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Extraction Behavior and Separation of Lanthanides with a Diglycol Amic Acid Derivative and a Nitrogen-donor Ligand

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Abstract

The extraction and separation of lanthanides have been investigated using CHON-type extractants, which are composed of only C, H, O, and N atoms. N,N-Dioctyldiglycol amic acid (DODGAA) showed high extraction and separation performances for heavier lanthanides compared with typical CHON-type extractants. On the other hand, N,N,N′,N′-tetrakis(2-pyridylmethyl)ethylenediamine (TPEN) provided an unprecedentedly high selectivity for lighter lanthanides. Furthermore, it was found that the combination of DODGAA and TPEN under suitable conditions enabled the mutual separation of light, middle, and heavy lanthanides.

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Authors and Affiliations

  1. Division of Environment and Radiation Sciences, Nuclear Science and Engineering Directorate, Japan Atomic Energy Agency, Tokai, Ibaraki, 319-1195, Japan

    Kojiro Shimojo & Hirochika Naganawa

  2. Research Department, NISSAN ARC, LTD., Yokosuka, 237-0061, Japan

    Junji Noro

  3. Department of Applied Chemistry, Graduate School of Engineering and Center for Future Chemistry, Kyushu University, 744 Motooka, Fukuoka, 819-0395, Japan

    Fukiko Kubota & Masahiro Goto

Authors
  1. Kojiro Shimojo
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  2. Hirochika Naganawa
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  3. Junji Noro
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  4. Fukiko Kubota
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  5. Masahiro Goto
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Correspondence to Kojiro Shimojo.

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Shimojo, K., Naganawa, H., Noro, J. et al. Extraction Behavior and Separation of Lanthanides with a Diglycol Amic Acid Derivative and a Nitrogen-donor Ligand. ANAL. SCI. 23, 1427–1430 (2007). https://doi.org/10.2116/analsci.23.1427

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  • DOI: https://doi.org/10.2116/analsci.23.1427

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