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Three-dimensional lithography by elasto-capillary engineering of filamentary materials

  • Patterning via Self-organization and Self-folding
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Abstract

Surface textures with three-dimensional (3D) architectures demonstrate the ability to control interfacial, optical, chemical, and mechanical properties. Potential applications range from device-scale biomolecule sensing to meter-scale optical or nonwetting coatings. In recent years, capillary forming has become a versatile and scalable approach to creating complex geometries at the nano- and micron scales. Surface tension of a liquid can deform straight pillars and assemble them into 3D architectures with predetermined orientation, where short-range adhesion forces stabilize the final forms. A variety of techniques have been demonstrated for carbon nanotubes and polymer filamentary materials to fabricate useful devices and textures. We discuss these materials and processes as well as the underlying elasto-capillary physics. We indicate the need for new simulation tools to design and engineer elasto-capillary transformations and methods to increase their throughput toward scalable manufacturing.

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References

  1. J.A. Liddle, G.M. Gallatin, Nanoscale 3 (7), 2679 (2011).

    Article  CAS  Google Scholar 

  2. K.-H. Chu, R. Xiao, E.N. Wang, Nat. Mater. 9 (5), 413 (2010).

    Article  CAS  Google Scholar 

  3. C.L. Pint, K. Takei, R. Kapadia, M. Zheng, A.C. Ford, J. Zhang, A. Jamshidi, R. Bardhan, J.J. Urban, M. Wu, J.W. Ager, M.M. Oye, A. Javey, Adv. Energy Mater. 1 (6), 1040 (2011).

    Article  CAS  Google Scholar 

  4. A.T. Paxson, K.K. Varanasi, Nat. Commun. 4, 1492 (2013).

    Article  CAS  Google Scholar 

  5. J.K. Gansel, M. Thiel, M.S. Rill, M. Decker, K. Bade, V. Saile, G. von Freymann, S. Linden, M. Wegener, Science 325 (5947), 1513 (2009).

    Article  CAS  Google Scholar 

  6. J. Mei, G. Ma, M. Yang, Z. Yang, W. Wen, P. Sheng, Nat. Commun. 3, 756 (2012).

    Article  CAS  Google Scholar 

  7. Y. Zhao, M.A. Belkin, A. Alù, Nat. Commun. 3, 870 (2012).

    Article  CAS  Google Scholar 

  8. M. De Volder, A.J. Hart, Angew. Chem. Int. Ed. 52 (9), 2412 (2013).

    Article  CAS  Google Scholar 

  9. B. Roman, J. Bico, J. Phys. Condens. Matter 22, 493101 (2010).

    Article  CAS  Google Scholar 

  10. Y. Hu, Z. Lao, B.P. Cumming, D. Wu, J. Li, H. Liang, J. Chu, W. Huang, M. Gu, Proc. Natl. Acad. Sci. U.S.A. 112 (22), 6876 (2015).

    Article  CAS  Google Scholar 

  11. D. Copic, S.J. Park, S. Tawfick, M. De Volder, A.J. Hart, Lab Chip 11 (10), 1831 (2011).

    Article  CAS  Google Scholar 

  12. Y. Hayamizu, T. Yamada, K. Mizuno, R.C. Davis, D.N. Futaba, M. Yumura, K. Hata, Nat. Nanotechnol. 3 (5), 289 (2008).

    Article  CAS  Google Scholar 

  13. S. Tawfick, M. De Volder, A.J. Hart, Langmuir 27 (10), 6389 (2011).

    Article  CAS  Google Scholar 

  14. P.O. Vaccaro, K. Kubota, T. Fleischmann, S. Saravanan, T. Aida, Microelectron. J. 34 (5–8), 447 (2003).

    Article  CAS  Google Scholar 

  15. X. Guo, H. Li, B. Yeop Ahn, E.B. Duoss, K.J. Hsia, J.A. Lewis, R.G. Nuzzo, Proc. Natl. Acad. Sci. U.S.A. 106 (48), 20149 (2009).

