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Effects of Nano-sized Microalloyed Carbonitrides and High-density Pinned Dislocations on Sulfide Stress Cracking Resistance of Pipeline Steels

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Abstract

Sulfide stress cracking (SSC) resistance was investigated by comparing acicular ferrite (AF) and ferrite-pearlite (FP) in a microalloyed steel and in a non-microalloyedsteel. In microalloyed steel, AF exhibited better SSC resistance than FP, while in non-microalloyed steel, AF presented far worse SSC resistance than FP. In microalloyed steel, nano-sized carbonitrides and high-density pinned dislocations in AF were analyzed to behave as innocuous hydrogen traps, offering numerous sites for hydrogen redistribution and modifying critical cracking conditions. Dislocations in AF of microalloyed steel in the final analysis are attributed to pinning by the nano-sized carbonitrides.

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References

  1. T.S. Janzen and W.N. Horner: The alliance pipeline—A design short in long distance gas transmission, in Proc. International Pipeline Conf. (ASME, New York, NY, 1998), p. 83.

    Google Scholar 

  2. Workshops on the summarization of X70 grade pipeline steel trial productions. Dec. 18-21, 2000, Langfang, China (West-East Natural Gas Transportation Project Management Organization of Petrochina Co. Ltd. 2000), p. 3.

    Google Scholar 

  3. J.C. Charbonnier, H. Margot-Marette, A.M. Brass and M. Aucouturier: Sulfide stress cracking of high-strength modified Cr-Mo steels. Metall. Trans. A 16A, 935 (1985).

    Article  CAS  Google Scholar 

  4. H.F. Lopez, R. Raghunath, J.L. Albarran and L. Martinez: Microstructural aspects of sulfide stress cracking in an API X-80 pipeline steel. Metall. Mater. Trans. A 27A, 3601 (1996).

    Article  CAS  Google Scholar 

  5. NACE Standard TM0177-96. Laboratory Testing of Metals for Resistance to Specific Forms of Environmental Cracking in H2S Environments. (NACE International, Houston, TX, 1996).

    Google Scholar 

  6. Y. Zhang, Y. Wang, Y.B. Wang, W.Y. Chu and C.M. Hsiao: Hydrogen-induced cracking of Ti-24Al-11Nb at room-temperature. Scripta Metall. Mater. 29, 975 (1993).

    Article  CAS  Google Scholar 

  7. B.F. Brown: Stress Corrosion Cracking in High Strength Steels and in Titanium and Aluminum Alloys, edited by B.F. Brown (Washington, DC, 1972), p. 34.

  8. M.C. Zhao, K. Yang and Y.Y. Shan: The effects of thermo-mechanical control process on microstructures and mechanical properties of a commercial pipeline steel. Mater. Sci. Eng. A 335, 14 (2002).

    Article  Google Scholar 

  9. M.C. Zhao, K. Yang, F.R. Xiao and Y.Y. Shan: Continuous cooling transformation of undeformed and deformed low carbon pipeline steels. Mater. Sci. Eng. A 355, 126 (2003).

    Article  Google Scholar 

  10. Y.E. Smith, A.P. Coldren and R.L. Cryderman: Mn-Nb-Mo acicular ferrite steels, with high strength and toughness, in Toward Improved Ductility and Toughness (Climax Molybdenum Company, Tokyo, Japan, 1972), p. 119.

    Google Scholar 

  11. H.F. Lopez, R. Bharadwaj, J.L. Albarran and L. Martinez: The role of heat treating on the sour gas resistance of an X-80 steel for oil and gas transport. Metall. Mater. Trans. A 30A, 2419 (1999).

    Article  CAS  Google Scholar 

  12. H. Margot-Marette, G. Bardou and J.C. Charbonnier: The application of the slow strain rate test method for the development of linepipe steels resistant to sulfide stress cracking. Corros. Sci. 27, 1009 (1987).

    Article  CAS  Google Scholar 

  13. M.C. Zhao, B. Tang, Y.Y. Shan and K. Yang: Role of microstructure on sulfide stress cracking of oil and gas pipeline steels. Metall. Mater. Trans. A 34A, 1089 (2003).

    Article  CAS  Google Scholar 

  14. G.M. Pressouyre and I.M. Bernstein: Kinetic trapping model for hydrogen-induced cracking. Acta Metall. 27, 89 (1979).

    Article  CAS  Google Scholar 

  15. M.C. Zhao and K. Yang: Strengthening and improvement of sulfide stress cracking resistance in acicular ferrite pipeline steels by nano-sized carbonitrides. Scripta Mater. 52, 881 (2005).

    Article  CAS  Google Scholar 

  16. T. Tsuchida, T. Hara and K. Tsuzaki: Relationship between microstructure and hydrogen absorption behavior in a V-bearing high strength steel. Tetsu-to-Hagane 88, 771 (2002).

    Article  CAS  Google Scholar 

  17. P. Rozenak, I.M. Robertson and H.K. Birnbaum: HVEM studies of the effects of hydrogen on the deformation and fracture of aisi type 316 austenitic stainless-steel. Acta Metall. 38, 2031 (1990).

    Article  CAS  Google Scholar 

  18. G.M. Bond, I.M. Robertson and H.K. Birnbaum: Effects of hydrogen on deformation and fracture processes in high-purity aluminum. Acta Metall. 36, 2193 (1988).

    Article  CAS  Google Scholar 

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Correspondence to Ming-Chun Zhao.

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Zhao, MC., Yang, K. Effects of Nano-sized Microalloyed Carbonitrides and High-density Pinned Dislocations on Sulfide Stress Cracking Resistance of Pipeline Steels. Journal of Materials Research 20, 2248–2251 (2005). https://doi.org/10.1557/jmr.2005.0321

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  • DOI: https://doi.org/10.1557/jmr.2005.0321

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