Skip to main content
Log in

Preparation of Mn-doped BiOBr microspheres for efficient visible-light-induced photocatalysis

  • Research Letters
  • Published:
MRS Communications Aims and scope Submit manuscript

Abstract

Mn-doped bismuth oxide bromide microspheres have been prepared by the hydrothermal method. The resultant composite microspheres exhibited higher photocatalytic activity under visible light irradiation, attributing to the improvement of the photo-absorption property and the separation efficiency of photogenerated electrons and holes. The holes and O2•− are the main active species in aqueous solution under visible light irradiation, rather than •OH.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Figure 1
Figure 2
Figure 3

Similar content being viewed by others

References

  1. X. Shen, Z. Zhang, B. Zhou, J. Peng, M. Xie, M. Zhang, and D. Pang: Visible light-induced plasmid DNA damage catalyzed by a CdSe/ZnS-photosensitized nano-TiO2 film. Environ. Sci. Technol. 42, 5049 (2008).

    Article  CAS  Google Scholar 

  2. S.S. Turkar, D.B. Bharti, and G.S. Gaikwad: Various methods involved in waste water treatment to control water pollution. J. Chem. Pharm. Res. 3, 58 (2011).

    CAS  Google Scholar 

  3. P. Gustavo and B. Damià: Photosensitized degradation of organic pollutants in water: processes and analytical applications. TrAC, Trends Anal. Chem. 17, 605 (1998).

    Article  Google Scholar 

  4. C. He, M.A. Asi, Y. Xiong, D. Shu, and X. Li: Photoelectrocatalytic degradation of organic pollutants in aqueous solution using a Pt-TiO2 Film. Int. J. Photoenergy 2009, 634369 (2009).

    Article  Google Scholar 

  5. C. Galindo, P. Jacques, and A. Kalt: Photochemical and photocatalytic degradation of an indigoid dye: a case study of acid blue 74 (AB74). J. Photochem. Photobiol., A 141, 47 (2001).

    Article  CAS  Google Scholar 

  6. D. Chatterjee and A. Mahata: Visible light induced photodegradation of organic pollutants on dye adsorbed TiO2 surface. J. Photochem. Photobiol., A 153, 199 (2002).

    Article  CAS  Google Scholar 

  7. R. Wang, G. Jiang, Y. Ding, Y. Wang, X. Sun, X. Wang, and W. Chen: Photocatalytic activity of heterostructures based on TiO2 and halloysite nanotubes. ACS Appl. Mater. Interfaces 3, 4154 (2011).

    Article  CAS  Google Scholar 

  8. Z. Zainal, L.K. Hui, M.Z. Hussein, A.H. Abdullah, and I.R. Hamadneh: Characterization of TiO2-chitosan/glass photocatalyst for the removal of a monoazo dye via photodegradation-adsorption process. J. Hazard. Mater. 164, 138 (2009).

    Article  CAS  Google Scholar 

  9. G. Jiang, X. Wang, Y. Zhou, R. Wang, R. Hu, X. Xi, and W. Chen: Hollow TiO2 nanocages with rubik-like structure for high-performance photocatalysts. Mater. Lett. 89, 59 (2012).

    Article  CAS  Google Scholar 

  10. G. Jiang and J. Zeng: Preparation of nano-TiO2/polystyrene hybrid microspheres and their antibacterial properties. J. Appl. Polym. Sci. 116, 779 (2010).

    CAS  Google Scholar 

  11. Y. Xie and C. Yuan: Photocatalysis of neodymium ion modified TiO2 sol under visible light irradiation. Appl. Surf. Sci. 221, 17 (2004).

    Article  CAS  Google Scholar 

  12. L. Chen, F. Chen, Y. Shi, and J. Zhang: Preparation and visible light photocatalytic activity of a graphite-like carbonaceous surface modified TiO2 photocatalyst. J. Phys. Chem. C 116, 8579 (2012).

    Article  CAS  Google Scholar 

  13. K. Kalyanasundaram and M. Grätzel: Applications of functionalized transition metal complexes in photonic and optoelectronic devices. Coord. Chem. Rev. 77, 347 (1998).

    Article  Google Scholar 

  14. Z. Li, W. Luo, M. Zhang, J. Feng, and Z. Zou: Photoelectrochemical cells for solar hydrogen production: current state of promising photoelectrodes, methods to improve their properties, and outlook. Energy Environ. Sci. 6, 347 (2013).

    Article  CAS  Google Scholar 

  15. A. Primo, A. Corma, and H. García: Titania supported gold nanoparticles as photocatalyst. Phys. Chem. Chem. Phys. 13, 886 (2011).

    Article  CAS  Google Scholar 

  16. Y. Zhao, M. Wei, J. Lu, Z. Wang, and X. Duan: Biotemplated hierarchical nanostructure of layered double hydroxides with improved photocatalysis performance. ACS Nano 3, 4009 (2009).

    Article  CAS  Google Scholar 

  17. C. Yu, K. Yang, Y. Xie, Q. Fan, J. Yu, Q. Shu, and C. Wang: Novel hollow Pt-ZnO nanocomposite microspheres with hierarchical structure and enhanced photocatalytic activity and stability. Nanoscale 5, 2142 (2013).

    Article  CAS  Google Scholar 

  18. J. Zhu, Y. Cao, Z. Bian, S. Wang, Y. Huo, H. Li, and Y. Lu: Synthesis of photocatalytic TiO2 with controlled hierarchical structure by alcohol-induced assembly. Sci. Sin. Chim. 42, 1627 (2012).

