Skip to main content
Log in

Effects of electromigration on the growth of intermetallic compounds in Cu/SnBi/Cu solder joints

  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

In this study, the effects of electromigration (EM) on the growth of Cu–Sn intermetallic compounds (IMCs) in Cu/SnBi/Cu solder joints under 5 × 103 A/cm2 direct current stressing at 308, 328, and 348 K were investigated. For each Cu/SnBi/Cu solder joint under current stressing, the IMCs at the cathode side grew faster than that at the anode side. The growth of these IMCs at the anode side and the cathode side were enhanced by electric current. The growth of these IMCs at the cathode followed a parabolic growth law. The kinetics parameters of the growth of the IMCs were calculated from the thickness data of the IMCs at the cathode side at different ambient temperatures. The calculated intrinsic diffusivity (D0) of the Cu–Sn IMCs was 9.91 × 10−5 m2/s, and the activation energy of the growth of the total Cu–Sn IMC layer was 89.2 kJ/mol (0.92 eV).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

FIG. 1
FIG. 2
FIG. 3
FIG. 4
FIG. 5
FIG. 6

Similar content being viewed by others

References

  1. K.J. Puttlitz, G.T. Gaylon: Impact of the ROHS directive on high-performance electronic systems. Part I: Need for lead utilization in exempt systems. J. Mater. Sci.-Mater. Electron. 18, 331 2007

    Article  CAS  Google Scholar 

  2. K. Zeng, K.N. Tu: Six cases of reliability study of Pb-free solder joints in electronic packaging technology. Mater. Sci. Eng., R 38, 55 2002

    Article  Google Scholar 

  3. K. Suganuma, K-S. Kim: Sn–Zn low temperature solder. J. Mater. Sci.-Mater. Electron. 18, 121 2007

    Article  CAS  Google Scholar 

  4. H-W. Miao, J-G. Duh: Microstructure evolution in Sn–Bi and Sn–Bi–Cu solder joints under thermal aging. Mater. Chem. Phys. 71, 255 2001

    Article  CAS  Google Scholar 

  5. K.N. Tu: Recent advances on electromigration in very-large-scale integration of interconnects. J. Appl. Phys. 94, 5451 2003

    Article  CAS  Google Scholar 

  6. Y-S. Lai, K-M. Chen, C-L. Kao, C-W. Lee, Y-T. Chiu: Electromigration of Sn–37Pb and Sn–3Ag–1.5Cu/Sn–3Ag–0.5Cu composite flip-chip solder bumps with Ti/Ni(V)/Cu under bump metallurgy. Microelectron. Reliabil. 47, 1273 2007

    Article  CAS  Google Scholar 

  7. J.W. Nah, F. Ren, K.N. Tu, S. Venk, G. Camara: Electromigration in Pb-free flip chip solder joints on flexible substrates. J. Appl. Phys. 99, 023520 2006

    Article  Google Scholar 

  8. J.D. Wu, P.J. Zheng, C.W. Lee, S.C. Hung, J.J. Lee: A study in flip-chip UBM/ bump reliability with effects of SnPb solder composition. Microelectron. Reliabil. 46, 41 2006

    Article  Google Scholar 

  9. X.F. Zhang, J.D. Guo, J.K. Shang: Abnormal polarity effect of electromigration on intermetallic compound formation in Sn–9Zn solder interconnect. Scr. Mater. 57, 513 2007

    Article  CAS  Google Scholar 

  10. L-T. Chen, C-M. Chen: Electromigration study in the eutectic SnBi solder joint on the Ni/Au metallization. J. Mater. Res. 21, 962 2006

    Article  CAS  Google Scholar 

  11. Q.L. Yang, J.K. Shang: Interfacial segregation of Bi during current stressing of Sn–Bi/Cu solder interconnect. J. Electron. Mater. 34, 1363 2005

