujii, K. Togano K. Ozawa: Effects of both addition and chemical treatment of SiC nanoparticles on the grain coupling and the critical current density in ex-situ processed MgB2 tapes using chemically treated MgB2 powder. Supercond. Sci. Technol. 21, 015002 2008

    Article  Google Scholar 

  24. G. Grasso, A. Malagoli, C. Ferdeghini, S. Roncallo, V. Braccini, A.S. Siri M.R. Cimberle: Large transport critical currents in unsintered MgB2 superconducting tapes. Appl. Phys. Lett. 79, 230 2001

    Article  CAS  Google Scholar 

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Acknowledgments

The authors cordially thank Dr. Nakane for assistance of the Ic measurements and the helpful discussions. This research was supported by a Grant-in Aid for Scientific Research (C) from Japan Society for the Promotion of Science (No. 18580323).

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Fujii, H., Togano, K. & Ozawa, K. Improved critical current densities in MgB2 tapes fabricated through an ex situ process using powders treated in various chemical solutions. Journal of Materials Research 23, 507–514 (2008). https://doi.org/10.1557/JMR.2008.0059

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  • DOI: https://doi.org/10.1557/JMR.2008.0059

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