Journal of the Ceramic Society of Japan
Online ISSN : 1348-6535
Print ISSN : 1882-0743
ISSN-L : 1348-6535
Special Articles: The 66th CerSJ Awards for Academic Achievements in Ceramic Science and Technology: Review
Size effect of barium titanate: fine particles and ceramics
Takuya HOSHINA
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2013 Volume 121 Issue 1410 Pages 156-161

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Abstract

The size effect of ferroelectric materials is one of the most important issues to develop next-generation dielectric devices. In this paper, we reviewed our studies on the size effects of barium titante (BaTiO3) fine particles and ceramics. In the size effect of BaTiO3 fine particles, the maximum of dielectric permittivity was observed at a particle size of around 140 nm, and was explained by the composite structure model including a gradient lattice strain layer (GLSL) having a very high permittivity. In contrast, the grain size effect of BaTiO3 ceramics, where the permittivity showed a maximum at a grain size of about 1.1 µm, was interpreted as the superposition effect of domain-wall contributions and grain boundary effect.

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© 2013 The Ceramic Society of Japan
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