Journal of the Ceramic Society of Japan
Online ISSN : 1348-6535
Print ISSN : 1882-0743
ISSN-L : 1348-6535
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Effect of MgSiN2 addition on gas pressure sintering and thermal conductivity of silicon nitride with Y2O3
X. W. ZHUYoshio SAKKAY. ZHOUKiyoshi HIRAO
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2008 Volume 116 Issue 1354 Pages 706-711

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Abstract

This paper reports the gas pressure sintering and thermal conductivity of silicon nitride with 2 mol% Y2O3 and varied contents of MgSiN2 in the range of 0 to 5 mol% at 1900°C under a nitrogen pressure of 1 MPa N2. It was found that the density curves show a typical "V" shape against the MgSiN2 content. The 1 mol% MgSiN2 hinders significantly the densification, but the 5 mol% MgSiN2 leads to complete densification. The inhibited densification is associated with the pronounced normal grain growth. However, the abnormal grain growth is inhibited with the addition of MgSiN2. After sintering for 12 h, the sample without MgSiN2 exhibits the coarsest and highest bimodal microstructure, whereas the one with 5 mol% MgSiN2 exhibits the finest microstructure. Although the MgSiN2 addition leads to a slightly enhanced thermal conductivity, it tends to reduce the thermal diffusivity. The thermal conductivity without porosity shows a decrease with the increase of MgSiN2 content because of the inhibited grain growth.

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© 2008 The Ceramic Society of Japan
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