Journal of the Ceramic Society of Japan
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
Theoretical Model for Viscoelastic Sliding of Interfaces and Creep Behavior of Anion-Doped Si3N4/SiC Composites
Giuseppe PEZZOTTIKen'ichi OTA
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1997 Volume 105 Issue 1217 Pages 1-5

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Abstract

A theoretical model for relating the interface viscosity to the creep behavior of highly refractory ceramics is proposed. Experimental confirmation of the model is given by monitoring the effect of systematic modifications in the interface viscosity on the creep behavior of Si3N4/SiC composites. A model material was selected for this basic study with a continuous film, consisting of glassy SiO2, at the interface, whose bulk anion composition was varied by incorporating increasing amounts of glass-network modifier ions (i.e., F or Cl anions). Internal friction measurements allowed to experimentally evaluate the micromechanical response of the internal interfaces, when subjected to an externally applied shear stress. Starting from this important experimental information, the short-term macroscopic creep behavior of the polycrystal could be predicted and consistently related to microscopic interface viscosity parameter.

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