    Article  CAS  Google Scholar 

  16. T.G. Leong, A.M. Zarafshar, D.H. Gracias, Small 6 (7), 792 (2010).

    Article  CAS  Google Scholar 

  17. G.M. Whitesides, B. Grzybowski, Science 295 (5564), 2418 (2002).

    Article  CAS  Google Scholar 

  18. N. Bowden, S. Brittain, A.G. Evans, J.W. Hutchinson, G.M. Whitesides, Nature 393 (6681), 146 (1998).

    Article  CAS  Google Scholar 

  19. C. Duprat, S. Protiere, A.Y. Beebe, H.A. Stone, Nature 482 (7386), 510 (2012).

    Article  CAS  Google Scholar 

  20. R. Maboudian, R.T. Howe, J. Vac. Sci. Technol. B 15 (1), 1 (1997).

    Article  CAS  Google Scholar 

  21. P. Lambert, M. Mastrangeli, J.-B. Valsamis, G. Degrez, Microfluid. Nanofluid. 9 (4–5), 797 (2010).

    Article  Google Scholar 

  22. A. Legrain, T.G. Janson, J.W. Berenschot, L. Abelmann, N.R. Tas, J. Appl. Phys. 115 (21), 214905 (2014).

    Article  CAS  Google Scholar 

  23. J.G. Fan, D. Dyer, G. Zhang, Y.P. Zhao, Nano Lett. 4 (11), 2133 (2004).

    Article  CAS  Google Scholar 

  24. B. Pokroy, S.H. Kang, L. Mahadevan, J. Aizenberg, Science 323 (5911), 237 (2009).

    Article  CAS  Google Scholar 

  25. N.R. Bernardino, V. Blickle, S. Dietrich, Langmuir 26 (10), 7233 (2010).

    Article  CAS  Google Scholar 

  26. M.K. Dawood, H. Zheng, T.H. Liew, K.C. Leong, Y.L. Foo, R. Rajagopalan, S.A. Khan, W.K. Choi, Langmuir 27 (7), 4126 (2011).

    Article  CAS  Google Scholar 

  27. M.K. Smith, V. Singh, K. Kalaitzidou, B.A. Cola, ACS Nano 9 (2), 1080 (2015).

    Article  CAS  Google Scholar 

  28. A. Grinthal, S.H. Kang, A.K. Epstein, M. Aizenberg, M. Khan, J. Aizenberg, Nano Today 7 (1), 35 (2012).

    Article  CAS  Google Scholar 

  29. N. Chakrapani, B. Wei, A. Carrillo, P.M. Ajayan, R.S. Kane, Proc. Natl. Acad. Sci. U.S.A. 101 (12), 4009 (2004).

    Article  CAS  Google Scholar 

  30. H. Liu, S.H. Li, J. Zhai, H.J. Li, Q.S. Zheng, L. Jiang, D.B. Zhu, Angew. Chem. Int. Ed. 43 (9), 1146 (2004).

    Article  CAS  Google Scholar 

  31. A.E. Cohen, L. Mahadevan, Proc. Natl. Acad. Sci. U.S.A. 100 (21), 12141 (2003).

    Article  CAS  Google Scholar 

  32. J.-L. Liu, X.-Q. Feng, Acta Mech. Sin. 28 (4), 928 (2012).

    Article  Google Scholar 

  33. S.J. Chae, F. Güneş, K.K. Kim, E.S. Kim, G.H. Han, S.M. Kim, H.-J. Shin, S.-M. Yoon, J.-Y. Choi, M.H. Park, C.W. Yang, D. Pribat, Y.H. Lee, Adv. Mater. 21 (22), 2328 (2009).

