Abstract
A wide variety of materials are currently used as supplementary cementitious materials (SCMs) for concrete, including natural materials and byproducts from various industries. Historically, natural SCMs, mostly derived from volcanic deposits, were common in concrete. In recent years, the dominant SCMs have been industrial by-products such as fly ash, ground granulated blast furnace slag (GGBFS), and silica fume. There is currently a resurgence of research into historic and natural SCMs, as well as other alternative SCMs for many reasons. The primary benefits of SCM use in improvement of long-term mechanical performance, durability, and sustainability are widely accepted, so local demand for these materials can exceed supply. This paper describes some of the SCMs that are attracting attention in the global research community and the properties and characteristics of these materials that affect their performance. Special attention is paid to the importance and demands of material characterization. Many SCMs do not necessarily lend themselves to characterization methods used in standardized test methods, which sometimes fail to describe the properties that are most important in predicting reactivity.
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References
P. Van den Heede and N. De Belie, Cem. Concr. Comp. 34, 431 (2012).
M. Schneider, M. Romer, M. Tschudin and H. Bolioc, Cem. Concr. Res. 41, 642 (2011).
S.H. Kosmatka and M.L. Wilson, Design and Control of Concrete Mixtures, 15 th ed., (Port. Cem. Assoc., Skokie, IL, 2011).
K.L. Scrivener and R.J. Kirkpatrick, Cem. Concr. Res. 38, 128 (2008).
CEMBUREAU, The European Cement Association Activity Report (2011).
K. Scrivener, Am. Ceram. Soc. Bull. 91 (5) 47–50 (2012).
V.M. Malhotra, Concr. Int. 28 (9) 42 (2006).
S. Reynolds, The Future of Ferrous Slag, Market Forecasts to 2020, (Pira International Ltd, Leatherhead, UK, 2009).
J.S. Damtoft, J. Lukasik, D. Herfort, D. Sorrentino and E.M. Gartner, Cem. Concr. Res. 38, 115 (2008).
K.L Scrivener, and A. Nonat, Cem. Concr. Res. 41, 651 (2011).
R.E. Davis, R.W. Carlson, J.W. Kelly and H.E. Davis, J. Am. Concrete. Inst. 33, 577 (1937).
N. Bouzoubaâ, M.H. Zhang, V.M. Malhotra and D.M. Golden, ACI Mater. J. 96, 641 (1999).
N. Bouzoubaâ and M. Lachemi, Cem. Concr. Res. 31, 413 (2001).
H. Yazıcı, S. Aydın, H. Yiğiter and B. Baradan, Cem. Concr. Res. 35, 1122 (2005).
S. Schlorholtz, T. Demirel and J.M. Pitt, Cem. Concr. Res. 14, 499 (1984).
D. Cross, J. Stephens and J. Vollmer, (World of Coal Ash, Lexington, KY 2005).
R.T. Hemmings and E.E. Berry, in Fly Ash and Coal Conversion By-Products: Characterization, Utilization, and Disposal IV, edited by G.J. McCarthy, F.P. Glasser, D.M. Roy (Mater. Res. Soc. Symp. Proc 113, Warrendale, PA, 1988), pp. 3–38.
J.C. Qian, E.E. Lachowski and F.P. Glasser, in Fly Ash and Coal Conversion By-Products: Characterization, Utilization, and Disposal IV, edited by G.J. McCarthy, F.P. Glasser, D.M. Roy (Mater. Res. Soc. Symp. Proc 113, Warrendale, PA, 1988), pp. 45–54
J.H. Brindle and M.J. McCarthy, Energ. Fuel 20, 2580 (2006).
C.R. Ward and D. French, Fuel 85, 2268 (2006).
CUAP “Fly Ash for Concrete” (annexe B) (2006) (ETA request No. 0301/34)
I. Odler, Special inorganic cements (E&FN Spon, Taylor& Francis Group, London, 2000).
M.P. Luxán, M.I. Sánchez de Rojas and M. Frías, Cem. Concr. Res. 19, 69 (1989).
B. Mather, Cem. Concr. Res. 14, 887 (1984).
R.L. Hill, S.L. Sarkar, R.F. Rathbone and J.C. Hower, Cem. Concr. Res. 27, 193 (1997).
