Abstract
Hydrodynamic cavitation was shown to be a powerful tool for the synthesis of nanostructured catalysts, ceramics, and piezoelectrics in high phase purities. The macro-, micro-, and nano- properties of solid-state materials could be controlled through adjusting the cavitational regime during synthesis by simple mechanical adjustment. The synthesis of nanostructured titania, piezoelectrics, perovskites, supported and unsupported cobalt molybdates, and Pd and Ag supported on alumina illustrate changes in morphology and size of crystals, growth in a preferred orientation of crystallites, and control of crystallographic strain and size compared to classically prepared materials. The high shear and cavitational forces during synthesis induce micro-strain into the materials and are a function of the Reynolds and cavitation numbers.
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References
W.R. Moser, U.S. Patent No. 5 466 646 (1995).
W.R. Moser, U.S. Patent No. 5 417 956 (1995).
W.R. Moser, T. Giang, S. Nyguen, and O. Kozyuk, in Process Intensification for the Chemical Industry, edited by A. Green (BHR Group Publications, The Book Company, Suffolk, United Kingdom, 1999), Vol. 38, pp. 173–187.
K.S. Suslick, T. Hyeon, M. Fang, and A.A. Cichowlas, Mater. Sci. Eng. A A204, 186 (1995).
K.S. Suslick, Y. Didenko, M.M. Fang, T. Hyeon, K.J. Kolbeck, W.B. McNamara III, M.M. Mdleleni, and M. Wong, Philos. Trans. Roy. Soc. A 357, 335 (1999).
W.B. McNamara III, Y. Didenko, and K.S. Suslick, Nature 401, 772 (1999).
O.V. Kozyuk, A.A. Litvinenko, K, B.K. Kravets, and V.V. Berezin, U.S. Patent No. 5 492 654 (20 February 1996).
O.V. Kozyuk, U.S. Patent No. 5 969 207 (1999).
W. Kraus and G. Noltze, PowderCell for WINDOWS Version 2.3, Berlin, Germany (1999).
J.R. Young, Cavitation (McGraw Hill, New York, 1989).
G.K. Williamson and W.H. Hall, Acta Metall. 1, 22 (1953).
Powder Diffraction File-2 Sets 1–47, Card 18–117 (1997), Newtown Square, PA.
Powder Diffraction File -2 Sets 1–47, Card 37–381 (1997), New-town Square, PA.
Powder Diffraction File-2 Sets 1–47, Card 21–570 (1997), Newtown Square, PA.
R. Rajan, R. Kumar, and K.S. Gandhi, Chem. Eng. Sci. 3, 255 (1998).
D.V.P. Naidu, R. Rajan, R. Kumar, K.S. Gandhi, V.H. Arakeri, and S. Chandrasekaran, Chem. Eng. Sci. 49, 877 (1994).
T. Uchiyama, Appl. Math Modelling 22, 235 (1998).
E. Buckingham, Phys. Rev. 4, 345 (1914).
M.M. Mdleni, T. Hyeon, and K.S. Suslick, J. Am. Chem. Soc. 120, 6189 (1998).
J.R. Groza, S. H. Risbud, and K. Yamazaki, J. Mater. Res. 7, 2643 (1992).
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Find, J., Emerson, S., Krausz, I. et al. Hydrodynamic cavitation as a tool to control macro-, micro-, and nano-properties of inorganic materials. Journal of Materials Research 16, 3503–3513 (2001). https://doi.org/10.1557/JMR.2001.0481
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DOI: https://doi.org/10.1557/JMR.2001.0481