    Article  CAS  Google Scholar 

  34. H. Duan, J.K. Yang, K.K. Berggren, Small 7 (18), 2661 (2011).

    Article  CAS  Google Scholar 

  35. J. Bico, B. Roman, L. Moulin, A. Boudaoud, Nature 432 (7018), 690 (2004).

    Article  CAS  Google Scholar 

  36. H.Y. Kim, L. Mahadevan, J. Fluid Mech. 548, 141 (2006).

    Article  Google Scholar 

  37. C. Py, R. Bastien, J. Bico, B. Roman, A. Boudaoud, Europhys. Lett. 77, 44005 (2007).

    Article  CAS  Google Scholar 

  38. D. Chandra, S. Yang, Acc. Chem. Res. 43, 1080 (2010).

    Article  CAS  Google Scholar 

  39. Y.P. Zhao, J.G. Fan, Appl. Phys. Lett. 88 (10), 103123 (2006).

    Article  CAS  Google Scholar 

  40. D. Chandra, S. Yang, Langmuir 25 (18), 10430 (2009).

    Article  CAS  Google Scholar 

  41. M.A. Correa-Duarte, N. Wagner, J. Rojas-Chapana, C. Morsczeck, M. Thie, M. Giersig, Nano Lett. 4 (11), 2233 (2004).

    Article  CAS  Google Scholar 

  42. F. Chiodi, B. Roman, J. Bico, Europhys. Lett. 90, 44006 (2010).

    Article  CAS  Google Scholar 

  43. N.J. Glassmaker, A. Jagota, C.-Y. Hui, J. Kim, J. R. Soc. Interface 1 (1), 23 (2004).

    Article  CAS  Google Scholar 

  44. P. Roca-Cusachs, F. Rico, E. Martínez, J. Toset, R. Farré, D. Navajas, Langmuir 21 (12), 5542 (2005).

    Article  CAS  Google Scholar 

  45. F. Delrio, M. De Boer, J. Knapp, E. Reedy, P. Clews, M. Dunn, Nat. Mater. 4 (8), 629 (2005).

    Article  CAS  Google Scholar 

  46. S.H. Kang, B. Pokroy, L. Mahadevan, J. Aizenberg, ACS Nano 4 (11), 6323 (2010).

    Article  CAS  Google Scholar 

  47. M.K. Chaudhury, T. Weaver, C.Y. Hui, E.J. Kramer, J. Appl. Phys. 80 (1), 30 (1996).

    Article  CAS  Google Scholar 

  48. D.N. Futaba, K. Hata, T. Yamada, T. Hiraoka, Y. Hayamizu, Y. Kakudate, O. Tanaike, H. Hatori, M. Yumura, S. Iijima, Nat. Mater. 5 (12), 987 (2006).

    Article  CAS  Google Scholar 

  49. T. Yamada, T. Namai, K. Hata, D.N. Futaba, K. Mizuno, J. Fan, M. Yudasaka, M. Yumura, S. Iijima, Nat. Nanotechnol. 1 (2), 131 (2006).

    Article  CAS  Google Scholar 

  50. M. De Volder, S.H. Tawfick, S.J. Park, D. Copic, Z. Zhao, W. Lu, A.J. Hart, Adv. Mater. 22 (39), 4384 (2010).

    Article  CAS  Google Scholar 

  51. H. Duan, K.K. Berggren, Nano Lett. 10 (9), 3710 (2010).

    Article  CAS  Google Scholar 

  52. S.H. Kang, N. Wu, A. Grinthal, J. Aizenberg, Phys. Rev. Lett. 107 (17), 177802 (2011).

    Article  CAS  Google Scholar 

  53. D. Chandra, S. Yang, A.A. Soshinsky, R.J. Gambogi, ACS Appl. Mater. Interfaces 1 (8), 1698 (2009).

    Article  CAS  Google Scholar 

  54. P. Vukusic, B. Hallam, J. Noyes, Science 315 (5810), 348 (2007).

    Article  CAS  Google Scholar 

  55. S.J. Barcelo, A. Kim, W. Wu, Z. Li, ACS Nano 6 (7), 6446 (2012).

    Article  CAS  Google Scholar 

  56. E. Hao, G.C. Schatz, J. Chem. Phys. 120 (1), 357 (2004).

    Article  CAS  Google Scholar 

  57. K.L. Wustholz, A.I. Henry, J.M. McMahon, R.G. Freeman, N. Valley, M.E. Piotti, M.J. Natan, G.C. Schatz, R.P. Van Duyne, J. Am. Chem. Soc. 132 (31), 10903 (2010).

    Article  CAS  Google Scholar 

  58. Y. Fang, N.H. Seong, D.D. Dlott, Science 321 (5887), 388 (2008).

    Article  CAS  Google Scholar 

  59. A. Kim, S.J. Barcelo, R.S. Williams, Z. Li, Anal. Chem. 84 (21), 9303 (2012).

    Article  CAS  Google Scholar 

  60. M. Hu, F.S. Ou, W. Wu, I. Naumov, X. Li, A.M. Bratkovsky, R.S. Williams, Z. Li, J. Am. Chem. Soc. 132 (37), 12820 (2010).

    Article  CAS  Google Scholar 

  61. F.S. Ou, M. Hu, I. Naumov, A. Kim, W. Wu, A.M. Bratkovsky, X. Li, R.S. Williams, Z. Li, Nano Lett. 11 (6), 2538 (2011).

    Article  CAS  Google Scholar 

  62. A. Kim, F.S. Ou, D.A. Ohlberg, M. Hu, R.S. Williams, Z. Li, J. Am. Chem. Soc. 133 (21), 8234 (2011).

    Article  CAS  Google Scholar 

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Acknowledgments

S.T. acknowledges funding by the Mechanical Science and Engineering Department at the University of Illinois at Urbana-Champaign. J.B. acknowledges partial funding by the IAP 7/38 MICROMAST program initiated by BELSPO.

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Correspondence to Sameh H. Tawfick.

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Tawfick, S.H., Bico, J. & Barcelo, S. Three-dimensional lithography by elasto-capillary engineering of filamentary materials. MRS Bulletin 41, 108–114 (2016). https://doi.org/10.1557/mrs.2016.4

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