K.H. Pedersen, A.D. Jensen and K. Dam-Johansen, Combust. Flame 157 (2) 208 (2010).
S. Wang, A. Miller, E. Llamazos, F. Fonseca and L. Baxter, Fuel 87, 365 (2008).
A. Johnson, L.J.J. Catalan and S.D. Kinrade, Fuel 89, 3042 (2010).
P. Duxson and J.L. Provis, J. Am. Ceram. Soc. 91, 3864 (2008).
S. Diamond, Cem. Concr. Res. 13, 459 (1983).
R.T. Chancey, P. Stutzman, M.C.G. Juenger and D.W. Fowler, Cem. Concr. Res. 40, 146 (2010).
H.S. Pietersen, A.L.A. Fraay and J.M. Bijen, in Fly Ash and Coal Conversion By-Products VI, edited by R.L. Day and F.P. Glasser (Mater. Res. Soc. Symp. Proc. 178, Boston, MA, 1989) pp. 139–157.
H.J.H. Brouwers and R.J. van Eijk, J. Mater.Sci. 37, 2129 (2002).
J.L. Provis and J.S.J. van Deventer, Chem. Eng. Sci. 62, 2318 (2007).
G. Baert, N. De Belie and G. De Schutter, J. Mater. Civil Eng. 23, 761 (2011).
R.D. Hooton, Supplementary Cementing Materials, edited by V.M. Malhotra (CANMET 1987) p. 247.
F. Schröder, Proceedings of the Fifth International Symposium on the Chemistry of Cement, (Tokyo, 1968) vol. IV, p. 149.
H. Kollo and J. Geiseler, Beton-Informationen, 4, 48 (1987).
H. Kollo, Beton-Informationen 31, 22 (1991).
H.G. Smolczyk, Zement-Kalk-Gips 31 (6), 294 (1978).
E. Olbrich, Struktur und Reaktionsfähigkeit von Hüttensandglas, (PhD Thesis, TU Clausthal, Germany 1999).
L. Tetmajer, Stahl und Eisen, 6, 473 (1886).
J.C. De Langavant, Revue des Matériaux de Construction et de Traveaux Publics, 401, 381 (1949).
S.-D. Wang, K.L. Scrivener, and P.L. Pratt, Cem. Concr. Res. 24, 1033 (1994).
F. Schröder, Tonmineralogie-Zeitung, 85, (2/3), 39 (1961).
R.D. Hooton, and J.J. Emery, Proceedings, First International Conference on the Use of Fly Ash, Silica Fume, Slag and Other Mineral By-Products in Concrete, (ACI SP79, vol. 2, Montebello, Quebec, 1983) p. 943.
W. Matthes, Holcim Group Support Ltd. (private communication).
O. Farkas, Freiberger Forschungshefte, Reihe B, 106, 43 (1951).
J.O.M. Bockris and J.D. Kitchener, T. Faraday Soc., 51, 1734 (1955).
F. Keil, Hochofenschlacke, 2 nd edition, (Verlag Stahleisen M.B.H., Düsseldorf 1963).
E. Demoulian, P. Gourdin, F. Hawthorn and C. Vernet, Proceedings of the Seventh International Congress on the Chemistry of Cement, 2(III) (Paris, 1980) p. 89.
G. Frigione, Blended Cements, (ASTM STP 897, 1986) p. 15.
W. Wassing, Cement I., 5, 94 (2003).
M. Regourd, J.H. Thomassin, P. Baillif and J.C. Touray, Cem. Concr. Res. 13, 549 (1983).
R. Dron and F. Brivot Proceedings of the Seventh International Conference of Cement and Concrete, 2, III (Paris, 1980) p. 134.
P. Javelle, Cent. Doc. Siderurg., Circ. Inform. Tech., 26 (3) 689 (1969).
H.E. Schwiete and F.C. Dölbor, Forschungsberichte des Landes Nordrhein-Westfahlen, Deutschland, Nr. 1186, (1963) 119 pp.
