doiSerbia

Comparison of properties of silver-metal oxide electrical contact materials

Ćosović V. (Institute of Chemistry, Technology and Metallurgy, Belgrade)
Talijan N. (Institute of Chemistry, Technology and Metallurgy, Belgrade)
Živković D. (Technical Faculty, Bor)
Minić D. (Faculty of Technical Sciences, Kosovska Mitrovica)
Živković Ž. (Technical Faculty, Bor)

Changes in physical properties such as density, porosity, hardness and electrical conductivity of the Ag-SnO2 and Ag-SnO2In2O3 electrical contact materials induced by introduction of metal oxide nanoparticles were investigated. Properties of the obtained silver-metal oxide nanoparticle composites are discussed and presented in comparison to their counterparts with the micro metal oxide particles as well as comparable Ag-SnO2WO3 and Ag-ZnO contact materials. Studied silvermetal oxide composites were produced by powder metallurgy method from very fine pure silver and micro- and nanoparticle metal oxide powders. Very uniform microstructures were obtained for all investigated composites and they exhibited physical properties that are comparable with relevant properties of equivalent commercial silver based electrical contact materials. Both Ag-SnO2 and Ag- SnO2In2O3 composites with metal oxide nanoparticles were found to have lower porosity, higher density and hardness than their respective counterparts which can be attributed to better dispersion hardening i.e. higher degree of dispersion of metal oxide in silver matrix.

Keywords: silver based electrical contacts, metal oxide nanoparticles, powder metallurgy, physical properties