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Facile preparation of superhydrophobic and superoleophilic sponge for fast removal of oils from water surface

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Abstract

The removal of oil spills or oily organic solvents from water surface is a great technological challenge for environmental protection. Here, a facile method to prepare superhydrophobic and superoleophilic sponge for fast and selective removal of oils from water surface has been reported. The as-prepared sponge exhibited superhydrophobic property with the water contact angle around 165°, which can be used for the absorption of oil spills or oily organic solvents. Furthermore, the resultant sponge showed good durability toward temperature. This fabrication technique is easy to grasp and to be extended. So we believe that this new functionalized sponge could be realized for the large-scale commercialized production.

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References

  1. J. Yuan, X. Liu, O. Akbulut, J. Hu, S. Suib, J. Kong, and F. Stellacci: Superwetting nanowire membranes for selective absorption. Nat. Nanotechnol. 3, 332 (2008).

    Article  CAS  Google Scholar 

  2. A. Rao, N. Hegde, and H. Hirashima: Absorption and desorption of organic liquids in elastic superhydrophobic silica aerogels. J. Colloid Interface Sci. 305, 124 (2007).

    Article  Google Scholar 

  3. Y. Liu, L. Jiang, H. Dong, Z. Tang, and W. Hu: Large-area single-crystalline nanocone arrays of an organic charge-transfer complex: Controlling growth, characterization, and applications. Small 7, 1412 (2011).

    Article  CAS  Google Scholar 

  4. D. Ishii, H. Yabu, and M. Shimomura: Novel biomimetic surface based on a self-organized metal-polymer hybrid structure. Chem. Mater. 21, 1799 (2009).

    Article  CAS  Google Scholar 

  5. H. Zhu, S. Qiu, W. Jiang, D. Wu, and C. Zhang: Evaluation of electrospun polyvinyl chloride/polystyrene fibers as sorbent materials for oil spill cleanup. Environ. Sci. Technol. 45, 4527 (2011).

    Article  CAS  Google Scholar 

  6. C. Wang, F. Tzeng, H. Chen, and C. Chang: Ultraviolet-durable superhydrophobic zinc oxide-coated mesh films for surface and underwater-oil capture and transportation. Langmuir 28, 10015 (2012).

    Article  CAS  Google Scholar 

  7. L. Zhang, J. Wu, Y. Wang, Y. Long, N. Zhao, and J. Xu: Combination of bioinspiration: A general route to superhydrophobic particles. J. Am. Chem. Soc. 134, 9879 (2012).

    Article  CAS  Google Scholar 

  8. X. Liu, Y. Liang, F. Zhou, and W. Liu: Extreme wettability and tunable adhesion: Biomimicking beyond nature? Soft Matter 8, 2070 (2012).

    Article  Google Scholar 

  9. M. Guix, J. Orozco, M. García, W. Gao, S. Sattayasamitsathit, A. Merkoç, A. Escarpa, and J. Wang: Superhydrophobic alkanethiol-coated microsubmarines for effective removal of oil. ACS Nano 6, 4445 (2012).

    Article  CAS  Google Scholar 

  10. T. Nguyen, F. Simon, N. Khan, M. Schmutz, and P. Mésini: Formation of reactive aerogels and their reactivity in aqueous media. Wettability induces hydrophobic vs. hydrophilic selectivity. J. Mater. Chem. 22, 7712 (2012).

    Article  CAS  Google Scholar 

  11. M. Cheng, Y. Gao, X. Guo, Z. Shi, J. Chen, and F. Shi: A functionally integrated device for effective and facile oil spill cleanup. Langmuir 27, 7371 (2011).

    Article  CAS  Google Scholar 

  12. Q. Zhu, Q. Pan, and F. Liu: Facile removal and collection of oils from water surfaces through superhydrophobic and superoleophilic sponges. J. Phys. Chem. C 115, 17464 (2011).

    Article  CAS  Google Scholar 

  13. J. Li, L. Shi, Y. Chen, Y. Zhang, Z. Guo, B. Su, and W. Liu: Stable superhydrophobic coatings from thiol-ligand nanocrystals and their application in oil/water separation. J. Mater. Chem. 22, 9774 (2012).

    Article  CAS  Google Scholar 

  14. W. Choi, A. Tuteja, S. Chhatre, J. Mabry, R. Cohen, and G. McKinley: Fabrics with tunable oleophobicity. Adv. Mater. 21, 2190 (2009).

    Article  CAS  Google Scholar 

  15. T. Stoebe, Z. Lin, R. Hill, M. Ward, and H. Davis: Superspreading of aqueous films containing trisiloxane surfactant on mineral oil. Langmuir 13, 7282 (1997).

    Article  CAS  Google Scholar 

  16. L. Rossi, L. Shi, F. Quina, and Z. Rosenzweig: Stöber synthesis of monodispersed luminescent silica nanoparticles for bioanalytical assays. Langmuir 21, 4277 (2005).

