2001 年 57 巻 5 号 p. 148-152
Desized and scoured ramie fabric was treated with liquid ammonia (NH3) using a practical range. Crystllinity, moisture regain, water absorption, and dyeing properties were measured to investigate the internal structure of the fiber by the NH3 trestment. Crystallite structure of ramie cellulose I was transformed to cellulose III by the NH3 treatment. Crystallinity was decreased not only by the NaOH but also by the NH3 treatments, especially by the latter. Water absorption was increased by the NaOH treatment, whereas it decreased by the NH3 treatment. Early dyeing rate of the fabric was increased considerably with NaOH treatment, while it decreased greatly with the NH3 and NaOH/NH3 treatments. Nevertheless equilibrium dye uptake was increased a little by the NH3 treatment. As a measure of fabric hand, shearing and bending hysteresis curves were obtained using KES instrument. Shearing modulus G, bending hysteresis width 2HG, bending modulus B and bending hysteresis width 2HB were obviously decreased by the NH3 and NaOH/NH3 treatments.