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Formation of gold-coated magnetic nanoparticles using TiO2 as a bridging material

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Abstract

TiO2 nanoparticles with embedded magnetite were suspended in aqueous HAuCl4 and ultraviolet irradiated to photodeposit gold on the surface. The degree of gold coating and the wavelength of absorbance could be controlled by adjusting [HAuCl4]. Absorbance maxima were between 540-590 nm. Particles exhibited superparamagnetic properties (blocking temperature ~170 K) whether or not coated with gold. These particles have potential applications as drug delivery agents, magnetic imaging contrast agents, and magnetically separatable photocatalysts with unique surface properties.

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References

  1. J.L. Lyon, D.A. Fleming, B.B. Stone, P. Schiffer, M.E. Williams: Synthesis of Fe oxide core/Au shell nanoparticles by iterative hydroxylamine seeding. Nano Lett. 4, 719 (2004).

    Article  CAS  Google Scholar 

  2. L. Wang, J. Luo, M.M. Maye, Q. Fan, Q. Rendeng, M.H. Engelhard, C. Wang, Y. Lin, C.J. Zhong: Iron oxide-gold core-shell nanoparticles and thin film assembly. J. Mater. Chem. 15, 1821 (2005).

    Article  CAS  Google Scholar 

  3. D. Caruntu, G. Caruntu, Y. Chen, O’C.J. Connor, G. Goloverda, V.L. Kolesnichenko: Synthesis of variable-sized nanocrystals of Fe3O4 with high surface reactivity. Chem. Mater. 16, 5527 (2004).

    Article  CAS  Google Scholar 

  4. D. Caruntu, Y. Remond, N.H. Chou, M.J. Jun, G. Caruntu, J. He, G. Goloverda, O’C. Connor, V. Kolesnichenko: Reactivity of 3D transition metal cations in diethylene glycol solutions. synthesis of transition metal ferrites with the structure of discrete nanoparticles complexed with long-chain carboxylate anions. Inorg. Chem. 41, 6137 (2002).

    Article  CAS  Google Scholar 

  5. C.M. Fu, Y.F. Wang, Y.C. Chao, S.H. Hung, M.D. Yang: Directly labeling ferrite nanoparticles with Tc-99m radioisotope for diagnostic applications. IEEE Trans. Magn. 40, 3003 (2004).

    Article  CAS  Google Scholar 

  6. R.F. Service: Nanotechnology takes aim at cancer. Science 310, 1132 (2005).

    Article  Google Scholar 

  7. X. Gao, Y. Cui, R.M. Levenson, L.W.K. Chung, S. Nie: In vivo cancer targeting and imaging with semiconductor quantum dots. Nat. Biotechnol. 22, 969 (2004).

    Article  CAS  Google Scholar 

  8. H. Yu, M. Chen, P.M. Rice, S.X. Wang, R.L. White, S. Sun: Dumbbell-like bifunctional Au–Fe3O4 nanoparticles. Nano Lett. 5, 379 (2005).

    Article  CAS  Google Scholar 

  9. D. Caruntu, B.L. Cushing, G. Caruntu, O’C.J. Connor: Attachment of gold nanograins onto colloidal magnetite nanocrystals. Chem. Mater. 17, 3398 (2005).

    Article  CAS  Google Scholar 

  10. M. Mikhaylova, D.K. Kim, N. Bobrysheva, M. Osmolowsky, V. Semenov, T. Tsakalakos, M. Muhammed: Superparamagnetism of magnetite nanoparticles: Dependence on surface modification. Langmuir 20, 2472 (2004).

    Article  CAS  Google Scholar 

  11. M. Spasova, V. Salgueiriño-Maceira, A. Schlachter, M. Hilgendorff, M. Giersig, L.M. Liz-Marzán, M. Farle: Magnetite and optical tunable microsphere with a magnetic/gold nanoparticle shell. J. Mater. Chem. 15, 2095 (2005).

    Article  CAS  Google Scholar 

  12. D. Beydoun, R. Amal, G.K.C. Low, S. McEvoy: Novel photocatalyst: Titania-coated magnetite. Activity and photodissolution. J. Phys. Chem. B 104, 4387 (2000).

    Article  CAS  Google Scholar 

  13. M. Jakob, H. Levanon: Charge distribution between UV-irradiated TiO2 and gold nanoparticles: Determination of shift in the fermi level. Nano Lett. 3, 353 (2003).

    Article  CAS  Google Scholar 

  14. H. Haick, Y. Paz: Long-range effects of noble metals on the photocatalytic properties of titanium dioxide. J. Phys. Chem. B 107, 2319 (2003).

    Article  CAS  Google Scholar 

  15. I.M. Arabatzis, T. Stergiopoulos, D. Andreeva, S. Kitova, S.G. Neophytides, P. Falaras: Characterization and photocatalytic activity of Au/TiO2 thin films for azo-dye degradation. J. Catal. 220, 127 (2003).

    Article  CAS  Google Scholar 

  16. M. Jakob, H. Levanon: Charge distribution between UV-irradiated TiO2 and gold nanoparticles: Determination of shift in the Fermi level. Nano Lett. 3, 353 (2003).

    Article  CAS  Google Scholar 

  17. K. Malik, M. Mandal, N. Pradhan, T. Pal: Seed mediated formation of bimetallic nanoparticles by UV irradiation: A photochemical approach for the preparation of “core-shell” type structures. Nano Lett. 1, 319 (2001).

    Article  Google Scholar 

  18. J. Rodriguez, G. Liu, R. Jirsak, J. Hrbek, Z. Chang, J. Dvorak, A. Maiti: Activation of gold on titania: Adsorption and reaction of SO2 on Au/TiO2(110). J. Am. Chem. Soc. 124, 5242 (2002).

    Article  CAS  Google Scholar 

  19. Y. Iizuka, T. Tode, T. Takao, K. Yatsu, T. Takeuchi, S. Tsubota, M. Haruta: A kinetic and adsorption study of CO oxidation over unsupported fine gold powder and over gold supported on titanium dioxide. J. Catal. 187, 50 (1999).

    Article  CAS  Google Scholar 

  20. T.V. Choudhary, C. Sivadinarayana, C.C. Chusuei, A.K. Datye, J.P. Fackler Jr., D.W. Goodman: CO oxidation on supported nano-Au catalysts synthesized from a [Au6(PPh3)6](BF4)2 complex. J. Catal. 207, 247 (2002).

    Article  CAS  Google Scholar 

  21. H. Kominami, T. Nakaseko, Y. Shimida, A. Furusho, H. Inoue, S. Murakami, Y. Kera, B. Ohtani: Selective photocatalytic reduction of nitrate to nitrogen molecules in an aqueous suspension of metal-loaded titanium(IV) oxide particles. Chem. Commun. 2933 (2005).

    Google Scholar 

  22. G. Shemer, G. Markovich: Enhancement of magneto-optical effects in magnetite nanocrystals near gold surfaces. J. Phys. Chem. B 106, 9195 (2002).

    Article  CAS  Google Scholar 

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Correspondence to Matthew A. Tarr.

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Oliva, B.L., Pradhan, A., Caruntu, D. et al. Formation of gold-coated magnetic nanoparticles using TiO2 as a bridging material. Journal of Materials Research 21, 1312–1316 (2006). https://doi.org/10.1557/jmr.2006.0163

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  • DOI: https://doi.org/10.1557/jmr.2006.0163

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