    Article  CAS  Google Scholar 

  17. K. Nozawa, H. Gailhanou, L. Raison, P. Panizza, H. Ushiki, E. Sellier, J. Delville, and M.H. Delville: Smart control of monodisperse Stöber silica particles: Effect of reactant addition rate on growth process. Langmuir 21, 151 (2005).

    Article  Google Scholar 

  18. P. Calcagnile, D. Fragouli, I. Bayer, G. Anyfantis, L. Martiradonna, P. Cozzoli, R. Cingolani, and A. Athanassiou: Magnetically driven floating foams for the removal of oil contaminants from water. ACS Nano 6, 5413 (2012).

    Article  CAS  Google Scholar 

  19. E. Burkarter, C. Saul, F. Thomazi, N. Cruz, L. Roman, and W. Schreiner: Superhydrophobic electrosprayed PTFE. Surf. Coat. Technol. 202, 194 (2007).

    Article  CAS  Google Scholar 

  20. D. Xu, M. Wang, X. Ge, M. Lam, and X. Ge: Fabrication of raspberry SiO2/polystyrene particles and superhydrophobic particulate film with high adhesive force. J. Mater. Chem. 22, 5784 (2012).

    Article  CAS  Google Scholar 

  21. H. Teisala, M. Tuominen, M. Aromaa, M. Stepien, J. Mäkelä, and J. Jarkko: Nanostructures increase water droplet adhesion on hierarchically rough superhydrophobic surfaces. Langmuir 28, 3138 (2012).

    Article  CAS  Google Scholar 

  22. R. David and A. Neumann: Computation of the wetting properties of randomly structured superhydrophobic surfaces. J. Phys. Chem. C 116, 2362 (2012).

    Google Scholar 

  23. L. Zhang, R. Dillert, D. Bahnemann, and M. Vormoor: Photo-induced hydrophilicity and self-cleaning: models and reality. Energy Environ. Sci. 5, 7491 (2012).

    Article  CAS  Google Scholar 

  24. H. Park, S. Yoon, and Y. Do: Superhydrophobicity of 2D SiO2 hierarchical micro/nanorod structures fabricated using a two-step micro/nanosphere lithography. J. Mater. Chem. 22, 14035 (2012).

    Article  CAS  Google Scholar 

  25. A. Rawlings, J. Bramble, and S. Staniland: Innovation through imitation: Biomimetic, bioinspired and biokleptic research. Soft Matter 8, 6675 (2012).

    Article  CAS  Google Scholar 

  26. G. Gong, J. Wu, J. Liu, N. Sun, Y. Zhao, and L. Jiang: Bio-inspired adhesive superhydrophobic polyimide mat with high thermal stability. J. Mater. Chem. 22, 8257 (2012).

    Article  CAS  Google Scholar 

  27. L. Hao, Z. Chen, R. Wang, C. Guo, P. Zhang, and S. Pang: A non-aqueous electrodeposition process for fabrication of superhydrophobic surface with hierarchical micro/nano structure. Appl. Surf. Sci. 258, 8970 (2012).

    Article  CAS  Google Scholar 

  28. H. Fan, N. Zhao, H. Wang, X. Li, and J. Xu: One step preparation of polyaniline micro/nanohierarchical structures with superhydrophobicity. Mater. Lett. 78, 42 (2012).

    Article  CAS  Google Scholar 

  29. L. Wu, Q. Shao, X. Wang, H. Zheng, and C. Wong: Hierarchical structured sol-gel coating by laser textured template imprinting for surface superhydrophobicity. Soft Matter 8, 6232 (2012).

    Article  CAS  Google Scholar 

  30. J. Wang, Q. Yang, M. Wang, C. Wang, and L. Jiang: Rose petals with a novel and steady air bubble pinning effect in aqueous media. Soft Matter 8, 2261 (2012).

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

This work was financially supported by the Qianjiang Talents Project of Zhejiang Province (Grant No. 2010R10023), the Scientific Research Foundation for the Returned Overseas Chinese Scholars, the State Education Ministry (Grant No. 1001603-C), the Natural Science Foundation of Zhejiang Province (Grant No. Y4100045), Training Foundation for the Excellent Young Talents by the Key Laboratory of Advanced Textile Materials and Manufacturing Technology (ATMT), Ministry of Education (Grant No. 2011QN04), and the National Natural Science Foundation of China (Grant No. 51133006).

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Correspondence to Guohua Jiang.

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Jiang, G., Hu, R., Xi, X. et al. Facile preparation of superhydrophobic and superoleophilic sponge for fast removal of oils from water surface. Journal of Materials Research 28, 651–656 (2013). https://doi.org/10.1557/jmr.2012.410

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  • DOI: https://doi.org/10.1557/jmr.2012.410

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