    Article  CAS  Google Scholar 

  12. C-M. Chen, L-T. Chen, Y-S. Lin: Electromigration-induced Bi segregation in eutectic SnBi solder joint. J. Electron. Mater. 36, 168 2007

    Article  CAS  Google Scholar 

  13. B.Y. Wu, Y.C. Chan, H.W. Zhong, M.O. Alam, J.K.L. Lai: Study of the thermal stress in a Pb-free half-bump solder joint under current stressing. Appl. Phys. Lett. 90, 232112 2007

    Article  Google Scholar 

  14. S-W. Chen, C-M. Chen, W-C. Liu: Electric current effects upon the Sn–Cu and Sn–Ni interfacial reactions. J. Electron. Mater. 27, 1193 1998

    Article  CAS  Google Scholar 

  15. C-M. Chen, S-W. Chen: Electromigration effect upon the Sn–0.7 wt% Cu/Ni and Sn–3.5 wt% Ag/Ni interfacial reactions. J. Appl. Phys. 90, 1208 2001

    Article  CAS  Google Scholar 

  16. H. Gan, K.N. Tu: Polarity effect of electromigration on kinetics of intermetallic compound formation in Pb-free solder V-groove samples. J. Appl. Phys. 97, 063514 2005

    Article  Google Scholar 

  17. A. Kumar, M. He, Z. Chen, P.S. Teo: Effect of electromigration on interfacial reactions between electroless Ni-P and Sn–3.5% Ag solder. Thin Solid Films 413, 462 2004

    Google Scholar 

  18. F. Ren, J-W. Nah, K.N. Tu, B.S. Xiong, L.H. Xu, J.H.L. Pang: Electromigration induced ductile-to-brittle transition in lead-free solder joints. Appl. Phys. Lett. 89, 141914 2006

    Article  Google Scholar 

  19. M.Y. Yan, J.O. Suh, F. Ren, K.N. Tu, A.V. Vairagar, S.G. Mhaisalkar, A. Krishnamoorthy: Effect of Cu3Sn coatings on electromigration lifetime improvement of Cu dual-damascene interconnects. Appl. Phys. Lett. 87, 211103 2005

    Article  Google Scholar 

  20. J.E. Garay, U. Anselmi-Tamburini, Z.A. Munir: Enhanced growth of intermetallic phases in the Ni–Ti system by current effects. Acta Mater. 51, 4487 2003

    Article  CAS  Google Scholar 

  21. J-W. Nah, J.H. Kim, H.M. Lee, K-W. Paik: Electromigration in flip chip solder bump of 97Pb–3Sn/37Pb–63Sn combination structure. Acta Mater. 52, 129 2004

    Article  CAS  Google Scholar 

  22. J-W. Nah, J.O. Suh, K.N. Tu, S.W. Yoon, V.S. Rao, V. Kripesh, F. Hua: Electromigration in flip chip solder joints having a thick Cu column bump and a shallow solder interconnect. J. Appl. Phys. 100, 123513 2006

    Article  Google Scholar 

  23. T.Y. Lee, W.J. Choi, K.N. Tu, J.W. Jang, S.M. Kuo, J.K. Lin, D.R. Frear, K. Zeng, J.K. Kivilahti: Morphology, kinetics, and thermodynamics of solid-state aging of eutectic SnPb and Pb-free solders (Sn–3.5Ag, Sn–3.8Ag–0.7Cu and Sn–0.7Cu) on Cu. J. Mater. Res. 17, 291 2002

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This project has been supported by CityU SRG project (Project No. 7002083). The authors are grateful to Prof. and Mrs. Brian Ralph at Brunel University for their hard work and great help.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Y.C. Chan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gu, X., Yang, D., Chan, Y. et al. Effects of electromigration on the growth of intermetallic compounds in Cu/SnBi/Cu solder joints. Journal of Materials Research 23, 2591–2596 (2008). https://doi.org/10.1557/JMR.2008.0331

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/JMR.2008.0331

Navigation