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Enhancement of plasticity in Ti-rich Ti–Zr–Be–Cu–Ni–Ta bulk glassy alloy via introducing the structural inhomogeneity

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Abstract

The effect of microstructural inhomogeneities with different length scale on the plasticity of (Ti45Zr16Be20Cu10Ni9)100–xTax (x = 0, 5, and 10) bulk glassy alloys has been studied. The formation of specific heterogeneous microstructures with a different type of structural inhomogeneity, i.e., short-/medium-range ordered clusters or micrometer-scale ductile dendrites combined with a glassy matrix, evolved by appropriately tuning the alloy chemistry, improves the room temperature plasticity up to ∼12.5% and ∼15%, respectively. The pronouncedly enhanced plasticity is mainly attributed to the retardation of shear localization and multiplication of shear bands by controlling the plastic and failure instabilities otherwise responsible for premature failure.

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References

  1. F. Spaepen: Microscopic mechanism for steady state inhomogeneous flow in metallic glasses. Acta Metall. 25, 407 1977

    Article  CAS  Google Scholar 

  2. A.L. Greer: Metallic glasses. Science 267, 1947 1995

    Article  CAS  Google Scholar 

  3. W.L. Johnson: Bulk glass-forming metallic alloys. MRS Bull. 24, 42 1999

    Article  CAS  Google Scholar 

  4. A.S. Argon: Plastic deformation in metallic glasses. Acta Metall. 27, 47 1979

    Article  CAS  Google Scholar 

  5. A. Inoue: Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater. 48, 279 2000

    Article  CAS  Google Scholar 

  6. J.M. Park, J.S. Park, D.H. Kim, J-H. Kim, E. Fleury: Formation, and mechanical and magnetic properties of bulk ferromagnetic Fe–Nb–B–Y–(Zr, Co) alloys. J. Mater. Res. 21, 1019 2006

    Article  CAS  Google Scholar 

  7. J.F. Löffler: Bulk metallic glasses. Intermetallics 11, 529 2003

    Article  Google Scholar 

  8. A.R. Yavari, J.J. Lewandowski, J. Eckert: Mechanical properties of bulk metallic glasses. MRS Bull. 32, 635 2007

    Article  CAS  Google Scholar 

  9. C.A. Schuh, T.C. Hufnagel, U. Ramamurty: Mechanical behavior of amorphous alloys. Acta Mater. 55, 4067 2007

    Article  CAS  Google Scholar 

  10. J. Eckert, J. Das, S. Pauly, C. Duhamel: Mechanical properties of bulk metallic glasses and composites. J. Mater. Res. 22, 285 2007

    Article  CAS  Google Scholar 

  11. A. Leonhard, L.Q. Xing, M. Heilmaier, A. Gebert, J. Eckert, L. Schultz: Effect of crystalline precipitations on the mechanical behavior of bulk glass forming Zr-based alloys. Nanostruct. Mater. 10, 805 1998

    Article  CAS  Google Scholar 

  12. J.M. Park, J.S. Park, J-H. Kim, H.J. Chang: Mechanical behaviors of partially devitrified Ti-based bulk metallic glasses. J. Mater. Sci. 40, 4999 2005

    Article  CAS  Google Scholar 

  13. T. Ohkubo, D. Nagahama, T. Mukai, K. Hono: Stress-strain behaviors of Ti-based bulk metallic glass and their nanostructures. J. Mater. Res. 22, 1406 2007

    Article  CAS  Google Scholar 

  14. Y.C. Kim, J.H. Na, J.M. Park, D.H. Kim, J.K. Lee, W.T. Kim: Role of nanometer-scale quasicrystals in improving the mechanical behavior of Ti-based bulk metallic glasses. Appl. Phys. Lett. 83, 3093 2003

    Article  CAS  Google Scholar 

  15. L.Q. Xing, Y. Li, K.T. Ramesh, J. Li, T.C. Hufnagel: Enhanced plastic strain in Zr-based bulk amorphous alloys. Phys. Rev. B: Condens. Matter 64, 180201 2001

    Article  Google Scholar 

  16. J. Das, M.B. Tang, K.B. Kim, R. Theissmann, F. Baier, W.H. Wang, J. Eckert: Work-hardenable ductile bulk metallic glass. Phys. Rev. Lett. 94, 205501 2005

    Article  Google Scholar 

  17. A. Inoue, W. Zhang, T. Tsurui, A.R. Yavari, A.L. Greer: Unusual room-temperature compressive plasticity in nanocrystal-toughened bulk copper-zirconium glass. Philos. Mag. Lett. 85, 221 2005

    Article  CAS  Google Scholar 

  18. J.M. Park, H.J. Chang, K.H. Han, W.T. Kim, D.H. Kim: Enhancement of plasticity in Ti-rich Ti–Zr–Be–Cu–Ni bulk metallic glasses. Scr. Mater. 53, 1 2005