K. Grade, Proceedings of the Fifth International Symposium on the Chemistry of Cement, 4, (Tokyo, 1968), p. 168.
Kocaba. V, Gallucci E., Scrivener K. (2012) Methods for determination of degree of reaction of slag in blended cement pastes Cement and Concrete Research, Volume 42, Issue 3, Pages 511–525
Taylor H.F.W. (1992) Cement Chemistry, Academic Press Ltd., London, 2nd printing, 475 pp.
Poulsen S.L., Jacobson H.J., Skibsted J (2009) Methodologies for measuring the degree of hydration in Portland cement blends with Supplementary Cementitious Materials by 27Al and 29Si MAS NMR Spectroscopy, Proc. 17th Ibausil, Weimar, Germany, 1, 177–188
R.D. Hooton, Can. J. Civil Eng., 27, 754 (2000).
ACI 234R-06, “Guide for the Use of Silica Fume in Concrete,” ACI Manual of Concrete Practice. (ACI 2006).
P. Fidjestol, Elkem Materials (private communication).
B. Nebesar and G.G. Carette, Cem. Concr. Aggr. 8, 42 (1986).
P.C. Aïtcin, P. Pinsonneault, and D.M. Roy, Ceram. Bull., 63, 1487 (1984).
K. Popovic, V. Ukraincik, and A. Djurekovic, Durability Build. Mater., 2 (2) 171 (1984).
V.M. Malhotra, V.S. Ramachandran, R.F. Feldman, and P.C. Aïtcin, Condensed Silica Fume in Concrete, (CRC Press, Inc., Boca Raton, FL, 1987).
G.W. Brindley and M. Nakahira, J.Am. Ceram. Soc. 42 (7), 311 (1959).
B.B. Sabir, S. Wild and J. Bai, Cem. Concr. Comp. 23(6), 441 (2001).
B. Lothenbach, K. Scrivener and R.D. Hooton, Cem. Concr. Res. 41, 1244 (2011).
D.R. Collins, A.N. Fitch and C.R.A. Catlow, J. Mater. Chem. 1 (6), 965 (1991).
S. Lee, Y.J. Kim and H.S. Moon, J. Am. Ceram. Soc. 86 (1), 174 (2003).
C.E. White, J.L. Provis, T. Proffen, D.P. Riley and J.S.J. van Deventer, Phys. Chem. Chem. Phys. 12 (13), 3239 (2010).
C.E. White, J.L. Provis, T. Proffen, D.P. Riley and J.S.J. van Deventer, J. Phys. Chem. A 114 (14) 4988 (2010).
R. Fernandez, F. Martirena and K.L. Scrivener, Cem. Concr. Res. 41, 113 (2011).
J. Ambroise, M. Murat, and J. Pera, Cem. Concr. Res. 15, 261 (1985).
C. He, B. Osbaeck and E. Makovicky, Cem. Concr. Res. 25, 1691 (1995).
C. He, E. Makovicky and B. Osbæck, Appl. Clay Sci. 17, 141 (2000)
G. Habert, N. Choupay, G. Escadeillas, D. Guillaume and J.M. Montel, Appl. Clay Sci. 43 322 (2009).
A. Tironi, M.A. Trezza, A.N. Scian and E.F. Irassar, Const. Build. Mat. 28, 276 (2012).
M.G. Idorn, Concrete Progress from Antiquity to the Third Millenium (Telford, London 1997).
D.J. Cook, in Cement Replacement Materials, edited by R.N. Swamy (Surrey University Press, London 1986) p 1–39.
V.M. Malhotra and P.K. Mehta, Pozzolanic and Cementitious Materials (Taylor & Francis 1996).
C. Colella, M. de Gennaro, and R. Aiello, Rev. Mineral Geochem. 45, 551 (2001).
F. Massazza, in Lea’s Chemistry of Cement and Concrete. Edited by P.C. Hewlett (Butterworth-Heinemann, Oxford 2001) p 471–636.
F. Massazza, in Structure and Performance of Cements, 2 nd ed., edited by J. Bensted and P. Barnes P (Spon Press, London 2002) p 326–352.