    Article  CAS  Google Scholar 

  19. Y. Li, J. Liu, and X. Huang: Synthesis and visible-light photocatalytic property of Bi2WO6 hierarchical octahedron-like structures. Nanoscale Res. Lett. 3, 365 (2008).

    Article  CAS  Google Scholar 

  20. H. Zhang, L. Liu, and Z. Zhou: First-principles studies on facet-dependent photocatalytic properties of bismuth oxyhalides (BiOXs). RSC Adv. 2, 9224 (2012).

    Article  CAS  Google Scholar 

  21. H. Zhang, L. Liu, and Z. Zhou: Towards better photocatalysts: first-principles studies of the alloying effects on the photocatalytic activities of bismuth oxyhalides under visible light. Phys. Chem. Chem. Phys. 4, 1286 (2012).

    Article  Google Scholar 

  22. G. Jiang, R. Wang, X. Wang, R. Hu, X. Xi, Y. Zhou, S. Wang, T. Wang, and W. Chen: Novel highly active visible-light-induced photocatalysts based on BiOBr with Ti doping and Ag decorating. ACS Appl. Mater. Interfaces 4, 4440 (2012).

    Article  CAS  Google Scholar 

  23. R. Wang, G. Jiang, X. Wang, R. Hu, X. Xi, Y. Zhou, S. Bao, T. Tong, S. Wang, T. Wang, and W. Chen: Efficient visible-light-induced photocatalytic activity over the novel Ti-doped BiOBr Microspheres. Powder Technol. 228, 258 (2012).

    Article  CAS  Google Scholar 

  24. G. Jiang, X. Wang, Z. Wei, X. Li, X. Xi, R. Hu, B. Tang, R. Wang, S. Wang, T. Wang, and W. Chen: Photocatalytic property of hierarchical structure based on Fe-doped BiOBr hollow microspheres. J. Mater. Chem. A 1, 2406 (2013).

    Article  CAS  Google Scholar 

  25. W. Yao and S. Yu: Recent advances in hydrothermal syntheses of low dimensional nanoarchitectures. Int. J. Nanotechnol. 4, 129 (2007).

    Article  CAS  Google Scholar 

  26. H. Deng, J. Wang, Q. Peng, X. Wang, and Y. Li: Controlled hydrothermal synthesis of bismuth oxyhalide nanobelts and nanotubes. Chem. Eur. J. 11, 6519 (2005).

    Article  CAS  Google Scholar 

  27. Z. Jiang, F. Yang, G. Yang, L. Kong, M.O. Jones, T. Xiao, and P.P. Edwards: The hydrothermal synthesis of BiOBr flakes for visible-light-responsive photocatalytic degradation of methyl orange. J. Photochem. Photobiol. A 212, 8 (2010).

    Article  CAS  Google Scholar 

  28. S. Song, W. Gao, X. Wang, X. Li, D. Liu, Y. Xing, and H. Zhang: Microwave-assisted synthesis of BiOBr/graphene nanocomposites and their enhanced photocatalytic activity. Dalton Trans. 41, 10472 (2012).

    Article  CAS  Google Scholar 

  29. J. Cao, B. Xu, H. Lin, B. Luo, and S. Chen: Chemical etching preparation of BiOI/BiOBr heterostructures with enhanced photocatalytic properties for organic dye removal. Chem. Eng. J. 91, 185 (2012).

    Google Scholar 

  30. J.L. Rao, B.D.P. Raju, N.O. Gopal, and K.V. Narasimhulu: Electron paramagnetic resonance and optical absorption studies on Mn2+ ions doped in KZnClSO4·3H2O single crystals. Phys. B 355, 207 (2012).

    Article  Google Scholar 

  31. L. Ye, J. Liu, C. Gong, L. Tian, T. Peng, and L. Zan: Two different roles of metallic Ag on Ag/AgX/BiOX (X = Cl, Br) visible light photocatalysts: surface plasmon resonance and Z-scheme bridge. ACS Catal. 2, 1677 (2012).

    Article  CAS  Google Scholar 

  32. Y. Abdollahi, A.H. Abdullah, Z. Zainal, and N.A. Yusof: Synthesis and characterization of Manganese doped ZnO nanoparticles. Inter. J. Basic Appl. Sci. 11, 62 (2011).

    Google Scholar 

  33. L. Liu, R. Zuo, Q. Sun, and Q. Liang: Structure and electrical properties of Mn doped Bi(Mg1/2Ti1/2)O3-PbTiO3 ferroelectric thin films. Appl. Surf Sci. 268, 327 (2013).

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, the State Education Ministry (1001603-C), the “521 Talents Training Plan” in ZSTU, the National Natural Science Foundation of China (51133006), and Public Technological Research Project of Zhejiang Province (2012C21098). Z. W. thanks the Innovative Program for Graduate Students of Zhejiang Sci-Tech University through Grant YCX12007.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guohua Jiang.

Supplementary materials

Supplementary materials

For supplementary material for this article, please visit {rs|http://dx.doi.org/10.1557/mrc.2013.29|url|}

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wei, Z., Jiang, G., Shen, L. et al. Preparation of Mn-doped BiOBr microspheres for efficient visible-light-induced photocatalysis. MRS Communications 3, 145–149 (2013). https://doi.org/10.1557/mrc.2013.29

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/mrc.2013.29

Navigation