    Article  CAS  Google Scholar 

  19. J. Eckert, J. Das, S. Pauly, C. Duhamel, K.B. Kim, S. Yi, W.H. Wang: Impact of microstructural inhomogeneities on the ductility of bulk metallic glasses. Mater. Trans. 48, 1806 2007

    Article  CAS  Google Scholar 

  20. C. Fan, R.T. Ott, T.C. Hufnagel: Metallic glass matrix composite with precipitated ductile reinforcement. Appl. Phys. Lett. 81, 1020 2002

    Article  CAS  Google Scholar 

  21. H. Ma, J. Xu, E. Ma: Mg-based bulk metallic glass composites with plasticity and high strength. Appl. Phys. Lett. 83, 2793 2003

    Article  CAS  Google Scholar 

  22. Y.C. Kim, E. Fleury, J.C. Lee, D.H. Kim: Origin of the simultaneous improvement of strength and plasticity in Ti-based bulk metallic glass. J. Mater. Res. 20, 2474 2005

    Article  CAS  Google Scholar 

  23. C.C. Hays, C.P. Kim, W.L. Johnson: Microstructure controlled shear band formation and enhanced plasticity of bulk metallic glasses. Phys. Rev. Lett. 84, 2901 2000

    Article  CAS  Google Scholar 

  24. U. Kühn, J. Eckert, N. Mattern, L. Schultz: ZrNbCuNiAl bulk metallic glass matrix composites containing dendrite bcc phase precipitates. Appl. Phys. Lett. 80, 2478 2002

    Article  Google Scholar 

  25. Y. Zhang, W. Xu, H. Tan, Y. Li: Microstructure control and ductility improvement of La–Al–(Cu, Ni) composites by Bridgman solidification. Acta Mater. 53, 2607 2005

    Article  CAS  Google Scholar 

  26. H. Choi-Yim, R. Busch, U. Köster, W.L. Johnson: Synthesis and characterization of particulate reinforced Zr57Nb5Al10Cu15.4Ni12.6 bulk metallic glass composites. Acta Mater. 47, 2455 1999

    Article  CAS  Google Scholar 

  27. R.D. Conner, H. Choi-Yim, W.L. Johnson: Mechanical properties of Zr57Nb5Al10Cu15.4Ni12.6 metallic glass matrix particulate composites. J. Mater. Res. 14, 3292 1999

    Article  CAS  Google Scholar 

  28. C.P. Kim, R. Busch, A. Masuhr, H. Choi-Yim, W.L. Johnson: Processing of carbon-fiber-reinforced ZrTiCuNiBe bulk metallic glass composites. Appl. Phys. Lett. 79, 1456 2001

    Article  CAS  Google Scholar 

  29. J. Eckert, U. Kühn, N. Mattern, G. He, A. Gebert: Structural bulk metallic glasses with different length-scale of constituent phases. Intermetallics 10, 1183 2002

    Article  CAS  Google Scholar 

  30. M. Kusy, U. Kühn, A. Concustell, A. Gebert, J. Das, J. Eckert, L. Schultz, M.D. Baro: Fracture surface morphology of compressed bulk metallic glass-matrix-composites and bulk metallic glass. Intermetallics 14, 982 2006

    Article  CAS  Google Scholar 

  31. J.M. Park, Y.C. Kim, W.T. Kim, D.H. Kim: Ti-based bulk metallic glasses with high specific strength. Mater. Trans. 45, 595 2004

    Article  CAS  Google Scholar 

  32. F.R. De Boer, R. Boom, W.C.M. Mattens, A.R. Miedema, A.K. Niessen: Cohesion in Metals, (North-Holland, Amsterdam, 1989), p. 291

    Google Scholar 

  33. T.B. Massalski, H. Okamoto: Binary Alloy Phase Diagram ASM International Materials Park, OH 1990

    Google Scholar 

  34. JCPDFWIN Version 2.2, JCPDS, International Center for Diffraction Data: Newton Square, PA, 2001

    Google Scholar 

  35. Z.F. Zhang, G. He, J. Eckert, L. Schultz: Fracture mechanisms in bulk metallic glassy materials. Phys. Rev. Lett. 91, 045504 2003

    Article  Google Scholar 

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Acknowledgments

The authors are grateful to J.H. Na, K.R. Lim, J. Jayaraj, and J.S. Park for valuable discussions. This work was supported by the Global Research Laboratory Program of the Korea Ministry of Science and Technology. J.M. Park acknowledges the support from the Third Stage of Brain Korea 21 Project in 2008. E. Fleury is grateful for the grant (Code No.: 07K1501-00410) from the Center for Nanostructured Materials Technology under the “21st Century Frontier R&D Programs.”

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Correspondence to Do Hyang Kim.

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Park, J.M., Kim, D.H., Kim, K.B. et al. Enhancement of plasticity in Ti-rich Ti–Zr–Be–Cu–Ni–Ta bulk glassy alloy via introducing the structural inhomogeneity. Journal of Materials Research 23, 2984–2989 (2008). https://doi.org/10.1557/JMR.2008.0357

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  • DOI: https://doi.org/10.1557/JMR.2008.0357

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