R. Snellings, G. Mertens and J. Elsen, Rev. Min. Geoch. 74, 211 (2012).
U. Ludwig and H.E. Schwiete, Zem-Kalk-Gips 10, 421 (1963).
B. Mortureux, H. Hornain, E. Gautier and M. Regourd, Proc 7th Int Cong Chem Cement IV:110–115 (1980).
R.C. Mielenz, L.P. White and O.J. Glantz, in Symposium on the Use of Pozzolanic Materials in Mortars and Concrete. ASTM Special Technical Publication 99, 43 (1950)
M.S. Akman, F. Mazlum and F. Esenli, Comparative study of natural pozzolans used in blended cement production. ACI Special Publication 132, 471 (1992).
P.K. Mehta, Natural pozzolans: Supplementary cementing materials for concrete. CANMET Special Publication 86, 1 (1987).
D.S. Kosson, H.A. van der Sloot, and T.T. Eighmy, J. Haz. Mater. 47, 43 (1996)
L. Bertolini, M. Carsana, D. Cassago, A.Q. Curzio and M. Collepardi, Cem. Concr. Res. 34, 1899 (2004).
C.H.K. Lam, A.W.M. Ip, J.P. Barford and G. McKay, Sustainability 2, 1943 (2010).
M. Keppert, Z. Pavlík, R. Černý and P. Reiterman, IACSIT Coimbatore Conferences IPCSIT vol. 28 (IACSIT Press, Singapore, 2012) pp. 127–131.
G. Boghetich, L. Liberti, M. Notarnicola, M. Palma and D. Petruzzelli, Waste Manag. Res., 23, 57 (2005).
J. Pera, L. Coutaz, J. Ambroise, and M. Chababbet, Cem. Concr. Res. 27 (1), 1 (1997).
J.E. Aubert, B. Husson, A. Vaquier: Use of municipal solid waste incineration fly ash in concrete, Cem. Concr. Res. 34, 957 (2004).
R. Ito, G. Dodbiba, T. Fujita, J.W. Ahn, Waste Manag. 28: 1317 (2008).
G. Escadeillas Cement modified with limestone fillers: optimization by means of mechanical and physical properties, Doctoral thesis (in French) (Université de Toulouse, 1988).
L. Courard, R. Degeimbre, A. Darimont, F. Michel, X. Willem and St. Flamant, in ConMat’05 Third International Conference on construction materials: performance, innovations and structural implications, Theme 3-Chapter 5, (Vancouver, Canada, 2005).
P. Hawkins, P. Tennis, R. Detwiler, The Use of Limestone in Portland Cement: A State-of-the-art Review (Portland Cement Association, Skokie, IL 2003).
T. Matschei, B. Lothenbach, F.P. Glasser, Cem. Concr. Res. 37, 551 (2007).
B. Lothenbach, G. Le Saout, E. Gallucci, and K. Scrivener, Cem. Concr. Res. 38, 848 (2008).
F. Michel, Physical characterization of limestone fillers, Master’s Thesis (in French) (Université de Liège, Belgium 2006).
F. Michel, J. Pierard, L. Courard and V. Pollet, in 5th International RILEM Symposium on Self-Compacting Concrete Proceedings PRO 54, edited by G. De Schutter and V. Boel (Rilem Publications, Gent, Belgium 2007) p. 205–210.
E. Pirard, N. Vergara and V. Chapeau, in Proceedings of International congress for particle technology (Nuremberg, Gemany 2004).
H. He, L. Courard, F. Michel and E. Pirard, in Recueil des communications des journees scientifiques du (RF)2B: 26–35 (in French) (2012).
Acknowledgements
This work is an outcome of the committee work of the members of RILEM TC-SCM WG1, a working group on the characterization of supplementary cementitious materials. Members of the committee are thanked for their ideas and contributions. Funding for M. Juenger’s work on SCMs has been provided by the U.S. National Science Foundation (CMMI- 1030972) and the Texas Department of Transportation (project 0-6717). Work performed by H. He, F. Michel and L. Courard on limestone fillers was founded by Post-Doc Grant of Université de Liège and CEMCALC research project (Wallonia Grant).
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Juenger, M., Provis, J.L., Elsen, J. et al. Supplementary Cementitious Materials for Concrete: Characterization Needs. MRS Online Proceedings Library 1488, 8–22 (2012). https://doi.org/10.1557/opl.2012.1536
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DOI: https://doi.org/10.1557/opl.2012.1536