Abstract
We have studied grain coupling and critical current density (Jc) in ex situ processed Fe-sheathed MgB2 tapes fabricated by a powder-in-tube (PIT) technique, using MgB2 powder soaked in various chemical solutions. The grain coupling and the Jc are strongly influenced by the chemical solutions. Compared with the chemical treatment in a benzene solution of benzoic acid, the use of a cyclohexane solution of benzoic acid doubles the Jc value. Cyclohexane is less stable and hence effectively removed from the surface of MgB2 grains, bringing about the improved coupling of grains and the Jc enhancement.
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J. Nagamatsu, N. Nakagawa, T. Muranaka, Y. Zenitani J. Akimitsu: Superconductivity at 39 K in magnesium diboride. Nature 410, 63 2001
S. Jin, H. Mavoori R.B. van Dover: High critical currents in iron-clad superconducting MgB2 wires. Nature 411, 563 2001
H.L. Suo, C. Beneduce, M. Dhallé, N. Musolino, J-Y. Genoud R. Flükiger: Large transport critical currents in dense Fe- and Ni-clad MgB2 superconducting tapes. Appl. Phys. Lett. 79, 3116 2001
H. Fujii, H. Kumakura K. Togano: Improved critical current in MgB2 tapes sheathed with carbon steels. J. Mater. Res. 17, 2339 2002
H. Fujii, K. Togano H. Kumakura: Enhancement of critical current densities of powder-in-tube processed MgB2 tapes by using MgH2 as a precursor powder. Supercond. Sci. Technol. 15, 1571 2002
H. Fujii, K. Togano H. Kumakura: Fabrication of MgB2 tapes sheathed with carbon steels by ex situ and in situ methods. IEEE Trans. Appl. Supercond. 13(2), 3217 2003
H. Yamada, M. Hirakawa, H. Kumakura, A. Matsumoto H. Kitaguchi: Critical current densities of powder-in-tube MgB2 tapes fabricated with nanometer-size Mg powder. Appl. Phys. Lett. 84, 1728 2004
H. Yamada, M. Hirakawa, H. Kumakura H. Kitaguchi: Effect of aromatic hydrocarbon addition on in situ powder-in-tube processed MgB2 tapes. Supercond. Sci. Technol. 19, 175 2006
H. Fujii, H. Kumakura K. Togano: Influence of MgB2 powder quality on the transport properties of Cu-sheathed MgB2 tapes. Physica C 363, 237 2001
T. Nakane, H. Kitaguchi H. Kumakura: Improvement in the critical current density of ex situ powder in tube processed MgB2 tapes by utilizing powder prepared from an in situ processed tape. Appl. Phys. Lett. 88, 022513 2006
H. Fang, S. Padmanabhan, Y.X. Zhou K. Salama: High critical current density in iron-clad MgB2 tapes. Appl. Phys. Lett. 82, 4113 2003
C. Fisher, C. Rodig, W. Hassler, O. Perner, J. Eckert, K. Nenkov, G. Fuchs, H. Wendrock, B. Holzapfel L. Schultz: Preparation of MgB2 tapes using a nanocrystalline partially reacted precursor. Appl. Phys. Lett. 83, 1803 2003
H. Fujii, K. Togano K. Ozawa: Improved critical current densities in ex-situ processed MgB2 tapes fabricated with chemically treated powder. J. Mater. Res. 22, 1281 2007
T. Masui, S. Lee S. Tajima: Carbon-substitution effect on the electronic properties of MgB2 single crystals. Phys. Rev. B 70, 024504 2004
R.H.T. Wilke, S.L. Bud’ko, P.C. Canfield, D.K. Finnemore, R.J. Suplinskas S.T. Hannahs: Systematic effects of carbon doping on the superconducting properties of Mg(B1−xCx)2. Phys. Rev. Lett. 92, 217003 2004
Handbook of Chemistry, Basic II 5th ed. (The Chemical Society of Japan, Tokyo, in Japanese) 340
S.X. Dou, S. Soltanian, J. Horvat, X.L. Wang, S.H. Zhou, M. Ionescu, H.K. Liu, P. Monroe M. Tomsic: Enhancements of the critical current density and flux pinning of MgB2 superconductor by nanoparticle SiC doping. Appl. Phys. Lett. 81, 3419 2002
C.P. Bean: Magnetization of high-field superconductors. Rev. Mod. Phys. 36, 31 1964
H. Fujii, K. Togano, H. Kumakura K. Ozawa: Effect of SiC addition on the superconducting properties of MgB2 tapes fabricated through an ex-situ process using chemically treated powder. Supercond. Sci. Technol. 20, 579 2007
T. Takenobu, T. Ito, D.H. Chi, K. Prassides Y. Iwasa: Intralayer carbon substitution in the MgB2 superconductor. Phys. Rev. B 64, 134513 2001
A. Bharathi, S.J. Balaselvi, S. Kalavathi, G.L.N. Reddy, V.S. Sastry, Y. Hariharan T.S. Radhakrishnan: Carbon solubility and superconductivity in MgB2. Physica C 370, 211 2002
S. Lee, T. Masui, A. Yamamoto, H. Uchiyama S. Tajima: Carbon-substituted MgB2 single crystals. Physica C 397, 7 2003
H. Fujii, K. Togano K. Ozawa: Effects of both addition and chemical treatment of SiC nanoparticles on the grain coupling and the critical current density in ex-situ processed MgB2 tapes using chemically treated MgB2 powder. Supercond. Sci. Technol. 21, 015002 2008
G. Grasso, A. Malagoli, C. Ferdeghini, S. Roncallo, V. Braccini, A.S. Siri M.R. Cimberle: Large transport critical currents in unsintered MgB2 superconducting tapes. Appl. Phys. Lett. 79, 230 2001
Acknowledgments
The authors cordially thank Dr. Nakane for assistance of the Ic measurements and the helpful discussions. This research was supported by a Grant-in Aid for Scientific Research (C) from Japan Society for the Promotion of Science (No. 18580323).
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Fujii, H., Togano, K. & Ozawa, K. Improved critical current densities in MgB2 tapes fabricated through an ex situ process using powders treated in various chemical solutions. Journal of Materials Research 23, 507–514 (2008). https://doi.org/10.1557/JMR.2008.0059
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DOI: https://doi.org/10.1557/JMR.2008.0059