Journal of the Ceramic Society of Japan
Online ISSN : 1348-6535
Print ISSN : 1882-0743
ISSN-L : 1348-6535
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Turbostratic boron nitride consolidated by SPS
Naoki TOYOFUKUNatsuki YAMASAKIYasuhiro KODERAManshi OHYANAGIZuhair A. MUNIR
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2009 Volume 117 Issue 1362 Pages 189-193

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Abstract

Turbostratic boron nitride (t-BN) powder prepared by mechanical grinding of hexagonal boron nitride (h-BN) under the nitrogen atmosphere with the oxygen concentration less than 1 ppm was consolidated by spark plasma sintering (SPS). The turbostratic structure was maintained after the consolidation, which was characterized by XRD, Raman and IR spectra. The t-BN consolidated without any additives at 1900°C for 10 min under applied pressure of 100 MPa showed a bulk density of 95%. The bending strength, Young's modulus and Shore hardness of the consolidated t-BN were 72 MPa, 259 GPa and 117 Hs, respectively. They were much higher than those of conventionally consolidated h-BN. On the other hand, the thermal conductivity was 3 W/mK and much lower than the compact of h-BN.

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© 2009 The Ceramic Society of Japan
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