Abstract
Nitrate and nitrite ions were found to be successfully electroreduced at an in situ electrochemically pretreated copper electrode in acidic media, and their reduction peaks of a cyclic voltammogram were found at two distinct electrode potentials. Cyclic voltammetric experiments revealed a highly sensitive behavior of the pretreated copper electrode upon the electroreduction of nitrate and nitrite ions, and showed that a simultaneous voltammetric determination of the ions was achievable. Differential pulse voltammetry (DPV) was applied to the simultaneous determination. As a result, the detection limits were 0.26 and 0.17 µmol dm–3 for nitrate and nitrite ions, respectively. Simultaneous determinations for real samples (river water) were carried out by DPV at the pretreated copper electrode and spectrophotometry (the Griess method). The determination values obtained by both methods were in a good agreement with each other.
Similar content being viewed by others
References
M. J. Moorcroft, J. Davis, and R. G. Compton, Talanta, 2001, 54, 785.
B. Yu, P. Chen, L. Nie, and S. Yao, Anal. Sci., 2001, 17, 495.
M. I. H. Helaleh and T. Korenaga, J. Chromatogr., B, 2000, 744, 433.
J. Threeprom, S. Watanesk, R. Watanesk, P. Kijjanapanich, P. Wiriyacharee, and R. L. Deming, Anal. Sci., 2002, 18, 947.
S. H. Lee and L. R. Field, Anal. Chem., 1984, 56, 2647.
K. Fukushi, K. Tada, S. Takeda, S. Wakida, M. Yamane, K. Higashi, and K. Hiiro, J. Chromatogr., A, 1999, 838, 303.
A. A. Okemgbo, H. H. Hill, and W. F. Siems, Anal. Chem., 1999, 71, 2725.
T. Aoki and M. Wakabayashi, Anal. Chim. Acta, 1995, 308, 308.
M. Zhang, D. Yuan, G. Chen, Q. Li, Z. Zhang, and Y. Liang, Microchim. Acta, 2009, 165, 427.
E. D. Wood, F. A. J. Armstrong, and F. A. Richards, J. Mar. Biol. Assoc. U.K., 1967, 47, 23.
M. J. Ahmed, C. D. Stalikas, S. M. Tzouwara-karayanni, and M. I. Karayannis, Talanta, 1996, 43, 1009.
O. V. Kaminskaya, E. A. Zakharova, and G. B. Slepchenko, J. Anal. Chem., 2004, 59, 1091.
J. Davis, M. J. Moorcroft, S. J. Wilkins, R. G. Compton, and M. F. Cardosi, Analyst, 2000, 125, 737.
T. R. L. C. Paixao, J. L. Cardoso, and M. Bertotti, Talanta, 2007, 71, 186.
J. Krista, M. Kopanica, and L. Novotny, Electroanalysis, 2000, 12, 199.
G. Zhao, K. Liu, S. Lin, J. Liang, X. Guo, and Z. Zhang, Microchim. Acta, 2004, 144, 75.
M. E. Bodini and D. T. Sawyer, Anal. Chem., 1977, 49, 485.
K. Soropogui, M. Sigaud, and O. Vittori, Electroanalysis, 2007, 19, 2559.
J. Mo, D. Jin, J. Pei, and Z. Zhao, Anal. Sci., 1990, 6, 251.
Y. Lou, Y. Shao, P. Li, Z. Li, and Z. Niu, J. Electroanal. Chem., 2008, 624, 33.
C. Polatides and G. Kyriacou, J. Appl. Electrochem., 2005, 35, 421.
S. E. Bae, K. L. Stewart, and A. A. Gewirth, J. Am. Chem. Soc., 2007, 129, 10171.
W. Y. Ko, W. H. Chen, C. Y. Cheng, and K. J. Lin, Sens. Actuators, B, 2009, 137, 437.
A. G. Fogg, S. P. Scullion, and T. E. Edmonds, Analyst, 1991, 116, 573.
G. E. Badea, Electrochim. Acta, 2009, 54, 996.
D. Reyter, D. Belanger, and L. Roue, Electrochim. Acta, 2008, 53, 5977.
S. M. Shariar, M. Suga, Y. Nishikawa, and T. Hinoue, Anal. Sci., 2009, 25, 499.
“Standard Methods for the Examination of Water and Wastewater. American Public Health Association”, 1999, American Water Works Association, Water Environment Federation.
S. Glasstone and A. Hickling, “Electrolytic Oxidation and Reduction: Inorganic and Organic”, ed. E. H. Tripp, 1935, Vol. 9, Chap. 6, Chapman & Hall, Ltd., London.
L. D. Burke, A. M. O’connel, R. Sharna, and C. A. Buckley, J. Appl. Electrochem., 2006, 36, 919.
W. J. Plieth, “Nitrogen”, in “Encyclopedia of Electrochemistry of the Elements”, 1978, Vol. 8, Chap. 5, 321 - 479.
J. Davis, M. J. Moorcroft, S. J. Wilkins, R. G. Compton, and M. F. Cardosi, Electroanalysis, 2000, 12, 1363.
A. Vicenzo and P. L. Cavallotti, J. Appl. Electrochem., 2002, 32, 743.
Database of 2001 – 2005 Mineral Data Publishing, Ver. 1, http://www.handbookofmineralogy.org/.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shariar, S.M., Hinoue, T. Simultaneous Voltammetric Determination of Nitrate and Nitrite Ions Using a Copper Electrode Pretreated by Dissolution/Redeposition. ANAL. SCI. 26, 1173–1179 (2010). https://doi.org/10.2116/analsci.26.1173
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.2116/analsci.26.1173